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21.
有机锡化合物对水生无脊椎动物的毒性研究   总被引:3,自引:0,他引:3  
陈天乙  郑素平 《环境化学》1994,13(3):266-268
通过不同层次水生无脊椎动物的毒理学研究,能更好地反映有机化合物的生态效应,以氯化三丁基锡(TBTCl)为例,结果表明,TBTCl对原生动物等5种水生无脊椎动物的半致死浓度(LC50)为25.65-355.63ppb,有明显的种特异性,TBTCl对河口轮虫种群净生殖率EC50为10ppb,影响平均寿命EC50为22ppb,根据浓度C及原生动物平衡种类数Seq进行回归,得方程Seq=11.87-1.8  相似文献   
22.

The electric power grid is a critical societal resource connecting multiple infrastructural domains such as agriculture, transportation, and manufacturing. The electrical grid as an infrastructure is shaped by human activity and public policy in terms of demand and supply requirements. Further, the grid is subject to changes and stresses due to diverse factors including solar weather, climate, hydrology, and ecology. The emerging interconnected and complex network dependencies make such interactions increasingly dynamic, posing novel risks, and presenting new challenges to manage the coupled human–natural system. This paper provides a survey of models and methods that seek to explore the significant interconnected impact of the electric power grid and interdependent domains. We also provide relevant critical risk indicators (CRIs) across diverse domains that may be used to assess risks to electric grid reliability, including climate, ecology, hydrology, finance, space weather, and agriculture. We discuss the convergence of indicators from individual domains to explore possible systemic risk, i.e., holistic risk arising from cross-domain interconnections. Further, we propose a compositional approach to risk assessment that incorporates diverse domain expertise and information, data science, and computer science to identify domain-specific CRIs and their union in systemic risk indicators. Our study provides an important first step towards data-driven analysis and predictive modeling of risks in interconnected human–natural systems.

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23.
In this study, super-fine powdered activated carbon (SPAC) has been proposed and investigated as a novel catalyst for the catalytic ozonation of oxalate for the first time. SPAC was prepared from commercial granular activated carbon (GAC) by ball milling. SPAC exhibited high external surface area with a far greater member of meso- and macropores (563% increase in volume). The catalytic performances of activated carbons (ACs) of 8 sizes were compared and the rate constant for pseudo first-order total organic carbon removal increased from 0.012 min–1 to 0.568 min–1 (47-fold increase) with the decrease in size of AC from 20 to 40 mesh (863 mm) to SPAC (~1.0 mm). Furthermore, the diffusion resistance of SPAC decreased 17-fold compared with GAC. The ratio of oxalate degradation by surface reaction increased by 57%. The rate of transformation of ozone to radicals by SPAC was 330 times that of GAC. The results suggest that a series of changes stimulated by ball milling, including a larger ratio of external surface area, less diffusion resistance, significant surface reaction and potential oxidized surface all contributed to enhancing catalytic ozonation performance. This study demonstrated that SPAC is a simple and effective catalyst for enhancing catalytic ozonation efficacy.
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24.
伴随重金属污染风险的不断提高,流域重金属迁移转化模型的构建和水体重金属的模拟预测受到广泛关注,关键参数的甄选是模型优化的重点.本文构建了某电镀集中区Ni、Cu重金属迁移转化数学模型,以Ni为例,采用标准秩回归分析方法(SRRC法)和Sobol多元自适应回归样条算法(Mars-Sobol法)对7个重金属模型参数进行敏感性分析,并针对确定的2个敏感性参数对Ni、Cu模型进行率定和验证.结果表明:1SRRC法的Ni河沙分配系数的敏感性占比为96.1%~99.7%,平均为99.2%,泥沙沉降速率为0.1%~3.3%,平均为0.5%.2Mars-Sobol法的Ni河沙分配系数的总敏感度占比为87.18%~93.44%,平均为90.28%;泥沙沉降速率为5.68%~10.68%,平均为8.21%;随水流运动方向,Ni河沙分配系数敏感性逐渐减低,泥沙沉降速率参数敏感性逐渐增强.3相较于SRRC法,Mars-Sobol考虑了参数间的交互作用,通过Ni、Cu迁移转化模型中敏感参数"河沙分配系数"和"泥沙沉降速率"的率定和验证,Ni、Cu模拟相对误差可控制在15.28%和14.46%,实现了重金属模型的高效和高精度预测.  相似文献   
25.
利用活性污泥-生物膜一体化反应器处理含苯酚废水,考察了反应器对苯酚和COD的处理效果以及反应器运行中生物膜干质量(SS)、挥发性干质量(VSS)、活性生物量、脱氢酶活性(DHA)、胞外聚合物(EPS)的变化,探究了生物膜特性与废水处理效果之间的关系.结果表明:在进水苯酚质量浓度由50mg·L-1逐步提高到500mg·L...  相似文献   
26.
Environmental Science and Pollution Research - Colloids associated with heavy metals are ubiquitous in contaminated groundwater; waste accumulation at imperfectly sealed landfills can produce large...  相似文献   
27.
采用PM2.5质量浓度长期连续观测资料,结合地面气象资料和后向轨迹方法,分析2009-2018年天津地区PM2.5质量浓度的长期变化趋势,并探讨气象条件对其浓度变化的影响.结果表明,2013年受不利天气影响,PM2.5质量浓度达到近10 a来的峰值,其后逐年下降,2018年年均值降至52 μg·m-3,与优良天气和重污染及以上天气发生频率的年际变化趋势一致.相关性分析和主成分分析都表明相对湿度、风速和混合层厚度是影响天津地区,尤其是冬季PM2.5浓度的主要气象影响因素.不同季节下随着相对湿度增高,地面风速减小,混合层厚度降低,均有PM2.5污染加重的趋势,其中冬季差异最大,与该季节气象因素剧烈多变、静稳天气和寒潮交替发生有关.后向轨迹的聚类分析结果表明,途经天津偏南区域的短距离近地气流下PM2.5质量浓度较高,与该气流下易形成静稳天气有关,春季西北方向的长距离轨迹对应较高浓度的PM2.5则与沙尘天气有关.  相似文献   
28.
模拟污染指标水体统计分析   总被引:5,自引:0,他引:5  
介绍了模拟污染水体中各类指标的单回归,逐步聚类分析,主成份分析及逐步判别分析,在聚类图和判虽函数中,溶解氧与色度具有最紧密关系,水中总和氮氮对水质也有显影响。对模拟试验样品,主成份分类与判别分析分类的结果相类似,而对城市河流体品用判别函数别的结果与观察到的天然状态相一致。  相似文献   
29.
三丁基锡对螺旋藻的毒性作用   总被引:7,自引:1,他引:7  
研究了氯化三丁基锡对盐泽螺放心藻的毒性作用。结果表明,TBT对盐泽螺旋藻的半数生长抑制浓度IC50为5.09μg/L。  相似文献   
30.
Abstract

As the main organic pollutant in municipal living waste, kitchen waste causes secondary pollution in the course of its being gathered and transported to the landfill by mixing with other refuse and by decomposition. This makes pollution prevention more difficult and raises the cost of landfill engineering. However, the amount of solid waste to be treated can be decreased and such pollution burden lessened by disposing of the solid waste in local municipal areas. The program in Beijing also shows that this works well with our situation in China and can accelerate marketization and public participation.  相似文献   
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