全文获取类型
收费全文 | 677篇 |
免费 | 18篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 22篇 |
废物处理 | 33篇 |
环保管理 | 156篇 |
综合类 | 94篇 |
基础理论 | 170篇 |
环境理论 | 1篇 |
污染及防治 | 134篇 |
评价与监测 | 32篇 |
社会与环境 | 41篇 |
灾害及防治 | 15篇 |
出版年
2023年 | 8篇 |
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 16篇 |
2018年 | 14篇 |
2017年 | 17篇 |
2016年 | 28篇 |
2015年 | 14篇 |
2014年 | 24篇 |
2013年 | 63篇 |
2012年 | 35篇 |
2011年 | 31篇 |
2010年 | 28篇 |
2009年 | 37篇 |
2008年 | 46篇 |
2007年 | 36篇 |
2006年 | 26篇 |
2005年 | 29篇 |
2004年 | 30篇 |
2003年 | 20篇 |
2002年 | 16篇 |
2001年 | 18篇 |
2000年 | 20篇 |
1999年 | 5篇 |
1998年 | 10篇 |
1997年 | 9篇 |
1996年 | 10篇 |
1995年 | 8篇 |
1994年 | 10篇 |
1993年 | 7篇 |
1992年 | 10篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 4篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 2篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有698条查询结果,搜索用时 15 毫秒
41.
Tim S. Nawrot Nino Kuenzli Jordi Sunyer Tingming Shi Teresa Moreno Mar Viana Joachim Heinrich Bertil Forsberg Frank J. Kelly Muhammad Sughis Benoit Nemery Paul Borm 《Atmospheric environment (Oxford, England : 1994)》2009,43(30):4595-4602
We assessed the extent to which constituents of PM2.5 (transition metals, sodium, chloride) contribute to the ability to generate hydroxyl radicals (OH) in vitro in PM2.5 sampled at 20 locations in 19 European centres participating in the European Community Respiratory Health Survey. PM2.5 samples (n = 716) were collected on filters over one year and the oxidative activity of particle suspensions obtained from these filters was then assessed by measuring their ability to generate OH in the presence of hydrogen peroxide. Associations between OH formation and the studied PM constituents were heterogeneous. The total explained variance ranged from 85% in Norwich to only 6% in Albacete. Among the 20 centres, 15 showed positive correlations between one or more of the measured transition metals (copper, iron, manganese, lead, vanadium and titanium) and OH formation. In 9 of 20 centres OH formation was negatively associated with chloride, and in 3 centres with sodium. Across 19 European cities, elements which explained the largest variations in OH formation were chloride, iron and sodium. 相似文献
42.
Steen Solvang Jensen Tim Larson K.C. Deepti Joel D. Kaufman 《Atmospheric environment (Oxford, England : 1994)》2009,43(30):4544-4556
We evaluated the Danish AirGIS air quality and exposure model system using air quality measurement data from New York City in the Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air). Measurements were used from three US EPA Air Quality System (AQS) monitoring stations and a comprehensive MESA Air measurement campaign including about 150 different locations and about 650 samples of about 2 week measurements of NOx, NO2 and PM2.5. AirGIS is a deterministic exposure model system based on the dispersion models Operational Street Pollution Model (OSPM) and the Urban Background Model (UBM). The UBM model reproduced the annual levels within 1–26% depending on station and pollutant at the three urban background EPA monitor stations, and generally reproduced well the seasonal and diurnal variation. The full model with OSPM and UBM reproduced the MESA Air measurements with a correlation coefficient of r2 = 0.51 for NOx, r2 = 0.28 for NO2 and r2 = 0.73 for PM2.5. 相似文献
43.
44.
Thomas H. Hutchinson Amanda Beesley Patricia E. Frickers James W. Readman Jenny P. Shaw Jürg Oliver Straub 《Environment international》2009,35(6):931-936
In case of an avian-influenza-derived human flu pandemic, an inordinately high use of medicines over several weeks is predicted, in particular for the recommended influenza antiviral oseltamivir (Tamiflu). While the risk of oseltamivir to sewage works and freshwater bodies has already been assessed, the fact that a large percentage of the human population worldwide lives relatively close to the sea raises concern for its environmental compatibility in coastal marine waters. The potential risk of high oseltamivir use to the marine compartment is assessed in this publication, based on the 2003 European Community Technical Guidance Document (TGD) for risk assessment. Subchronic embryo–larval ecotoxicity tests with three marine invertebrates (Pomatoceros triqueter, Annelida; Mytilus edulis, Mollusca; Paracentrotus lividus, Echinodermata) and chronic growth inhibition tests with two different groups of marine microalgae (Isochrysis galbana, Haptophyta; Skeletonema costatum, Heterokontophyta) were performed with the active substance oseltamivir carboxylic acid to derive a dependable marine predicted no-effect concentration (PNEC). This was compared to a predicted environmental concentration (PEC) for oseltamivir in coastal waters, based on the worst-case freshwater PEC. The PEC/PNEC risk characterisation ratio for the marine compartment is well below 1, which in the terminology of the TGD signifies no immediate concern. Further, while oseltamivir may be persistent (P), it is not bioaccumulative (B) nor highly ecotoxic (T) and therefore not a PBT substance. In conclusion, even a high pandemic use of oseltamivir would not lead to a significant risk for the marine compartment, in confirmation of the risk assessment for sewage works and freshwaters. 相似文献
45.
A hydrodynamic field study of the Segara Anakan lagoon combined with a reconstruction of the recorded data using a three-dimensional
numerical model provides insights into the processes driving the hydrodynamics of the lagoon. This includes bathymetry, quantification
of water volume fluxes with ADCP measurements, sea level recordings, salinity measurements, water budget and numerical model
results for the periods of the field studies. Salinity measurements at the Klaces village show a complete flushing of the
western lagoon during neap tide in the rainy season, which is assumed to increase the sedimentation. Mean salinities of the
western part are in the order of 10 and 21 g/kg, while the eastern part has a larger mean salinity of 27 and 32 g/kg for the
rainy and dry season, respectively. A numerical sensitivity study shows a relationship between the Citanduy discharge and
the nett water volume transport between the eastern and western part of Segara Anakan. A nett transport to the west, which
differs from neap to spring tides, turns to zero when Citanduy discharges are between 300 and 400 m3/s. The flushing time of the lagoon depends on the monsoon season and is about 1–3 days at the western outlet and increases
to 12 days in the central parts. 相似文献
46.
Jonathan M. H. Green Gemma R. Cranston William J. Sutherland Hannah R. Tranter Sarah J. Bell Tim G. Benton Eva Blixt Colm Bowe Sarah Broadley Andrew Brown Chris Brown Neil Burns David Butler Hannah Collins Helen Crowley Justin DeKoszmovszky Les G. Firbank Brett Fulford Toby A. Gardner Rosemary S. Hails Sharla Halvorson Michael Jack Ben Kerrison Lenny S. C. Koh Steven C. Lang Emily J. McKenzie Pablo Monsivais Timothy O’Riordan Jeremy Osborn Stephen Oswald Emma Price Thomas David Raffaelli Belinda Reyers Jagjit S. Srai Bernardo B. N. Strassburg David Webster Ruth Welters Gail Whiteman James Wilsdon Bhaskar Vira 《Sustainability Science》2017,12(2):319-331
Delivering access to sufficient food, energy and water resources to ensure human wellbeing is a major concern for governments worldwide. However, it is crucial to account for the ‘nexus’ of interactions between these natural resources and the consequent implications for human wellbeing. The private sector has a critical role in driving positive change towards more sustainable nexus management and could reap considerable benefits from collaboration with researchers to devise solutions to some of the foremost sustainability challenges of today. Yet opportunities are missed because the private sector is rarely involved in the formulation of deliverable research priorities. We convened senior research scientists and influential business leaders to collaboratively identify the top forty questions that, if answered, would best help companies understand and manage their food-energy-water-environment nexus dependencies and impacts. Codification of the top order nexus themes highlighted research priorities around development of pragmatic yet credible tools that allow businesses to incorporate nexus interactions into their decision-making; demonstration of the business case for more sustainable nexus management; identification of the most effective levers for behaviour change; and understanding incentives or circumstances that allow individuals and businesses to take a leadership stance. Greater investment in the complex but productive relations between the private sector and research community will create deeper and more meaningful collaboration and cooperation. 相似文献
47.
Environmental Economics and Policy Studies - This paper examines the consequences of an increase in the expected fine for non-compliance with an environmental design standard for an industry with... 相似文献
48.
John G. Watson Judith C. Chow Douglas H. Lowenthal L.-W. Antony Chen Stephanie Shaw Eric S. Edgerton 《Journal of the Air & Waste Management Association (1995)》2013,63(9):1104-1118
Positive matrix factorization (PMF) and effective variance (EV) solutions to the chemical mass balance (CMB) were applied to PM2.5 (particulate matter with an aerodynamic diameter <2.5 μm) mass and chemically speciated measurements for samples taken from 2008 to 2010 at the Atlanta, Georgia, and Birmingham, Alabama, sites. Commonly measured PM2.5 mass, elemental, ionic, and thermal carbon fraction concentrations were supplemented with detailed nonpolar organic speciation by thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS). Source contribution estimates were calculated for motor vehicle exhaust, biomass burning, cooking, coal-fired power plants, road dust, vegetative detritus, and secondary sulfates and nitrates for Atlanta. Similar sources were found for Birmingham, with the addition of an industrial source and the separation of biomass burning into open burning and residential wood combustion. EV-CMB results based on conventional species were qualitatively similar to those estimated by PMF-CMB. Secondary ammonium sulfate was the largest contributor, accounting for 27–38% of PM2.5, followed by biomass burning (21–24%) and motor vehicle exhaust (9–24%) at both sites, with 4–6% of PM2.5 attributed to coal-fired power plants by EV-CMB. Including organic compounds in the EV-CMB reduced the motor vehicle exhaust and biomass burning contributions at both sites, with a 13–23% deficit for PM2.5 mass. The PMF-CMB solution showed mixing of sources within the derived factors, both with and without the addition of speciated organics, as is often the case with complex source mixtures such as those at these urban-scale sites. The nonpolar TD-GC/MS compounds can be obtained from existing filter samples and are a useful complement to the elements, ions, and carbon fractions. However, they should be supplemented with other methods, such as TD-GC/MS on derivitized samples, to obtain a wider range of polar compounds such as sterols, sugars, and organic acids. The PMF and EV solutions to the CMB equations are complementary to, rather than replacements for, each other, as comparisons of their results reveal uncertainties that are not otherwise evident.Implications:?Organic markers can be measured on currently acquired PM2.5 filter samples by thermal methods. These markers can complement element, ion, and carbon fraction measurements from long-term speciation networks. Applying the positive matrix factorization and effective variance solutions for the chemical mass balance equations provides useful information on the accuracy of the source contribution estimates. Nonpolar compounds need to be complemented with polar compounds to better apportion cooking and secondary organic aerosol contributors. 相似文献
49.
Runzhi Gong Tim C. Keener 《Journal of the Air & Waste Management Association (1995)》2013,63(6):864-872
The effects of water vapor on binary vapor adsorption of toluene and methylene chloride by activated carbon were investigated on a bench-scale experimental system. Three levels of relative humidity (15, 65 and 90 percent) in conjunction with different concentrations of individual adsorbates (from 400 to 1200 ppmv) were tested by tracing the breakthrough curves of each adsorbate eluted from a fixed-bed adsorber. The adsorption capacities of the activated carbon tested for each adsorbate under the various conditions were obtained from calculations based on area integration of the breakthrough curves. It was found that with increasing relative humidity, the shape of breakthrough curves was asymmetrically distorted and the width of the breakthrough curves was broadened for toluene and steepened for methylene chloride. The adsorption capacities for both toluene and methylene chloride were decreased with the increase of relative humidity. The magnitude of the effect of water vapor is greater at the lower toluene concentration and at the higher concentration of methylene chloride. The mechanisms of water vapor influence on the process of multicomponent vapor adsorption are discussed. 相似文献
50.