Passive air sampling for persistent organic pollutants: introductory remarks to the special issue

There have been a number of developments in the need, design and use of passive air samplers (PAS) for persistent organic pollutants (POPs). This article is the first in a Special Issue of the journal to review these developments and some of the data arising from them. We explain the need and benefit of developing PAS for POPs, the different approaches that can be used, and highlight future developments and needs.     

Relationship between blood concentrations of heavy metals and cytogenetic and endocrine parameters among subjects involved in cleaning coastal areas affected by the 'Prestige' tanker oil spill

The sinking of the 'Prestige' oil tanker in front of the Galician coast (NW of Spain) in November 2002 offered a unique opportunity to analyze intermediate cytogenetic and endocrine effects among people exposed to the complex mixture of substances that oil constitutes, including several toxic heavy metals. In this work we evaluated the relationship between exposure to heavy metals (blood concentrations of aluminium, cadmium, nickel, lead and zinc) and genotoxic parameters (sister chromatid exchanges, micronucleus test and comet assay) or endocrine parameters (plasmatic concentrations of prolactin and cortisol) in subjects exposed to 'Prestige' oil during cleaning tasks developed after the spillage. Concentrations of lead were significantly related to the comet assay even after adjusting by age, sex and smoking. Cortisol concentrations were significantly influenced by aluminium, nickel (both, inversely) and cadmium (positively). Women had clearly higher concentrations of prolactin and cortisol, even when adjusting by age, smoking, cadmium, aluminium or nickel. Plasmatic cortisol was jointly influenced by gender, smoking and aluminium or nickel (all p<0.05). In women there was a strong relationship between concentrations of cadmium and prolactin (beta=0.37, p=0.031). When the effects of cadmium, aluminium and nickel on cortisol were simultaneously assessed, only the latter two metals remained statistically significant. Among parameters analysed, cortisol appeared to be the most sensitive to the effects of metal exposure. Plasma levels of cortisol deserve further evaluation as a potentially relevant biomarker to assess the effects of exposure to heavy metals.     

Copper-ligand complex for the decolorization of synthetic dyes

The reaction system containing Cu(II), hydrogen peroxide and D-arabinono-1,4-lactone was found to be effective in the decolorization and reduction of toxicity of azo, thiazine-, triphenylmethane- and anthraquinone-based synthetic dyes. More than 85% decolorization was obtained with 100ppm Acridine Orange, Azure B, Chicago Sky Blue 6B, Crystal Violet, Evans Blue, Poly B-411, Reactive Blue 2, Reactive Blue 5, and Remazol Brilliant Blue R incubated for 24h in the presence of 10mM CuSO(4), 20mM D-arabinono-1,4-lactone and 80 mM H(2)O(2). The rate of decolorization was not affected by pH in the range of 3-9. The rapid decolorization was accompanied by a fast decomposition of H(2)O(2) in the reaction mixture and by a fast production of hydroxyl radicals.     

Ranking and selecting dangerous crash locations: correcting for the number of passengers and Bayesian ranking plots

INTRODUCTION: In this paper a sensitivity analysis is performed to investigate how big the impact would be on the current ranking of crash locations in Flanders (Belgium) when only taking into account the most serious injury per crash instead of all the injured occupants. RESULTS: Results show that this would lead to a different selection of 23.8% of the 800 sites that are currently considered as dangerous. CONCLUSIONS: Considering this impact quantity, the researchers want to sensitize government that giving weight to the severity of the crash can correct for the bias that occurs when the number of occupants of the vehicles are subject to coincidence. Additionally, probability plots are generated to provide policy makers with a scientific instrument with intuitive appeal to select dangerous road locations on a statistically sound basis. Impact on industry Considering the impact quantity of giving weight to the severity of the crash instead of to all the injured occupants of the vehicle on the ranking of crash sites, the authors want to sensitize government to carefully choose the criteria for ranking and selecting crash locations in order to achieve an enduring and successful traffic safety policy. Indeed, giving weight to the severity of the crash can correct for the bias that occurs when the number of occupants of the vehicles are subject to coincidence. However, it is up to the government to decide which priorities should be stressed in the traffic safety policy. Then, the appropriate weighting value combination can be chosen to rank and select the most dangerous crash locations. Additionally, the probability plots proposed in this paper can provide policy makers with a scientific instrument with intuitive appeal to select dangerous road locations on a statistically sound basis. Note that, in practice, one should not only rank the crash locations based on the benefits that can be achieved from tackling these locations. Future research is also needed to incorporate the costs of infrastructure measures and other actions that these crash sites require in order to enhance the safety on these locations. By balancing these costs and benefits against each other, the crash locations can then be ranked according to the order in which they should be prioritized.     

A discourse-analytical perspective on sustainability assessment: interpreting sustainable development in practice

Sustainable development is a ubiquitously used concept in public decision-making: it refers to an ideal vision of global society where human development and environmental quality go hand in hand. Logically, any decision-supporting process aiming at facilitating and steering society toward a sustainable future then seems desirable. Assessing the sustainability of policy decisions is, however, influenced by what sustainable development is believed to entail, as different discourses coexist under the umbrella of the sustainable development meta-discourse. This paper proposes a typology of sustainable development discourses, and, subsequently, applies a discourse-analytical lens on two practical cases of sustainability assessment in different institutional and geographical contexts (in Belgium and in Benin). The results indicate that sustainability assessments tend to be influenced mainly by the consensual ‘sustainable development as integration’ discourse, while also providing a forum for dialogue between different discourses. The results shed light on context-specific discursive and institutional dynamics for the development and application of sustainability assessment. Acknowledging these dynamics as well as sustainable development’s inherent interpretational limits can lead to an improved use of sustainable development as a decision-guiding strategy.     

洞庭湖流域分布式水文模型

流域出口径流观测序列是水文模型参数率定重要依据,不受水文站控制区域的模型应用是水文研究关注点之一。首先根据水文站观测资料建立洞庭湖流域四水控制站之上基于水文响应单元的分布式水文模型,在此基础上结合实验、同质移植和虚拟水库等方法,将分布式水文模型拓展到包含无径流站控制区域的丘陵区间和平原圩垸区,最终实现了洞庭湖全流域水文过程模拟。结果表明:在较完备土壤、地形、土地利用等空间数据支持下,通过合理的流域划分和水文响应单元定义,建立的流域分布式水文模型可以较好地在水文响应单元尺度反应降水发生后蒸散、地表径流、土壤和地下水的响应特征。而基于观测实验及基流分割等方法获取的关键水文过程特征对模型参数优化的认识,可以提高模型参数率定效率,在较少优化迭代运算后既可使月径流模拟的效率系数NSE和确定性系数R²值高于0.81(日过程高于0.62)。借助参数同质移植和虚拟水库解决了区间和圩垸区无控制站区域水文过程模拟。在全流域水文过程的模拟中,基流指数和蒸散比例与实际过程具有较好的一致性。说明相关参数较好地反映了其物理机制,具备在相似气候及下垫面条件区域进行同质移植的基础,圩垸区径流交换采用虚拟水库的处理方式也合理可行。     

Wildlife impacts and vulnerable livelihoods in a transfrontier conservation landscape

Interactions between humans and wildlife resulting in negative impacts are among the most pressing conservation challenges globally. In regions of smallholder livestock and crop production, interactions with wildlife can compromise human well-being and motivate negative sentiment and retaliation toward wildlife, undermining conservation goals. Although impacts may be unavoidable when human and wildlife land use overlap, scant large-scale human data exist quantifying the direct costs of wildlife to livelihoods. In a landscape of global importance for wildlife conservation in southern Africa, we quantified costs for people living with wildlife through a fundamental measure of human well-being, food security, and we tested whether existing livelihood strategies buffer certain households against crop depredation by wildlife, predominantly elephants. To do this, we estimated Bayesian multilevel statistical models based on multicounty household data (n = 711) and interpreted model results in the context of spatial data from participatory land-use mapping. Reported crop depredation by wildlife was widespread. Over half of the sample households were affected and household food security was reduced significantly (odds ratio 0.37 [0.22, 0.63]). The most food insecure households relied on gathered food sources and welfare programs. In the event of crop depredation by wildlife, these 2 livelihood sources buffered or reduced harmful effects of depredation. The presence of buffering strategies suggests a targeted compensation strategy could benefit the region's most vulnerable people. Such strategies should be combined with dynamic and spatially explicit land-use planning that may reduce the frequency of negative human–wildlife impacts. Quantifying and mitigating the human costs from wildlife are necessary steps in working toward human–wildlife coexistence.     

Rapid assessment of insect pollination services to inform decision-making

Pollinator declines have prompted efforts to assess how land-use change affects insect pollinators and pollination services in agricultural landscapes. Yet many tools to measure insect pollination services require substantial landscape-scale data and technical expertise. In expert workshops, 3 straightforward methods (desk-based method, field survey, and empirical manipulation with exclusion experiments) for rapid insect pollination assessment at site scale were developed to provide an adaptable framework that is accessible to nonspecialist with limited resources. These methods were designed for TESSA (Toolkit for Ecosystem Service Site-Based Assessment) and allow comparative assessment of pollination services at a site of conservation interest and in its most plausible alternative state (e.g., converted to agricultural land). We applied the methods at a nature reserve in the United Kingdom to estimate the value of insect pollination services provided by the reserve. The economic value of pollination services provided by the reserve ranged from US$6163 to US$11,546/year. The conversion of the reserve to arable land would provide no insect pollination services and a net annual benefit from insect-pollinated crop production of approximately $1542/year (US$24∙ha^–1∙year^–1). The methods had wide applicability and were readily adapted to different insect-pollinated crops: rape (Brassica napus) and beans (Vicia faba) crops. All methods were rapidly employed under a low budget. The relatively less robust methods that required fewer resources yielded higher estimates of annual insect pollination benefit.     

Bio‐Based Poly(3-hydroxybutyrate)/Thermoplastic Starch Composites as a Host Matrix for Biochar Fillers

Journal of Polymers and the Environment - Biochar is an excellent, but less-used candidate to serve as an alternative filler in poly(3-hydroxybutyrate) (PHB)-based composites. Increasing amounts of...     

The need to look beyond the production and provision of relief seed: experiences from southern Sudan

Free distribution of seeds in selected areas of southern Sudan has been widespread as a way of increasing food security. Field research in areas targeted for seed relief found that farmer seed systems continue to meet the crop and varietal needs of farmers even following the 1998 famine. Donor investments in seed multiplication of improved sorghum have not been sustained due to a lack of effective demand for the improved seed beyond that created by the relief agencies. The article argues that rather than imposing outside solutions, whether through seed provisioning or seed production enterprises, greater attention needs to be given to building on the strengths of existing farmer systems and designing interventions to alleviate the weaknesses. The case is made to support dynamically the process of farmer experimentation through the informed introduction of new crops and varieties that can potentially reinforce the strength and diversity of local cropping systems.