全文获取类型
收费全文 | 520篇 |
免费 | 11篇 |
国内免费 | 4篇 |
专业分类
安全科学 | 29篇 |
废物处理 | 26篇 |
环保管理 | 67篇 |
综合类 | 45篇 |
基础理论 | 126篇 |
污染及防治 | 163篇 |
评价与监测 | 39篇 |
社会与环境 | 30篇 |
灾害及防治 | 10篇 |
出版年
2023年 | 7篇 |
2022年 | 10篇 |
2021年 | 10篇 |
2020年 | 8篇 |
2019年 | 10篇 |
2018年 | 12篇 |
2017年 | 13篇 |
2016年 | 17篇 |
2015年 | 16篇 |
2014年 | 16篇 |
2013年 | 47篇 |
2012年 | 26篇 |
2011年 | 43篇 |
2010年 | 29篇 |
2009年 | 30篇 |
2008年 | 29篇 |
2007年 | 33篇 |
2006年 | 35篇 |
2005年 | 33篇 |
2004年 | 19篇 |
2003年 | 14篇 |
2002年 | 17篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 6篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1985年 | 2篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1974年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有535条查询结果,搜索用时 15 毫秒
131.
Jürgen Breitung Drik Bruns-Nagel Klaus Steinbach Karl-Heinz Blotevogel Tom Gorontzy Ralf Dillert Ralf Winterberg Heiko Stoffers Rainer Haas Marco Müller Peter Asbach Lothar Kaminski Eberhard von Löw Diethard Gemsa 《Environmental Sciences Europe》1996,8(5):249-254
The formation of aromatic amines was investigated using a summarized test (NEDA-test) during the composting of 2,4,6-trinitrotoluene (TNT) contaminated soil. In this test, the aromatic amines were diazolated and then coupled to N-1-Naphthyl-ethylenediamine-dihydrochloride (NEDA) to yield an azo dye which can be monitored photometrically. The test was calibrated for known TNT-metabolites with an active amine-group. Liquid samples from composting- and liquid-culture-experiments were analyzed by HPLC for these known metabolites. Moreover, the samples were monitored by the NEDA-test and the expected extinction of the TNT-metabolites found with amine function were extrapolated with the help of calibration curves. It was shown that substantial differences are obvious between the monitored and extrapolated values. After separation into polar and non-polar aromatic amines, it became clear that these differences are made by the polar aromatic amines. Polar aromatic amines, which are not detectable by presently available analytical tests, were generated during the composting of TNT-contaminated soils. Contaminated stagnant water, which was generated during anaerobization of a compost prephase, was treated aerobically for 70 days in a biofermenter. During this treatment TNT and its known metabolites were eliminated almost entirely. Simultaneously, the toxicity in the Lumis Tox-test decreased drastically. In striking contrast, the sum of aromatic amines decreased only to a minor extent. Moreover, the percentage of polar compounds from total amount of aromatic amines increased drastically from 48% to more than 95%. At present, the chemical identification of these polar compounds is still missing and is the object for further research. 相似文献
132.
133.
Gaseous emissions from animal manure storage facilities can contribute to global greenhouse gas inventories. Biogas fluxes were measured for one year from a 2-ha anaerobic lagoon that received waste from a 10500-head swine (Sus scrofa) finishing operation in southwestern Kansas. During 2001, ebullition of biogas was measured continuously by using floating platforms equipped with gas-collection domes. Periodically, the composition of the biogas was determined by using gas chromatography. Detailed records of feed quality and quantity and animal weights and gains also were obtained to determine the carbon budget of the facility (barns and lagoon). Flux of biogas was very seasonal, with peak emission (18.7 mol m(-2) d(-1)) occurring in early June. Nearly 50% of the annual biogas losses occurred during a 30-d period beginning on day of year (DOY) 146. Flux patterns suggest that the start of the high biogas production period was governed by temperature, while the decline in production in mid-June was caused by substrate limitations. Average biogas composition was 0.71 L CH4 L(-1). The quantity of CH4 released from the lagoon was 86.3 Mg yr(-1), which represents about 38 g of CH4 per kg of animal weight gain. The average flux density of biogas from the lagoon was 382 mol m(-2) yr(-1) or 728 mol yr(-1) per resident animal where the resident animal population was 10500. Flux rates of CH4 were 1.7 to 3.4 times less than predictions made with Intergovernmental Panel on Climate Change (IPCC) models. Additional research is needed on the carbon budgets of other animal feeding operations so that better estimates of greenhouse gas emissions can be determined. 相似文献
134.
Tom Van Remmen 《Waste management (New York, N.Y.)》1998,18(6-8)
After many years of research and debate, in August of 1997 the United States Environmental Protection Agency (EPA) issued New Source Performance Standards (NSPS) and Emission Guidelines (EG) for medical/infectious waste incinerators in the United States. These new emissions and operational standards establish considerably more restrictive limitations on air emissions for medical/infectious waste incinerators and will undoubtedly have a significant impact on the over 2300 hospitals presently operating an incinerator on-site. This paper will explore the options available to these facilities, and those facilities which may be considering installation of an incinerator, relative to achieving compliance with the NSPS and EG for medical/infectious waste incinerators. 相似文献
135.
Ludmila Wilhelmová Milan Tomášek Karel Štukheil 《Environmental monitoring and assessment》1995,34(2):145-149
The results of measurements of Krypton-85 (85Kr) concentrations in the ground-level air of Prague between 1983 and 1992 are presented and time-related changes analysed. The long-term trend in activity level of 85Kr has been steadily increasing with a growth rate of 0.04 Bq.m–3 (STP) per year. Some peaks of 85Kr activity were observed due to the influence of undispersed radioactive plumes coming from distant sources. Short-term variations within a typical range of concentrations from 0.61 to 1.25 Bq.m–3 (STP) were found to be seasonally dependent, with the maximum occurring in spring. 相似文献
136.
Nitrogen (N) pollution is a growing concern in forests of the greater Sierra Nevada, which lie downwind of the highly populated
and agricultural Central Valley. Nitrogen content of Letharia vulpina tissue was analyzed from 38 sites using total Kjeldahl analysis to provide a preliminary assessment of N deposition patterns.
Collections were co-located with plots where epiphytic macrolichen communities are used for estimating ammonia (NH3) deposition. Tissue N ranged from 0.6% to 2.11% with the highest values occurring in the southwestern Sierra Nevada (range:
1.38 to 2.11). Tissue N at 17 plots was elevated, as defined by a threshold concentration of 1.03%. Stepwise regression was
used to determine the best predictors of tissue N from among a variety of environmental variables. The best model consisted
only of longitude (r
2 = 0.64), which was reflected in the geographic distribution of tissue values: the southwestern Sierra Nevada, the high Sierras
near the Tahoe Basin, and the Modoc Plateau, are three apparent N hotspots arranged along the tilted north–south axis of the
study area. Withholding longitude and latitude, the best regression model suggested that NH3 estimates and annual number of wetdays interactively affect N accumulation (r
2 = 0.61; % N ∼ NH3 + wetdays + (NH3 × wetdays)). We did not expect perfect correspondence between tissue values and NH3 estimates since other N pollutants also accumulate in the lichen thallus. Additionally, other factors potentially affecting
N content, such as growth rate and leaching, were not given full account. 相似文献
137.
Indoor and outdoor concentrations of PM2.5 trace elements at homes, preschools and schools in Stockholm, Sweden 总被引:1,自引:0,他引:1
Molnár P Bellander T Sällsten G Boman J 《Journal of environmental monitoring : JEM》2007,9(4):348-357
Fine particles (PM2.5) were sampled indoors and outdoors at 40 sampling sites; in ten classrooms in five schools, at ten preschools and 20 non-smoking homes, in three communities in Stockholm, Sweden, during nine 2-week periods. Each sampling site was sampled twice, once during winter and once during spring. The samples were analysed for elemental concentrations using X-ray fluorescence (XRF) spectroscopy. In all locations significantly higher outdoor concentrations were found for elements that are related to long-range transported air masses (S, Ni, Br and Pb), while only Ti was higher indoors in all locations. Similar differences for S, Br and Pb were found in both seasons for homes and schools. In preschools different seasonal patterns were seen for the long-range transported elements S, Br and Pb and the crustal elements Ti, Mn and Fe. The indoor/outdoor ratios for S and Pb suggest an outdoor PM2.5 particle net infiltration of about 0.6 in these buildings. The community located 25 km from the city centre had significantly lower outdoor concentrations of elements of crustal or traffic origin compared with the two central communities, but had similar levels of long-range transported elements. Significant correlations were found between PM2.5 and most elements outdoors (rs = 0.45-0.90). Copper levels were found to correlate well (rs = 0.64-0.91) to the traffic marker NO2 during both winter and spring in all locations. Copper may be a suitable elemental marker for traffic-related aerosols in health studies in areas without other significant outdoor Cu sources. 相似文献
138.
Marc D. Coleman Matthew Ellison Rod A. Robinson Tom D. Gardiner Thomas O. M. Smith 《Journal of the Air & Waste Management Association (1995)》2013,63(9):1070-1078
When annual average PM2.5 (fine particulate matter sized 2.5 microns and less) data for 2005 became available in April 2006 and the 3-yr average PM2.5 concentration in an area just north of the Houston Ship Channel reached 15.0 µg/m3, the Texas Commission on Environmental Quality (TCEQ) initiated daily collection of quartz fiber as well as Teflon PM2.5 filter samples for chemical speciation analysis. The purpose of the chemical speciation analysis was to use the speciation data, together with meteorological data and hourly TEOM (tapered element oscillating microbalance) PM2.5 mass data, to identify the causes of the high PM2.5 concentrations affecting the monitoring site and the neighborhood. The ultimate purpose was to target emission reduction efforts to sources contributing to the high measured PM2.5 concentrations. After a year of data collection, it was recognized that a specific source, unpaved driveways and loading areas along the Ship Channel and dirt tracked onto Clinton Drive, the main artery running east-west north of the Ship Channel, were the primary cause for the Clinton Drive site's measuring PM2.5 concentrations significantly higher than other sites in Houston. The source characterization and remediation steps that have led to sustained reduced concentrations are described in this paper.
Implications: With PM2.5 exceedances it can be essential to have or develop chemical speciation data as part of the process of identifying the source types causing exceedances of an annual standard. Positive matrix factorization (PMF) analysis proved to be a powerful tool that identified the two locally emitted species contributing to exceedances, which did not occur at other sites in the region. They were calcium sulfate (gypsum), an industrial by-product, and soil minerals. Other data analysis approaches were necessary to distinguish North African dust events, which PMF failed to identify. 相似文献
139.
In situ experiment to determine advective-diffusive controls on solute transport in a clay-rich aquitard 总被引:1,自引:0,他引:1
Solute transport in clay-rich aquitards is characterized as molecular diffusion- or advection-dominated based on the Péclet number (P(e)). However, few field-based measurements of the coefficient of molecular diffusion (D(e)) exist, and none with a range of advection- or diffusion-dominated conditions in the same aquitard. In this long-term field experiment, standing water in a recovering well was spiked with deuterium ((2)H), then water-level recovery and δ(2)H values were monitored as the well returned to static conditions over 1054 days. After a second (2)H spike, water levels and δ(2)H values were monitored to day 1644 while under near static conditions. Modeling of the second spike was used to define the D(e) of (2)H as (3-4)× 10(-10)m(2)s(-1) for an accessible porosity of 0.31. Reservoir concentrations from the initial spike were modeled to define the transition from advection- to diffusion-dominated transport. This occurred after 200 days, consistent with a transition in P(e) from <1 to >1 when the length term is taken as the radial extent of the tracer plume (normalized concentration <0.05). This study verifies plume extent as the characteristic length term in the calculation of P(e) and demonstrates the transition from advection- to diffusion-dominated transport as the value of P(e) decreases below unity. 相似文献
140.
Soudek P Petrová S Benešová D Dvořáková M Vaněk T 《Journal of environmental radioactivity》2011,102(6):598-604
Hydroponicaly cultivated plants were grown on medium containing uranium. The appropriate concentrations of uranium for the experiments were selected on the basis of a standard ecotoxicity test. The most sensitive plant species was determined to be Lactuca sativa with an EC50 value about 0.1 mM. Cucumis sativa represented the most resistant plant to uranium (EC50 = 0.71 mM). Therefore, we used the uranium in a concentration range from 0.1 to 1 mM.Twenty different plant species were tested in hydroponic solution supplemented by 0.1 mM or 0.5 mM uranium concentration. The uranium accumulation of these plants varied from 0.16 mg/g DW to 0.011 mg/g DW. The highest uranium uptake was determined for Zea mays and the lowest for Arabidopsis thaliana. The amount of accumulated uranium was strongly influenced by uranium concentration in the cultivation medium. Autoradiography showed that uranium is mainly localized in the root system of the plants tested. Additional experiments demonstrated the possibility of influencing the uranium uptake from the cultivation medium by amendments. Tartaric acid was able to increase uranium uptake by Brassica oleracea and Sinapis alba up to 2.8 times or 1.9 times, respectively. Phosphate deficiency increased uranium uptake up to 4.5 times or 3.9 times, respectively, by Brassica oleracea and S. alba. In the case of deficiency of iron or presence of cadmium ions we did not find any increase in uranium accumulation. 相似文献