Evaluation of the stability of arsenic immobilized by microbial sulfate reduction using TCLP extractions and long-term leaching techniques

An investigation was conducted to evaluate the stability or leachability of arsenic immobilized by microbial sulfate reduction. Anoxic solid-phase samples taken from a bioreactor previously used to treat metal and As contaminated water using sulfate reducing bacteria (SRB) were subjected to the toxicity characteristic leaching procedure (TCLP) and long-term column leaching tests. The results from TCLP experiments showed that the concentration of As leached from solid-phase sulfide material (SSM) samples after an 18 h extraction time was <300 microgl(-1), which is below the current maximum Australian TCLP leachate value for As, and thus would not be characterized as a hazardous waste. In terms of percent total As leached, this was equivalent to <8.5% for SSM samples initially containing 61.3 mgkg(-1) As. The levels of As extracted by the TCLP was found to be significantly lowered or underestimated in the presence of dissolved oxygen, with As concentrations increasing with decreasing headspace-to-leachant volume ratios. The concentration of As was also consistently higher in nitrogen purged extractions compared to those performed in air. This was attributed to the dissolution of Fe-sulfide precipitates and subsequent oxidation of Fe(II) ions and precipitation of ferric(hydr)oxides, resulting in the adsorption of soluble As and corresponding decrease in As concentrations. According to the experimental data, it is recommended that TCLP tests for As leachability should be performed at least in zero-headspace vessels or preferably under nitrogen to minimize the oxidation of Fe(II) to ferric(hydr)oxides. In long-term leaching studies (approximately 68 days), it was found that the low solubility of the SSM ensured that rate of release of As was relatively slow, and the resulting leachate concentrations of As were below the current Australian guideline concentration for arsenic in drinking water.     

Novel system of communication in crickets originated at the same time as bat echolocation and includes male-male multimodal communication

The Science of Nature - The capability of producing sounds and vibrations is well known in insects and is thought to be a form of intra- and interspecific communication. Sounds and vibrations are...     

Human dimensions of environmental change in small island developing states: some common themes

Regional Environmental Change - Climate change and its consequence of sea level rise are major issues for small island developing states (SIDS), as they worsen many other pressures on their people...     

Land Use for Military Training in the UK: The Current Situation,Likely Developments and Possible Alternatives

This paper describes the current pattern of land ownership for military training in the UK. The main component-armytraining areas-is considered in detail. Recent historical trends are reviewed in the context of changes in force size and weapons systems.Problems and benefits arising from the primary use of land for military training are defined. Relevant literature is reviewed. Comparisons are made with training systems in other countries, in particular the USA, the Netherlands,Switzerland, France and Australia. Recent developments in government policy are described and analysed. Possible future requirements are explored. This information is used to construct an argument that the current training system in the UK is outmoded and unsustainable. The authors contend that there is a need for a strategic review of military training, encompassing a thorough assessment of alternatives to traditional live firing on dedicated training areas.     

PREDICTION OF STREAM TEMPERATURE IN FORESTED WATERSHEDS1

ABSTRACT: Removal of streamside vegetation changes the energy balance of a stream, and hence its temperature. A common approach to mitigating the effects of logging on stream temperature is to require establishment of buffer zones along stream corridors. A simple energy balance model is described for prediction of stream temperature in forested headwater watersheds that allows evaluation of the performance of such measures. The model is designed for application to “worst case” or maximum annual stream temperature, under low flow conditions with maximum annual solar radiation and air temperature. Low flows are estimated via a regional regression equation with independent variables readily accessible from GIS databases. Testing of the energy balance model was performed using field data for mostly forested basins on both the west and east slopes of the Cascade Mountains, and was then evaluated using the regional equations for low flow and observed maximum reach temperatures in three different east slope Cascades catchments. A series of sensitivity analyses showed that increasing the buffer width beyond 30 meters did not significantly decrease stream temperatures, and that other vegetation parameters such as leaf area index, average tree height, and to a lesser extent streamside vegetation buffer width, more strongly affected maximum stream temperatures.     

Science–policy interactions in Austrian,Dutch, and Swiss climate policy: a comparative account

Scientific expertise plays an important role in the complex field of climate policy. Consequently, science–policy interactions have been institutionalized in many countries. However, science–policy arenas vary considerably across countries. Scholars mainly attribute these differences to the influence of specific political cultures. The literature has primarily compared science–policy arenas of countries with diverging political cultures, whereas comparisons of countries with similar political cultures are rare. The latter is especially true for neo-corporatist cultures. Against this background, we compare the climate science–policy arenas of three neo-corporatist countries, Austria, the Netherlands, and Switzerland. Conceptually, we draw on the literature regarding politico-cultural imprints in science–policy arenas. We operationalize national science–policy arenas along four dimensions: the knowledge actors, the organizational formats, the styles of science–policy interactions, and their transparency and visibility. Overall, the three arenas reveal many similarities and much fewer differences. Most similarities correspond to neo-corporatist patterns. However, some similarities consistently deviate from neo-corporatist patterns. Interestingly, almost all differences between the countries match national variations of neo-corporatism. In light of these observations and the specific problem structure of climate policy, we develop research questions to investigate potential explanations for correspondence to and deviation from neo-corporatist patterns.     

Indoor/ambient residential air toxics results in rural western Montana

Indoor and ambient concentrations of 21 volatile organic compounds (including 14 hazardous air pollutants) were measured in the homes of nearly 80 western Montana (Missoula) high school students as part of the 'Air Toxics Under the Big Sky' program during the 2004/2005 and 2005/2006 school years. Target analytes were measured using low flow air sampling pumps and sorbent tubes, with analysis of the exposed samples by thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS). The results reported here present the findings of the first indoor/ambient air toxics monitoring program conducted in a semi-rural valley location located in the Northern Rocky Mountain/Western Montana region. Of all of the air toxics quantified in this study, toluene was found to be the most abundant compound in both the indoor and ambient environments during each of the two school years. Indoor log-transformed mean concentrations were found to be higher when compared with ambient log-transformed mean concentrations at P < 0.001 for the majority of the compounds, supporting the results of previous studies conducted in urban areas. For the air toxics consistently measured throughout this program, concentrations were approximately six times higher inside the student's homes compared to those simultaneously measured directly outside their homes. For the majority of the compounds, there were no significant correlations between indoor and ambient concentrations.