Physical and chemical properties of feedlot pen surfaces located on moderately coarse- and moderately fine-textured soils in southern Alberta

Southern Alberta has the highest density of feedlot cattle in Canada, and there is a concern that leaching of water and contaminants may be greater for feedlots located on coarser-textured than finer-textured soils. Our objective was to determine if infiltration and leaching were greater for a 4-yr-old feedlot located on a moderately coarse-textured (MC) soil compared with two feedlots located on moderately fine-textured (MF) soils (5- and 52-yr-old pens). Various soil physical properties of feedlot pen surfaces were measured, including field-saturated hydraulic conductivity (K(fs)) and near-saturated hydraulic conductivity at -0.9 and -3.9 cm water potential. Selected chemical properties of feedlot soil layers were measured, as well as the chloride content of the soil profile (0-100 cm). Mean K(fs), K(-0.9), and K(-3.9) values were not significantly (P > 0.10) greater at the MC site than the two MF sites, indicating no evidence of greater infiltration on coarser-textured soils. In addition, mean K(fs), K(-0.9), and K(-3.9) values of soils within feedlot pens at all three sites were significantly (P < or = 0.10) reduced by 46 to 78% compared with soil outside the pens. Depth of chloride accumulation was greatest at the 52-yr-old feedlot on MF soil (60-70 cm), followed by 4-yr-old feedlot on MC soil (40-50 cm) and 5-yr-old feedlot on MF soil (30-40 cm). Visual inspection determined that the black interface layer formed within 2 mo of cattle stocking at all three sites.     

Effects of amended compost on mobility and uptake of arsenic by rye grass in contaminated soil

Arsenic poses a major environmental and human health problem because of its carcinogenic nature and effect on the ecosystem. Therefore, a cost effective and socially acceptable technique is needed for its remediation. The effect of different combinations of compost amended with zeolite and/or iron oxide (up to 20% w/w) was tested on a contaminated soil with high arsenic levels (34470 mg kg(-1)). The bioavailability of arsenic was determined in terms of uptake by rye grass (Lolium perenne L.) under greenhouse experimental conditions. The results indicated that the arsenic concentrations in the rye grass was reduced to 2 mg kg(-1) dry weight by using 15% compost with 5% iron oxide and 15% compost with 5% zeolite. Less than 0.01% of the total arsenic content in the soil was being taken up by the plants. Both treatments were effective in establishing significantly higher plant growth on the contaminated soil compared to other treatments. The results from sequential extraction tests indicated that in all the compost-amended soils, there was a reduction in the soluble fraction (10-37%). Arsenic in soil was examined using Scanning Electron Microscopy coupled with Energy Dispersive X-ray spectroscopy. The results indicated that arsenic was distributed mostly within the matrix of iron and oxygen in treated samples. Amongst various treatment mixtures tested, high percent of compost (15%) with zeolite (5%) and/or iron oxide (5%) is effective in reducing arsenic uptake by plants and establish re-vegetation on the contaminated soil.     

Water resources issues of small island developing states

The water resources of most small island developing states (SIDS) are often very limited and require special consideration to ensure that they are developed and managed in a sustainable manner. Many small islands, typically located in the humid tropics, have no surface water resources and rely on limited groundwater resources in the form of thin freshwater lenses. The exposed location of small islands makes them particularly vulnerable to natural disasters such as cyclones, floods and droughts. Pollution from population centres and from agricultural and other activities is an increasing problem. This article provides an overview of the water resources of small islands, and the main problems and issues related to water resources. Some suggested solutions, based on practical experiences, are offered for water resource assessment and monitoring programmes, and water resource development. Water resource policy, planning and management issues are also addressed, and suggested approaches for resolving some of the major water resource problems presented.     

Initial Adjustments Within a New River Channel: Interactions Between Fluvial Processes, Colonizing Vegetation, and Bank Profile Development

A conceptual model of the morphological development of the riparian margins of newly cut river channels is presented, suggesting early feedbacks between vegetation growth and bank form. To test the model, observations of long and cross profiles, bank sediment and seed deposition, and bank vegetation development were collected over the first 2 years of river flows through a reach of the River Cole, West Midlands, UK. The newly created channel had a sinuous planform and varying asymmetric trapezoidal cross section in sympathy with the planform. No imposed bedforms or bank reseeding were included in the design. Over the 2 years, development of bedforms was rapid, with bed sediment sorting and bank profile adjustment occurring more steadily and progressively. Six classes of bank profile were identified by the end of the study period, illustrating close associations with sediment aggradation, vegetation colonization, and growth patterns. Vegetation colonization of the banks was seeded predominantly from local sources during the summer and from hydrochory (transport by the river) during the winter. Colonizing vegetation on the riverbanks appeared to act as a significant propagule source by the second summer and as an increasingly important roughness element, trapping both propagules and sediment, within the second year and providing early feedback into bank evolution. As a result, the time required for riparian margin development in the conceptual model was found to be considerably longer than observed in the study river. In addition, the role of surface wash/bank failure in modifying the bank profile and transporting seeds onto the upper bank face during the first year of bank development was found to be important in initiating rapid bank vegetation colonization and surface stabilization. This set of processes had not been incorporated in the initial conceptual model. In relation to channel restoration, this research illustrates that in small temperate rivers of modest energy the provision of an initial, sinuous corridor is sufficient to induce rapid development of fluvial features and vegetation cover without the need to construct bed forms or to seed the banks.     

Perceptions of Species Abundance,Distribution, and Diversity: Lessons from Four Decades of Sampling on a Government-Managed Reserve

/ We examined data relative to species abundance, distribution, anddiversity patterns of reptiles and amphibians to determine how perceptionschange over time and with level of sampling effort. Location data werecompiled on more than one million individual captures or observations of 98species during a 44-year study period on the US Department of Energy's(DOE) Savannah River Site National Environmental Research Park (SRS-NERP) inSouth Carolina. We suggest that perceptions of herpetofaunal speciesdiversity are strongly dependent on level of effort and that land managementdecisions based on short-term data bases for some faunal groups could resultin serious errors in environmental management. We provide evidence thatacquiring information on biodiversity distribution patterns is compatiblewith multiyear spatially extensive research programs and also provide aperspective of what might be achieved if long-term, coordinated researchefforts were instituted nationwide.To conduct biotic surveys on government-managed lands, we recommend revisionsin the methods used by government agencies to acquire and report biodiversitydata. We suggest that government and industry employees engaged inbiodiversity survey efforts develop proficiency in field identification forone or more major taxonomic groups and be encouraged to measure the status ofpopulations quantitatively with consistent and reliable methodologies. Wealso suggest that widespread academic cooperation in the dissemination ofinformation on regional patterns of biodiversity could result byestablishment of a peer-reviewed, scientifically rigorous journal concernedwith status and trends of the biota of the United States. KEY WORDS: Abundance; Amphibian; Biodiversity; Distribution; Landmanagement; Reptile     

Heavy metal speciation in solid-phase materials from a bacterial sulfate reducing bioreactor using sequential extraction procedure combined with acid volatile sulfide analysis

Heavy metal mobility, bioavailability and toxicity depends largely on the chemical form of metals and ultimately determines potential for environmental pollution. For this reason, determining the chemical form of heavy metals and metalloids, immobilized in sludges by biological mediated sulfate reduction, is important to evaluate their mobility and bioavailability. A modified Tessier sequential extraction procedure (SEP), complemented with acid volatile sulfide (AVS) and simultaneous extracted metals (SEM) measurements, were applied to determine the partitioning of five heavy metals (defined as Fe, Ni, Zn and Cu, and the metalloid As) in anoxic solid-phase material (ASM) from an anaerobic, sulfate reducing bioreactor into six operationally defined fractions. These fractions were water soluble, exchangeable, bound to carbonates (acid soluble), bound to Fe-Mn oxides (reducible), bound to organic matter and sulfides (oxidizable) and residual. It was found that the distribution of Fe, Ni, Zn, Cu and As in ASM was strongly influenced by its association with the above solid fractions. The fraction corresponding to organic matter and sulfides appeared to be the most important scavenging phases of As, Fe, Ni, Zn and Cu in ASM (59.8-86.7%). This result was supported by AVS and SEM (Sigma Zn, Ni and Cu) measurements, which indicated that the heavy metals existed overwhelmingly as sulfides in the organic matter and sulfide fraction. A substantial amount of Fe and Ni at 16.4 and 20.1%, respectively, were also present in the carbonate fraction, while an appreciable portion of As (18.3%) and Zn (19.4%) was bound to Fe-Mn oxides. A significant amount of heavy metals was also associated with the residual fraction, ranging from 2.1% for Zn to 18.8% for As. Based on the average total extractable heavy metal (TEHM) values, the concentration of heavy metals in the ASM was in the order of Cu > Ni > Zn > Fe > As. If the mobility and bioavailability of heavy metals are assumed to be related to their solubility and chemical forms, and that they decrease with each successive extraction step, then the apparent mobility and bioavailability of these five heavy metals in ASM increase in the order of Cu < As < Ni < Fe < Zn. The SEM/AVS ratio was less than one in eight replicate ASM samples, indicating that the ASM was non-toxic with regards to having a low probability of bioavailable metals in the pore water.     

How well should laboratories perform in proficiency tests

The long-term performance of laboratories is examined using results from three proficiency testing programmes in the water and environmental monitoring sector. A medium term proficiency test pass rate of greater than approximately 75% is suggested as a minimum target for routine analysis to demonstrate fitness for purpose. This pass rate is proposed as a practical yardstick to be used by QA managers and accreditation bodies. This recommendation is contingent on a laboratory's continued and largely uninterrupted participation in a PT programme.