Challenges with tracing the fate and speciation of mine-derived metals in turbid river systems: implications for bioavailability

The fast-flowing and highly turbid Lagaip River (0.5–10 g/L suspended solids) in the central highlands of Papua New Guinea receives mine-derived metal inputs in both dissolved and particulate forms. Nearest the mine, metal concentrations in suspended solids were 360, 9, 90, 740 and 1,300 mg/kg for As, Cd, Cu, Pb and Zn, while dissolved concentrations were 2.7, 0.6, 3.1, 0.1 and 25 μg/L, respectively. This creates a significant metal exposure source for organisms nearer the mine. However, because the Lagaip River is diluted by a large number of tributaries, the extent to which mine-derived metals may affect biota in the lower catchments is uncertain. To improve our understanding of the forms of potentially bioavailable metals entering the lower river system, we studied the partitioning and speciation of metals within the Lagaip River system. Dissolved and particulate metal concentrations decreased rapidly downstream of the mine due to dilution from tributaries. As a portion of the particulate metal concentrations, the more labile dilute acid-extractable forms typically comprised 10–30 % for As and Pb, 50–75 % for Cu and Zn, and 50–100 % for Cd. Only dissolved Cd, Cu and Zn remained elevated relative to the non-mine-impacted tributaries (<0.03, 0.5 and 0.3 μg/L), but the concentrations did not appreciably change with increasing dilution downriver. This indicated that release of Cd, Cu and Zn was likely occurring from the more labile metal phases of the mine-derived particulates. Chelex-labile metal analyses and speciation modelling indicated that dissolved copper and lead were largely non-labile and likely complexed by naturally occurring organic ligands, while dissolved cadmium and zinc were predominantly present in labile forms. The study confirmed that mine-derived particulates may represent a significant source of dissolved metals in the lower river system; however, comparison with water quality guidelines indicates the low concentrations would not adversely affect aquatic life.     

A Simplified Method of Estimating Atmospheric Diffusion Parameters

Studies at Brookhaven National Laboratory have revealed reliable relationships among the statistical properties of the three-dimensional wind components. Combining these results with functions relating these wind statistics to atmospheric diffusion has produced a simplified system for estimating diffusion parameters from a variety of instrument arrangements. The system is described; examples of its application are given.     

Precipitator Gas Flow Distribution

An electrostatic precipitator, furnished on a 500-Mw tan-gentially-fired steam generator burning coal, was to collect 99.6% of the fly ash being generated in the furnace of this unit. Preliminary measurements indicated that the installation was not meeting its collection guarantee. Precipitator outlet flue dust distribution indicated that poor gas flow distribution might be one of the causes of the low performance. When observation ports were installed in the outlet flue to permit a direct visual evaluation of the problem, it was found that high velocity jets were present in the collecting electrodes, and that hopper sweepage was present. A model study along with velocity distribution measurements of the installation were authorized. Flow analysis indicated that the field and model correlated well. Extensive changes were made in the model, which eliminated or minimized the high velocity jets and hopper sweepage. After these changes were made in the field installation, it was able to achieve the required dust collection efficiency.     

Engineering and Economic Considerations In Fabric Filtration

The basic engineering and economic factors relative to fabric filtration systems are reviewed. Fabrication and erection costs, and maintenance costs are then discussed in greater depth.     

Nomograph for Field Checking Meter Calibrations on EPA-Type Stack Sampling Trains

In a typical "EPA train" for stack sampling, there are two meters, the dry gas meter and the orifice meter, which require periodic calibration. The controversy which presently exists over the required frequency of calibration is the result of using meters which rarely need calibration, but which have the potential of changing calibration at any time.     

Estimating Overall Sample Train Efficiency

A common part of many gas analyses using bubblers is to combine the contents of the first n-1 impingers and analyze them separate from the nth. The nth impinger, yielding as it should a nil result, confirms that all of the sample entering the train was caught and that the concentration calculated therefrom represents the “true” value.

Many a hapless analyst has found himself stuck with nonzero nth impingers on occasion. Bemgloath tb reject the whole test, the analyst will often report the concentration based on the total catch (with appropriate qualifiers, of course). Another common practice is to calculate the percentage of the total catch in the first n-1 impingers. Sometimes this is reported, erroneously, as the sampler efficiency. The true sampler efficiency cannot be known (if it is less than 100%) because the presence of sample in the last impinger indicates that some unknown amount has passed through the train entirely.     

Characterization of Sonic Devices Used for Cleaning Fabric Filters

ABSTRACT

Ozone reactivity scales play an important role in selecting which chemical compounds are used in products ranging from gasoline to pesticides to hairspray in California, across the United States and around the world. The California Statewide Air Pollution Research Center (SAPRC) box model that calculates ozone reactivity uses a representative urban atmosphere to predict how much additional ozone forms for each kilogram of compound emission. This representative urban atmosphere has remained constant since 1988, even though more than 25 years of emissions controls have greatly reduced ambient ozone concentrations across the United States during this time period. Here we explore the effects of updating the representative urban atmosphere used for ozone reactivity calculations from 1988 to 2010 conditions by updating the meteorology, emission rates, concentration of initial conditions, concentration of background species, and composition of volatile organic compound (VOC) profiles. Box model scenarios are explored for 39 cities across the United States to calculate the Maximum Incremental Reactivity (MIR) scale for 1,233 individual compounds and compound-mixtures. Median MIR values across the cities decreased by approximately 20.3% when model conditions were updated. The decrease is primarily due to changes in atmospheric composition ultimately attributable to emissions control programs between 1998 and 2010. Further effects were caused by changes in meteorological variables stemming from shifting seasons for peak ozone events (summer versus early fall). Lumped model species with the highest MIR values in 1988 experienced the greatest decrease in MIR values when conditions were updated to 2010. Despite the reduction in the absolute reactivity in the updated 2010 atmosphere, the relative ranking of the VOCs according to their reactivity did not change strongly compared to the original 1988 atmosphere. These findings indicate that past decisions about ozone control programs remain valid today, and the ozone reactivity scale continues to provide relevant guidance for future policy decisions even as new products are developed.

Implications: Updating the representative urban atmosphere used for the Maximum Incremental Reactivity (MIR) scale from 1988 to 2010 conditions caused the reactivity of 1223 individual compounds and combined mixtures to decrease by an average of 20.3% but the relative ranking of the VOCs was not strongly affected. This means that previous guidance about preferred chemical formulations to reduce ozone formation in cities across the United States remain valid today, and the MIR scale continues to provide relevant guidance for future policy decisions even as new products are developed.     

Technician Training in Environmental Health Science

In colleges and universities across the country, courses in ecology and environmental science are among the newest additions to the catalog. The goal of such courses is to make students aware of the environmental dilemma, a just and necessary goal. However, there is a need to do more than this. Jobs dealing with environmental protection are becoming more and more complex due to the recent passage of State and Federal legislation, which includes the Clean Air Act, the Amendments to the Water Pollution Control Act and the Occupational Safety and Health Act, just to name a few. Trained personnel are needed by industry and government. For this reason, in 1971, Middlesex County College initiated an Environmental Health Science Technology Program.     

Filtration Properties of Fly Ash from Fluidized Bed Combustion

Some of the features of the fluidized-bed combustion (FBC) process have a direct bearing on the particulate properties that most strongly influence filtering pressure drop. A laboratory program was conducted to experimentally determine the relative pressure drop characteristics of ashes from the TVA-EPRI 20-MW bubbling bed, atmospheric pressure FBC (AFBC) pilot plant and six pulverized-coal combustion (PC) units. The combined influences of measured particle and dust cake properties on filtering pressure drop were estimated with existing filtration theories. These theories predict a higher pressure drop for a dust cake produced with the AFBC ash than for one consisting of any of the PC ashes. Laboratory measurements were made of the flow resistance of idealized, simulated dust cakes to confirm these predictions. Field operating data from the fabric filters collecting some of the tested ashes were available to validate the laboratory results. The laboratory and field data show relatively good agreement. The AFBC ash must be treated as a special case for fabric filters, and careful selection of cleaning method and fabric must be made to minimize the inherently high pressure drop characteristics of this ash.