WATER DEMAND AT WESTERN U.S. RECREATION DEVELOPMENTS1

Although the volume of potable water used at recreation developments is minor relative to total regional water use, very high quality is required and the source is often of limited capacity, such as a mountain spring or small local aquifer. Frequent confrontations between developers and regulatory agencies result from claims by developers that water demand will be very small while regulators tend to treat such developments the same as municipal residence. Almost no published data base exists for resolving such conflicts. Included here are: 1) Water use measurements of various peak period durations (seasonal, monthly, daily, and instantaneous) at several types of recreational developments in Utah and Wyoming (mountain cabins, both ski- and water-based condominiums, and recreation vehicle campgrounds), 2) statistical (frequency) analysis of the data and a comparison with municipal demands in the same region, and 3) analysis of occupancy rates at the various categories of developments.     

Environmental intervention: The monitoring paradigm

Summary Here, the author examines the management implications of a previously developed model of environmental control. A short account of the model is given, and its implications for an integrated environmental strategy are discussed. The need for a UK, national centre for environmental management, research, education and training is identified. An analytical system for investigating monitoring effort derived from the model is illustrated in use, by reference to the UK Monitoring Networks for Smoke and Sulphur Dioxide. The use of the model in providing the underlying theory for a systems approach to environmental management is demonstrated. The paper concludes by examining the implications of the model for education and training with special reference to technologists and professionals. Appropriate types of environmental education for such groups are considered. A curriculum generator is presented. Trevor Harvey trained as a microbiologist and subsequently specialised in pollution control. He was course organiser of “Environmental Pollution, Monitoring and Control”, an international course which was sponsored by Unesco, UNEP and WHO. This has become a prototype for training programmes in many countries.     

Application of a compact all solid-state laser system to the in situ detection of atmospheric OH,HO2, NO and IO by laser-induced fluorescence

A tuneable, high pulse-repetition-frequency, solid state Nd:YAG pumped titanium sapphire laser capable of generating radiation for the detection of OH, HO2, NO and IO radicals in the atmosphere by laser induced fluorescence (LIF) has been developed. The integration of the laser system operating at 308 nm into a field measurement apparatus for the simultaneous detection of hydroxyl and hydroperoxy radicals is described, with detection limits of 3.1 x 10(5) molecule cm(-3) (0.012 pptv in the boundary layer) and 2.6 x 10(6) molecule cm(-3) (0.09 pptv) achieved for OH and HO2 respectively (30 s signal integration, 30 s background integration, signal-to-noise ratio = 1). The system has been field tested and offers several advantages over copper vapour laser pumped dye laser systems for the detection of atmospheric OH and HO2 radicals by LIF, with benefits of greater tuning range and ease of use coupled with reduced power consumption, instrument footprint and warm-up time. NO has been detected in the atmosphere at approximately 1 ppbv by single photon LIF using the Alpha 2Sigma+ <-- Chi 2Pi1/2 (0,0) transition at 226 nm, with absolute concentrations in good agreement with simultaneous measurements made using a chemiluminescence analyser. With some improvements in performance, particularly with regard to laser power, the theoretical detection limit for NO is projected to be approximately 2 x 10(6) molecule cm(-3) (0.08 pptv). Whilst operating at 445 nm, the laser system has been used to readily detect the IO radical in the laboratory, and although it is difficult to project the sensitivity in the field, an estimate of the detection limit is < 1 x 10(5) molecule cm(-3) (< 0.004 pptv), well below previously measured atmospheric concentrations of IO.     

Multi-element geochemical analysis of snow samples: Use of discriminant analysis in interpreting the results

This paper records the concentrations of major and trace elements determined from snow samples collected during a comprehensive survey undertaken in the Scottish Highlands during the winter and spring period of 1987. The configuration of calculated back-trajectories allowed the samples to be categorized into one of five geographical sectors. Discriminant analysis was used to check the validity of these calculations, to isolate potentially deviant samples, and to predict the possible source of one sample whose back-trajectory could not be computed with confidence. Limitations of the statistical method are discussed, but we conclude that the technique justifies more use by environmental scientists involved in the evaluation of data.     

The Development and Implementation of Indicators of Ecosystem Health in the Great Lakes Basin

This paper describes a process for the selection of a suite of ecosystem health indicators for the Great Lakes, as called for in the Great Lakes Water Quality Agreement. The paper also presents some preliminary data on status and trends in ecosystem components based on those indicators. The indicator selection process was carried out by over 150 scientists and managers from both Canada and the USA, and involved the presentation of the proposed indicators at the State of the Lakes Ecosystem Conferences (SOLECs). An open period for comment followed the conferences where input from scientists involved in Great Lakes programs was received. The suite of indicators will, over time, present information in an understandable format that will allow for more informed management decisions.     

Arsenic-speciation in arsenate-resistant and non-resistant populations of the earthworm,Lumbricus rubellus

Arsenic speciation was determined in Lumbricus rubellus Hoffmeister from arsenic-contaminated mine spoil sites and an uncontaminated site using HPLC-MS, HPLC-ICP-MS and XAS. It was previously demonstrated that L. rubellus from mine soils were more arsenate resistant than from the uncontaminated site and we wished to investigate if arsenic speciation had a role in this resistance. Earthworms from contaminated sites had considerably higher arsenic body burdens (maximum 1,358 mg As kg-1) compared to the uncontaminated site (maximum 13 mg As kg-1). The only organo-arsenic species found in methanol/water extracts for all earthworm populations was arsenobetaine, quantified using both HPLC-MS and HPLC-ICP-MS. Arsenobetaine concentrations were high in L. rubellus from the uncontaminated site when concentrations were expressed as a percentage of the total arsenic burden (23% mean), but earthworms from the contaminated sites with relatively low arsenic burdens also had these high levels of arsenobetaine (17% mean). As arsenic body burden increased, the percentage of arsenobetaine present decreased in a dose dependent manner, although its absolute concentration rose with increasing arsenic burden. The origin of this arsenobetaine is discussed. XAS analysis of arsenic mine L. rubellus showed that arsenic was primarily present as As(III) co-ordinated with sulfur (30% approx.), with some As(v) with oxygen (5%). Spectra for As(III) complexed with glutathione gave a very good fit to the spectra obtained for the earthworms, suggesting a role for sulfur co-ordination in arsenic metabolism at higher earthworm arsenic burdens. It is also possible that the disintegration of As(III)-S complexes may have taken place due to (a) processing of the sample, (b) storage of the extract or (c) HPLC anion exchange. HPLC-ICP-MS analysis of methanol extracts showed the presence of arsenite and arsenate, suggesting that these sulfur complexes disintegrate on extraction. The role of arsenic speciation in the resistance of L. rubellus to arsenate is considered.     

An empirical examination of the role of attributions in psychological entitlement and its outcomes

Psychological entitlement refers to the phenomenon in which individuals consistently believe that they deserve preferential rewards and treatment, often with little consideration of actual qualities or performance levels. This study examines the influence of psychological entitlement on workplace outcomes, using attribution theory to explain its effects. Results suggested that entitlement perceptions are positively associated with self‐serving attribution styles and that diminished need for cognition mediates this relationship. Self‐serving attribution styles, in turn, were associated with reduced job satisfaction and increased levels of conflict with supervisors. A direct positive relationship between psychological entitlement and turnover intent was also observed. Overall, results suggest that an attributional perspective is useful in explaining and understanding the influence of entitlement perceptions on workplace outcomes. Copyright © 2008 John Wiley & Sons, Ltd.     

Australian approaches to coastal vulnerability assessment

The Australian coastline is one of the longest and most diverse of any in the world, and Australian researchers have developed preliminary models of the behaviour of major coastal systems such as beaches and reefs. The Australian population is particularly focused along the coastline, especially in metropolitan centres; however, the population of regional centres along the coast is increasing steadily in response to a phenomenon termed seachange. Coastal systems are increasingly threatened by potential impacts as a result of climate change, as indicated by the successive assessments by the Intergovernmental Panel on Climate Change (IPCC). Although Australia played a central role in applying a common methodology (CM), developed from IPCC guidelines in the 1990s, and in devising alternative approaches, which were initially trialled at nine sites on the Australian coast, there has not been a nationally co-ordinated approach to assessing the coastal vulnerability of Australia, and such an approach is only emerging now. Instead, there have been a series of different approaches adopted to look at the different parts of the Australian coast, including wetland mapping in northern Australia; geomorphic unit mapping in South Australia; storm surge vulnerability modelling in Queensland; probabilistic approaches to beach erosion in New South Wales; indicative mapping of potential coastal retreat in Tasmania. Additionally, there have been methods proposed by insurers and coastal engineers to meet their requirements. Since 2005, the Australian government has once again seen the need for a national coastal vulnerability assessment, and a series of studies are planned or under way to achieve the aims of a National Climate Change Adaptation Framework.