Influence of physico-chemical properties of soil clay fractions on the retention of dissolved organic carbon

This study investigated the effects of surface functional groups, cation exchange capacity (CEC), surface charge, sesquioxides and specific surface area (SSA) of three soil clay fractions (SCFs) (kaolinite–illite, smectite and allophane) on the retention of dissolved organic carbon (DOC) in soils. Physico-chemical properties of the SCFs before and after removing native carbon and/or sesquioxides were characterised, and the DOC adsorption–desorption tests were conducted by a batch method. Native organic carbon (OC)/sesquioxide removal treatments led to a small change in the CEC values of kaolinite–illite, but significant changes in those of smectite and allophane. The net negative surface charge increased in all samples with an increase in pH indicating their variable charge characteristics. The removal of native OC resulted in a slight increase in the net positive charge on soil clay surfaces, while sesquioxide removal increased the negative charge. Changes in the functional groups on the SCF surfaces contributed to the changes in CEC and zeta potential values. There was a strong relationship (R ² = 0.93, p < 0.05) between the Langmuir maximum DOC adsorption capacity (Q _max) and SSA. The Q _max value also showed a moderately strong relationship (R ² = 0.55, p < 0.05) with zeta potential (at pH 7). Q _max was only poorly correlated with CEC and native OC content. Therefore, along with SSA, the surface charge and functional groups of SCFs played the key role in determining the adsorption affinity and hence retention of DOC in soils.     

Congener profiles of polychlorinated biphenyls in core sediments of Sunderban mangrove wetland (N.E. India) and their ecotoxicological significance

The paper presents the first comprehensive survey of congener profiles of polychlorinated biphenyls (PCBs) in core sediment samples (<63 microm particle size) covering seven sites in Sunderban mangrove Wetland, north-eastern part of the Bay of Bengal. Results pointed out a non-homogenous contamination of the wetland with Sigma23PCB values ranging from 0.5 to 26.9 ng g(-1) dry weight, reflecting very low to moderate contamination closely in conformity to other Asian coastal environment. The general decreasing order of the dominant congeners to the total load was: CB138 > 153 > 149 > 101, indicating the predominance of hexa-chlorinated congeners. The spatial distribution revealed significant differences in concentration related to local urbanization with industrial and land-based sources. No uniform temporal trend on PCB levels was recorded probably due to particular hydrological characteristics of the wetland and/or non-homogenous inputs from point sources. Strong positive correlations between the seven dominant congeners suggest their common sources and similar environmental behaviors. These results were also used for a risk assessment evaluation in the Sunderban wetland, showing that the present PCB levels were exceeding in few cases the lower limit of sediment quality guidelines of Environmental Protection Agency and Canadian Council of Ministers of the Environment.     

GIS-based approach for optimized siting of municipal solid waste landfill

The exponential rise in the urban population of the developing countries in the past few decades and the resulting accelerated urbanization phenomenon has brought to the fore the necessity to develop environmentally sustainable and efficient waste management systems. Sanitary landfill constitutes one of the primary methods of municipal solid waste disposal. Optimized siting decisions have gained considerable importance in order to ensure minimum damage to the various environmental sub-components as well as reduce the stigma associated with the residents living in its vicinity, thereby enhancing the overall sustainability associated with the life cycle of a landfill. This paper addresses the siting of a new landfill using a multi-criteria decision analysis (MCDA) and overlay analysis using a geographic information system (GIS). The proposed system can accommodate new information on the landfill site selection by updating its knowledge base. Several factors are considered in the siting process including geology, water supply resources, land use, sensitive sites, air quality and groundwater quality. Weightings were assigned to each criterion depending upon their relative importance and ratings in accordance with the relative magnitude of impact. The results from testing the system using different sites show the effectiveness of the system in the selection process.     

Self-preserving characteristics in wall-wake flow downstream of an isolated bedform

Environmental Fluid Mechanics - The results of an experimental study on the turbulence characteristics in flow over and downstream of an isolated bedform are presented. The vertical profiles of...     

Ecological compensation of grain trade within urban,rural areas and provinces in China: a prospect of a carbon transfer mechanism

Environment, Development and Sustainability - In order to solve regional ecological inequity in carbon emissions, building a balanced ecological compensation mechanism is paramountly important....     

Innovative application of facile single pot green synthesized CuO and CuO@APTES nanoparticles in nanopriming of Vigna radiata seeds

Environmental Science and Pollution Research - Nanopriming is an emerging field of science which uses nanoparticles in solution to improve parameters of seed vigor. This leads to an initial...     

Study on the quality and stability of compost through a Demo Compost Plant

This study is concerned with the performance of a Demo Compost Plant for the development of acceptable composting technology in Bangladesh. The Demo Compost Plant was setup at the adjacent area of an existing compost plant located at Khulna city in Bangladesh. Four different composting technologies were considered, where Municipal Solid Waste (MSW) were used as a raw material for composting, collected from the adjacent areas of the plant. Initially the whole composting system was conducted through two experimental setups. In the 1st setup three different types of aerators (horizontal and vertical passively aerator and forced aerator) were selected. For a necessary observation four piles, using only MSW as the input materials in the first three compost pile, the fourth one was the existing Samadhan’s compost pile. Based on the analysis of the experimental findings, the horizontal passively aerated composting technique is suitable for Bangladesh as it had better performance for reducing composting period than that of the others. It was being observed from the quality parameters of compost in the both 1st and 2nd setup that as the waste directly come from kitchen, degradation rate of waste shows a positive result for reducing this waste and there is no possibility of toxic contamination, when it would be used as a soil conditioner. Though there is no significant improvement in the quality of the final product in the 2nd setup as comparing with the 1st setup but it fulfills one of the main objectives of this study is to reduce the whole composting period as well as immediate management of the increasing amount of waste and reducing load on landfill. Selfheating tests reveal that degree of stability of compost with respect to maturation period was remained in the acceptable level, which was further accelerated due to the use of organic additives.     

Dispersion of odour: a case study with a municipal solid waste landfill site in North London,United Kingdom

Municipal solid waste (MSW) landfills are a potential source of offensive odours that can create annoyance within communities. Dispersion modelling was used to quantify the potential odour strength causing an impact on the community around a particular MSW landfill site north of the London area in the United Kingdom. The case studies were completed with the short-term mode of COMPLEX-I, software developed by the US-EPA. The year 1998 was chosen as a source of baseline data. It was observed that by 2004, when the landfill will progress towards the west and a big band of the area towards the north would be partly/fully restored, the maximum contribution of the new sources giving higher odour concentrations would be in the southwesterly regions away from the landfill. Concentrations as high as 25.0 ou(E)/m(3) were observed with 3 min averaging time in the southwesterly areas as compared to concentrations of 20.0 ou(E)/m(3) at 10 min averaging times. However, the percentage frequency of such critical events occurring would be low. All other surrounding farms and small villages would be exposed to the concentration of 3.0 ou(E)/m(3) on certain occasions. In the year 2008, the majority of the filling fronts would be filled with wastes with no contributions from the active and operational cells. The maximum odour concentration around the landfill site for 1 h averaging time would be approximately 3 ou(E)/m(3) about 1.0 km north and 500 m west of the landfill site. For 3 min averaging time, the stretch of 5 ou(E)/m(3) band would be up to 2.5 km towards the north of the landfill site. It is argued that further analysis of the model calculations considering effects of wind direction, frequency of wind direction, stability of the atmosphere, selected odour threshold, integration time of the model, etc. would form a basis for calculating the separation distances of the landfill site from the surrounding community.     

Contrasting effects of engineered carbon nanotubes on plants: a review

Rapid surge of interest for carbon nanotube (CNT) in the last decade has made it an imperative member of nanomaterial family. Because of the distinctive physicochemical properties, CNTs are widely used in a number of scientific applications including plant sciences. This review mainly describes the role of CNT in plant sciences. Contradictory effects of CNT on plants physiology are reported. CNT can act as plant growth inducer causing enhanced plant dry biomass and root/shoot lengths. At the same time, CNT can cause negative effects on plants by forming reactive oxygen species in plant tissues, consequently leading to cell death. Enhanced seed germination with CNT is related to the water uptake process. CNT can be positioned as micro-tubes inside the plant body to enhance the water uptake efficiency. Due to its ability to act as a slow-release fertilizer and plant growth promoter, CNT is transpiring as a novel nano-carbon fertilizer in the field of agricultural sciences. On the other hand, accumulation of CNT in soil can cause deleterious effects on soil microbial diversity, composition and population. It can further modify the balance between plant-toxic metals in soil, thereby enhancing the translocation of heavy metal(loids) into the plant system. The research gaps that need careful attention have been identified in this review.     

Correction to: Influence of physico-chemical properties of soil clay fractions on the retention of dissolved organic carbon

Environmental Geochemistry and Health - Unfortunately, in the original publication of the article, Prof. Yong Sik Ok’s affiliation was incorrectly published. The author’s affiliation is...