NUMERICAL MODELING OF SOLUTE TRANSPORT PATTERNS IN THE DAMMAM AQUIFER1

ABSTRACT: During the past two decades, the Kingdom of Saudi Arabia has witnessed rapid development in its agricultural and urban areas, which has resulted in greater reliance being placed on its ground water aquifers. The intensive development, particularly along the coastline and in the absence of adequate replenishment sources, has led to major deterioration in the quality and quantity of ground water resources. A numerical model of the Dammam aquifer in the Eastern Province is developed and used to predict the extent of the saline intrusion in the aquifer. The types of stresses effecting the solute transport were identified and remedial measures were suggested. (KEY TERMS: numerical modeling; Saudi Arabia; aquifer; modeling/statistics.)     

Using environmental accounts to promote sustainable development: Experience in southern Africa

Environmental accounts bring together economic and environmental information in a common framework to measure the contribution of the environment to the economy and the impact of the economy on the environment. They enable governments to set priorities, monitor economic policies more precisely, enact more effective environmental regulations and resource management strategies, and design more efficient market instruments for environmental policies. This article uses examples from the regional environmental accounting programme in southern Africa to demonstrate the usefulness of environmental accounts to policy-making and natural resource management. The examples address the contribution of natural capital endowments (minerals and fisheries) to sustainable development in Botswana and Namibia; the economic importance of non-market forest goods and services in South Africa; and the socio-economic impact of current water allocation and pricing policies in Botswana, Namibia and South Africa. While there are many additional policy applications, these few provide a powerful argument for the use of environmental accounts in all countries.     

Feasibility of the hydrogen sulfide test for the assessment of drinking water quality in post-earthquake Haiti

In 2010, a magnitude 7.0 earthquake struck Haiti, severely damaging the drinking and wastewater infrastructure and leaving millions homeless. Compounding this problem, the introduction of Vibrio cholerae resulted in a massive cholera outbreak that infected over 700,000 people and threatened the safety of Haiti’s drinking water. To mitigate this public health crisis, non-government organizations installed thousands of wells to provide communities with safe drinking water. However, despite increased access, Haiti currently lacks the monitoring capacity to assure the microbial safety of any of its water resources. For these reasons, this study was designed to assess the feasibility of using a simple, low-cost method to detect indicators of fecal contamination of drinking water that could be implemented at the community level. Water samples from 358 sources of drinking water in the Léogâne flood basin were screened with a commercially available hydrogen sulfide test and a standard membrane method for the enumeration of thermotolerant coliforms. When compared with the gold standard method, the hydrogen sulfide test had a sensitivity of 65 % and a specificity of 93 %. While the sensitivity of the assay increased at higher fecal coliform concentrations, it never exceeded 88 %, even with fecal coliform concentrations greater than 100 colony-forming units per 100 ml. While its simplicity makes the hydrogen sulfide test attractive for assessing water quality in low-resource settings, the low sensitivity raises concerns about its use as the sole indicator of the presence or absence of fecal coliforms in individual or community water sources.     

Ferric-manganese doped sulphated zirconia nanoparticles catalyst for single-step biodiesel production from waste cooking oil: Characterization and optimization

Biodiesel of waste cooking oil origin is gaining attention as a replacement for current fossil fuels, as its low-priced, recycled feedstock shall prevent food source competition, which is estimated to happen with current biodiesel production processes. As a result, waste cooking oil has been claimed to be a highly potential feedstock for biodiesel production. In the present research work, Fe-Mn doped sulphated zirconia catalyst was synthesized and used in simultaneous esterification and transesterification of waste cooking oil to biodiesel synthesis. The catalyst was prepared through the impregnation method and characterized by using XRD, TPD-NH_3, FT-IR, BET, and TEM. Response surface methodology (RSM) in conjunction with the central composite design (CCD) was applied to statistically evaluate and optimize the biodiesel preparation process. It was found that the synthesis of biodiesel achieved an optimum level of 97.2% waste cooking oil methyl ester’s (WCOME’s) yield at the following reaction conditions: methanol/oil molar ratio: 10:1, catalyst concentration: 3.0 wt %, and reaction temperature: 160 °C. The extremely high WCOME’s yield of 97.2% was proved to be due to high acidity, surface area, and large pore diameter; reactants can easily diffuse into the interior pore of the catalyst and allow them to be in contact with active sites that enhance catalytic activity.     

Role of non-timber forest products in sustaining forest-based livelihoods and rural households' resilience capacity in and around protected area: a Bangladesh study†

People in the developing world derive a significant part of their livelihoods from various forest products, particularly non-timber forest products (NTFPs). This article attempts to explore the contribution of NTFPs in sustaining forest-based rural livelihood in and around a protected area (PA) of Bangladesh, and their potential role in enhancing households' resilience capacity. Based on empirical investigation, our study revealed that local communities gather a substantial amount of NTFPs from national park despite the official restrictions. Twenty seven percent households (HHs) of the area received at least some cash benefit from the collection, processing and selling of NTFPs, and NTFPs contribute to HHs' primary, supplementary and emergency sources of income. NTFPs also constituted an estimated 19% of HHs' net annual income, and were the primary occupation for about 18% of the HHs. HHs' dependency on nearby forests for various NTFPs varied vis-à-vis their socio-economic condition, as well as with their location from the park. Based on our case study, the article also offers some clues for improving the situation in PA.     

Integrating geospatial and ground geophysical information as guidelines for groundwater potential zones in hard rock terrains of south India

The increasing demand of water has brought tremendous pressure on groundwater resources in the regions were groundwater is prime source of water. The objective of this study was to explore groundwater potential zones in Maheshwaram watershed of Andhra Pradesh, India with semi-arid climatic condition and hard rock granitic terrain. GIS-based modelling was used to integrate remote sensing and geophysical data to delineate groundwater potential zones. In the present study, Indian Remote Sensing RESOURCESAT-1, Linear Imaging Self-Scanner (LISS-4) digital data, ASTER digital elevation model and vertical electrical sounding data along with other data sets were analysed to generate various thematic maps, viz., geomorphology, land use/land cover, geology, lineament density, soil, drainage density, slope, aquifer resistivity and aquifer thickness. Based on this integrated approach, the groundwater availability in the watershed was classified into four categories, viz. very good, good, moderate and poor. The results reveal that the modelling assessment method proposed in this study is an effective tool for deciphering groundwater potential zones for proper planning and management of groundwater resources in diverse hydrogeological terrains.     

Hydrochemical characterization and pollution assessment of groundwater in Jammu Siwaliks,India

Physico-chemical groundwater (GW) parameters were evaluated to understand the hydrogeochemical processes in the Siwalik plains of Jammu and Kashmir, India. During the 2012–2013 post-monsoon (POM) and pre-monsoon (PRM) seasons, GW samples (n = 207) from deep bore wells and shallow open wells were chemically analysed. Cations (Ca²⁺, Mg²⁺, Na⁺, K⁺ and Fe²⁺) and anions (HCO₃ ^?, Cl^?, SO₄ ^2? and F^?) showed a wide spatio-temporal variation. Results suggest that weathering and dissolution of carbonates and silicate rocks is the main source of water mineralization. The major hydrochemical facies is characterized by Ca-Mg-HCO₃ and Ca-HCO₃ during the PRM and POM seasons respectively. The presence of sulphate-bearing water in a large number of the samples indicates a significant role of gypsum dissolution and anthropogenic contamination of the GW. Factor analysis (FA) and hierarchical cluster analysis (HCA) revealed that the variability of hydrochemistry is mainly related to rock-water interaction, dissolution of carbonates and other lithological units as well as the influence of anthropogenic activities in the area. Overall, it was found that the GW quality is within the limits of human consumption. The higher concentration of a few chemicals indicates an increasing trend of industrial contamination of the GW. For sustainable development of the portable GW in Siwaliks, it is necessary to minimize the adverse impacts of the anthropogenic and industrial contamination on the GW resources through best management practices and prevent its further contamination to a level that could make GW unsuitable for human uses.     

Farmers’ attitude toward treated sludge use in the villages of West Bank,Palestine

An application of treated sewage sludge on agricultural land has been widely accepted, as this method is simple and economical for disposal of wastewater residues. When applied properly on an agricultural land, sludge can replenish organic matter and nutrients in soil. Although sewage sludge has been used in agriculture in many parts of the world, its acceptability varies with different cultures and beliefs among farmers. Farmers’ concerns on sludge use are primarily due to its anthropogenic origin, pollutants that it carries, a general perception of sewage being dirty, and its offensive odor. This paper aims to investigate farmers’ perceptions on land application of treated sewage sludge on their farm. This study targeted two farming communities, namely, Anza and Beit Dajan villages, located in Jenin and Nablus districts in the West Bank, Palestine. In this study, a sample of 106 farmers were randomly selected and surveyed through a mixture of structured and open-ended questions. Results indicated that, overall, farmers have positive perceptions on land application of sludge. A majority of the farmers are in favor of the concept of sludge use when a planned wastewater treatment plant is constructed and it becomes operational. Results also indicate that a majority of the farmers are in favor of using sludge for fertilizing fruit trees, rather than growing vegetables and other plants in a greenhouse, and that many of them have knowledge of sludge properties and advantages and disadvantages of sludge use in agriculture. Despite the positive perceptions by the majority of farmers, a small fraction of the farmers are in disfavor of the use of sludge for the following reasons: psychological and social concerns, potential health risks, and their religious beliefs. Results further suggest that the land application of treated sewage sludge can be accepted by more farmers if the consumers are willing to buy agricultural products fertilized by sludge, sludge meets the public health requirements, and sludge is available at low costs. To improve farmers’ perceptions on the land application of sludge, several measures are recommended.     

Spatial�Ctemporal assessment and redesign of groundwater quality monitoring network: a case study

Assessment of groundwater quality monitoring networks requires methods to determine the potential efficiency and cost-effectiveness of the current monitoring programs. To this end, the concept of entropy has been considered as a promising method in previous studies since it quantitatively measures the information produced by a network. In this study, the measure of transinformation in the discrete entropy theory and the transinformation?Cdistance (T?CD) curves, which are used frequently by other researchers, are used to quantify the efficiency of a monitoring network. This paper introduces a new approach to decrease dispersion in results by performing cluster analysis that uses fuzzy equivalence relations. As a result, the sampling (temporal) frequency determination method also recommends the future sampling frequencies for each location based on certain criteria such as direction, magnitude, correlation with neighboring stations, and uncertainty of the concentration trend derived from representative historical concentration data. The proposed methodology is applied to groundwater resources in the Tehran?CKaradj aquifer, Tehran, Iran.     

Phytoaccumulation prospects of cadmium and zinc by mycorrhizal plant species growing in industrially polluted soils

The natural vegetation growing along a wastewater channel was subjected to analyze the uptake of Cadmium (Cd) and Zinc (Zn) and their subsequent accumulation in aboveground and underground plant parts. Species which were mycorrhizal and growing in soils receiving industrially contaminated wastewater were collected along with their rhizospheric soil samples. The nearby uncontaminated control (reference) area was also subjected to sampling on similar pattern for comparison. Both Cd and Zn concentrations were significantly higher in soils of the study area as compared to the reference site. Five plant species i.e. Desmostachya bipinnata, Dichanthium annulatum, Malvastrum coromandelianum, Saccharum bengalense, and Trifolium alexandrinum were analyzed for metal uptake. The maximum phytoaccumulation of Cd was observed in Desmostachya bipinnata (20.41 μg g⁻¹) and Dichanthium annulatum (15.22 μg g⁻¹) for shoot and root tissues, respectively. However, Malvastrum coromandelianum revealed maximum Zn accumulation for both the shoot and the root tissues (134 and 140 μg g⁻¹, respectively). The examination of cleared and stained roots of the plants from both the areas studied revealed that all of them were colonized to a lesser or a greater degree by arbuscular mycorrhizal (AM) fungi. The Cd hyperaccumulating grasses i.e. Desmostachya bipinnata and Dichanthium annulatum, from study area had smaller root:shoot (R/S) ratio as compared to those growing on reference area indicating a negative pressure of soil metal contamination. The lower R/S ratio in the mycorrhizal roots observed was probably due to increased AM infection and its mediatory role in soil plant transfer of heavy metals. Furthermore, comparatively lower soil pH values in the study areas may have played a key role in making the overall phytoavailability of both the metals. Consequently variations in Cd and Zn tissue concentration among species were observed that also indicate the phytoaccumulation potential of the native species.