Ambient toxicity due to chlorpyrifos and diazinon in a central California coastal watershed

The Salinas River watershed along the central coast of California, U.S.A., supports rapidly growing urban areas and intensive agricultural operations. The river drains to an estuarine National Wildlife Refuge and a National Marine Sanctuary. The occurrence, spatial patterns, sources and causesof aquatic toxicity in the watershed were investigated by sampling four sites in the main river and four sites in representative tributaries during 15 surveys between September1998 and January 2000. In 96 hr toxicity tests, significant Ceriodaphnia dubia mortality was observed in 11% of the mainriver samples, 87% of the samples from a channel draining anurban/agricultural watershed, 13% of the samples fromchannels conveying agricultural tile drain runoff, and in 100% of the samples from a channel conveying agricultural surface furrow runoff. In six of nine toxicity identificationevaluations (TIEs), the organophosphate pesticides diazinon and/or chlorpyrifos were implicated as causes of observed toxicity, and these compounds were the most probable causes oftoxicity in two of the other three TIEs. Every sample collectedin the watershed that exhibited greater than 50% C. dubia mortality (n = 31) had sufficient diazinon and/or chlorpyrifos concentrations to account for the observed effects.Results are interpreted with respect to potential effects on other ecologically important species.     

Toward systemic campus sustainability: gauging dimensions of sustainable development via a motivational and perception-based approach

Universities have long borne an influential role in sustainability. Nonetheless, the affinity toward eclectic and piecemeal practices has been addressed as oxymoron to the essence of sustainable development, and the need to hone campus members’ buy-in is credited to be cardinal for systemic transformation. Major attributes for systemic campus sustainability are identified, incorporated, and proposed via a conceptual model. Those attributes are key sustainable development areas as well as perception and motivation on the topics that must be taken into consideration by universities to be able to adhere to a more pragmatic and inclusive sustainable development. Thus, the central intent of the authors is to offer a mechanism which may facilitate as well as elevate systemic campus sustainability. An extensive review of the literature in the area of sustainability, perception, and motivation is conducted, which includes articles, journals, conference proceedings, university reports, books, and materials from websites. By extracting and integrating crucial constituents of sustainable development from various studies, this paper contributes to the existing literature on sustainable development providing an input to the implementation of systemic campus sustainability.     

Criteria and indicators of forest sustainability assessment for Cameroon

Against a backdrop of continuous deforestation and the degradation of forest resources, this paper is an attempt to develop auspicious criteria and indicators of forest sustainability for Cameroon, drawing from the strength and weaknesses of those currently applicable. Using data emanating from both secondary and primary sources, this paper concludes that while the adoption and implementation of the criteria for forest sustainability should normally lead to sustainability, it should not be taken for granted because sustainability is not an abstract concept, but measurable. Thus, whether or not forest in Cameroon is sustainable can only be ascertained through the effective application of the criteria and indicators delineated in this paper.     

Cooling Suits,Physiological Response,and Task Performance in Hot Environments for the Power Industry

Heat stress on workers working outdoors in the power industry may result in fatigue and deterioration in task performance. This research collected and analyzed data on task performance of workers working indoors and outdoors with and without a cooling suit. The task performance was compared on the basis of heart rate, oxygen consumption, tympanic temperature, subjective responses, productivity, and error rates. Based on One-Way Analysis Of Variance (ANOVA) results, a significantly lower estimated working oxygen consumption was observed (p < .001) when the cooling suit was worn. The productivity was higher while workers wore the cooling suit as compared to no cooling suit (p = .011) whereas the error rates were significantly lower(p < .001). Also a significantly lower self-reported discomfort was observed in the neck and shoulders while working wearing the cooling suit (p = .004). This study concluded that wearing a cooling suit while working outdoors was associated with physiological benefits as well as improved task performance of the study participants.     

A formulation to optimize the risk reduction process based on LOPA

This paper presents a mixed integer nonlinear programming (MINLP) model to improve the computational use of the layer of protection analysis (LOPA). For a given set of independent protection layers to be implemented in a process, the proposed optimization model is solved to: a) Include costs associated with the different prevention, protection and mitigation devices, and b) Satisfy the risk level typically specified in the LOPA analysis through the occurrence probability. The underline purpose focuses on improving the analysis process and decision making to obtain the optimal solution in the safeguards selection that satisfies the requirements to be considered as IPL’s. The optimization is based on economic and risk tolerance criteria. As a first stage of this proposal, the safety instrumented system (SIS) design is optimized so that the selection of SIS components minimizes the risk and satisfies the safety integrity level (SIL) requirements. A case study is presented to validate the whole proposed approach.     

Estimating the energy consumption function: evidence from across the globe

Environmental Science and Pollution Research - The motivation for the current study stem from the United Nations Sustainable Development Goals (UN-SDGs) such as access to clean (SDG-7) and...     

Photocatalytic degradation of methylbutandioic acid (MBA) in aqueous TiO2 suspension: influences of MBA adsorption on the solid semi-conductor

In the present work we describe the photocatalytic degradation of methylbutandioic acid (MBA), focusing particularly on adsorption of the MBA on TiO₂ surface. We observe a very fast surface carboxylate formation, a decrease of the surface carboxylates during the reaction and an apparent zero order kinetic for the degradation of MBA. We conclude that the main way of MBA degradation is its reaction in the solution, and not on the surface of TiO₂. The influence of the surface carboxylates on the efficiency of the catalyser is under study.     

Microwave pretreatment for enhancement of phosphorus release from dairy manure

Both the advanced oxidation process (AOP) using a combination of hydrogen peroxide addition and microwave heating (H2O2/microwave), and the microwave heating process were used for solubilization of phosphorus from liquid dairy manure. About 80% of total phosphate was released into the solution at a microwave heating time of 5 min at 170 degrees C. With an addition of H2O2, more than 81% of total phosphate could be released over a reaction period of 49 h at ambient temperature. The AOP process could achieve up to 85% of total phosphate release at 120 degrees C. The results indicated that both the microwave, and the AOP processes could effectively release phosphate from liquid dairy manure. These processes could serve as pretreatments for phosphorus recovery from animal wastes, and could be combined with the struvite crystallization process to provide a new approach in treating animal wastes.     

Electrospun nanofibers of polyvinylidene fluoride incorporated with titanium nanotubes for purifying air with bacterial contamination

Environmental Science and Pollution Research - Polyvinylidene fluoride (PVDF) blended with varying concentrations of titanium nanotubes (TNT) was electrospun to result in a nanocomposite filter...     

Roadmap for climate alliance economies to vision 2030: retrospect and lessons

The United Nations Climate Conference 25, held in December 2019, reached a significant agreement against implementing the Paris agreement come 2020. Bound by the contract, 189 countries who are party to the deal agreed to constrain worldwide temperature to ascend to 1.5° Celsius. To this end, the present study attempts to investigate the readiness of selected countries in the European Union to implement the agreement, which will better the quality of the global environment. In line with this, this study appraises the connection between economic growth, renewable and non-renewable energy consumption, on emissions in 11 countries in the European Union from 1990 to 2016. The study utilises the Pooled Mean Group-Auto Regressive Distributed Lag (PMG-ARDL) model estimator and Dumitrescu and Hurlin Panel Causality analysis to analyse the long-run and short-run impact and direction of causality among these factors, respectively. The long-run study's empirical results show a U-shaped Environmental Kuznets Curve (EKC) and a negative connection between renewable energy use and emissions in the EU-11 countries. In the short-run, non-renewable energy use worsens CO₂ emissions while renewable energy use leads to a fall in emissions. Similarly, causality tests show a feedback mechanism between emissions and renewable energy use and between non-renewable energy and renewable use. Also, there is unidirectional causality from income to CO₂ emissions, non-renewable energy use to CO₂ emissions. The investigation recommends an expanded proportion of renewable energy sources in the EU countries’ energy mix to cut down on emissions.