我国腈纶废水物化预处理方法的研究进展

结合我国腈纶废水的特征,系统归纳了近年来我国腈纶废水常用物化预处理方法的研究进展。物化预处理方法包括内电解法、混凝法、Fenton氧化法、电解法、臭氧氧化法、光催化氧化法、微波法等。这些方法普遍存在高成本、高能耗、实际运行费用大等问题。对未来物化预处理方法的研究方向提出了建议。最后指出,腈纶废水的处理应朝着节能高效和资源化的方向发展,推动我国腈纶废水处理技术的不断进步和完善。     

Transformational leadership and organizational commitment: mediating role of psychological empowerment and moderating role of structural distance

Using a sample of 520 staff nurses employed by a large public hospital in Singapore, we examined whether psychological empowerment mediated the effects of transformational leadership on followers' organizational commitment. We also examined how structural distance (direct and indirect leadership) between leaders and followers moderated the relationship between transformational leadership and organizational commitment. Results from HLM analyses showed that psychological empowerment mediated the relationship between transformational leadership and organizational commitment. Similarly, structural distance between the leader and follower moderated the relationship between transformational leadership and organizational commitment. Implications for research and practice of our findings are discussed. Copyright © 2004 John Wiley & Sons, Ltd.     

大力加强安全文化建设

文化是人类社会的精神财富.先进文化是人类社会文明进步的结晶,是能够顺应社会发展规律,揭示未来发展方向,为文明进步提供强有力的思想保证、精神动力和智力支持的文化.     

学习力:提升矿工安全素质的第一要素

本文根据对同是高危险行业的煤矿系统和民航系统的安全状况比较分析,提出了通过提升矿工学习力以提高安全素质进而改善煤矿安全状况的重大课题.文中分析了学习力对提升矿工安全素质的作用机理,研究了学习力的控制要素及其结构关系,设计了学习力模型,根据模型提出了提升矿工学习力的具体方法.     

Investigation on road traffic safety of the mountain areas in southwest China based on Wulong County, Chongqing Municipality

OBJECTIVE: To study the present situation, characteristics, and main problems of the traffic safety in the mountain areas of Southwest China. METHODS: A study was done on the traffic status of Wulong County, Chongqing Municipality, by means of document review, field investigation, and inquiry. RESULTS: The traffic crashes and deaths in Wulong County were increasing since 1999. From 1997 to 2001, there occurred 126 severe and very severe traffic crashes resulting in 175 deaths and 411 serious injuries, which accounted for 9.4% of total crashes, 96.1% of total deaths, and 48.4% of total serious injuries, respectively. The severe and very severe traffic crashes were highest in 2000. One part for 83 km in length accounting for 3.0% of No. 319 National Highway was responsible for 54.5% of very severe traffic crashes, which closely related to conditions of the road itself and its environment and defective execution of traffic laws. CONCLUSIONS: Wulong County, one of the mountain counties in Southwest China, is now facing a complex and serious road traffic situation and serious traffic safety, with a high incidence of severe and very severe road traffic crashes. The crashes closely relate to imperfect road design, defective execution of traffic laws, imperfect management, and environmental factors.     

半胱氨酸合钴溶液膜吸收法处理NO废气

在中空纤维膜接触器中以半胱氨酸合钴溶液为吸收液,采用膜吸收法处理NO废气。研究了对传质系数和NO去除率的影响因素,以及吸收液循环使用效果。实验结果表明:在进气流速为0.005 m/s、进气中NO质量浓度为650.14 mg/m3、吸收液pH为9、吸收液中半胱氨酸合钴浓度为0.017 mol/L、吸收液流速为0.003 m/s、吸收液温度为50℃的优化工艺条件下,吸收时间在55 min之内时,NO去除率保持在98%以上;吸收时间超过55 min之后,NO去除率迅速下降。吸收液经SO2还原处理后可多次循环使用,吸收效果基本不变。     

改性SiO2气凝胶对废水中Fe3+的吸附性能

制备了改性SiO₂气凝胶,考察了经不同类型、不同配比的改性剂改性的SiO₂气凝胶对模拟含Fe³⁺废水的吸附处理效果。实验结果表明：改性SiO₂气凝胶的最佳制备条件为三甲基氯硅烷（TMCS）作改性剂,V（TMCS）#x02236;V（正己烷）=1#x02236;5;当改性SiO₂气凝胶加入量为75g/L、吸附时间为4h、Fe³⁺质量浓度为10mg/L时,模拟含Fe³⁺废水的Fe³⁺去除率为98.32%,剩余Fe³⁺质量浓度为0.168mg/L;采用改性SiO₂气凝胶动态吸附处理流量为420mL/h、Fe³⁺质量浓度为100mg/L的模拟含Fe³⁺废水,吸附后废水中剩余Fe³⁺质量浓度仅为0.196mg/L。     

两级氧化法处理油田压裂返排液

采用两级氧化法处理油田压裂返排液。在次氯酸钠、次氯酸钙、过氧化氢、高锰酸钾4种氧化剂中,次氯酸钠的氧化效果最好。以次氯酸钠作为一级氧化剂,进行一级氧化处理;再分别采用次氯酸钙、过氧化氢、高锰酸钾进行二级氧化处理。在次氯酸钠加入量为40mL/L、一级氧化反应时间为30min、二级氧化反应时间为30min、初始废水COD为3976mg/L的条件下,二级氧化剂过氧化氢、次氯酸钙、高锰酸钾的最佳加入量分别为80,40,40mL/L,对应的COD去除率分别为82.60%,71.50%,83.50%。     

紫外辐照-催化湿式过氧化氢氧化技术处理酸性大红GR染料废水

采用自制的负载型CuO-ZnO-CeO2/γ-Al2O3催化剂,常温常压下通过紫外辐照-催化湿式氧化技术处理酸性大红GR模拟染料废水。考察了催化剂加入量、H2O2加入量、废水pH、反应时间、初始酸性大红GR质量浓度等对废水脱色率的影响。实验得到最佳工艺条件为初始酸性大红GR质量浓度200mg/L,催化剂加入量10.0g/L,H2O2加入量2.0mL/L,废水pH4,反应时间2h。最佳工艺条件下废水脱色率达99.33%。