西南地区极端降水的时空变化特征

西南地区是我国山地灾害最为严重的区域之一,而短时极端降水则是山地灾害成灾演化的关键控制因素。以西南地区1960~2011年110个气象站的逐日降水量资料为基础,通过建立起超门限峰值序列(POT),结合GIS空间分析技术与线性倾向估计、Mann Kendall趋势检验、Morlet小波分析等方法,研究了西南地区极端降水事件的时空变化规律。结果发现：20世纪60年代以来,西南地区极端降水频数有增加趋势,速率为0017/10 a,极端降水量在总降水量中所占的比重不断增加,增幅为0.638%/10a;西南地区极端降水频数的变化在年代际间存在显著的区域增减差异,增加的区域主要呈现出斑块状分布,而减少的区域则呈现出较明显的条带状分布;云南西南部、贵州大部和四川盆地中部3个区域是极端降水频发区,而川滇交界处的元谋-会理一带和四川盆地北部山区则较少发生极端降水;季风期极端降水频数呈现出明显的增加趋势,速率为0031次/10 a,非季风期极端降水频数则呈现出减少的趋势,速率为-0014次/10 a;季风期和年极端降水频数均没有明显的突变年份,非季风期存在3个突变点,分别是1969、1983和1994年;季风期与年极端降水存在27、15和7 a时间尺度上的周期性振荡,非季风期的周期性振荡则主要集中在27和12 a时间尺度上     

碱式硫酸铝溶液中SO42-的测定

建立了以铬黑T为指示剂,乙二胺四乙酸二钠反滴定过量BaCl₂的碱式硫酸铝溶液中SO₄^2-的测定方法。实验确定的操作条件为：待测试样稀释后ρ（SO_4^2-）为0.025 ~0.100 g/L,BaCl₂过量率为25%~100%,并且在加入BaCl₂前将试样煮沸,三乙醇胺加入量为0.10 L/L。该法回收率在98.90%~100.72%,相对标准偏差小于1%。测定方法准确,可靠,且操作简便、快速。     

Sedimentary record of polycyclic aromatic hydrocarbons and DDTs in Dianchi Lake, an urban lake in Southwest China

Unique time trends of polycyclic aromatic hydrocarbons (PAHs) and dichlorodiphenyltrichloroethanes (DDTs) were found in a dated sediment core from Dianchi Lake (DC), an urban lake in Southwest China. The temporal trend of PAHs in DC was not only different from those in China's coastline and remote lakes of China, but also different from those in more developed countries. Identification of sources suggested that PAHs in DC originated primarily from domestic combustion of coal and biomass. However, a change of source from low- and moderate-temperature combustion to high-temperature combustion processes was observed. Different from those in China's coastline and some developed countries, the temporal trend of DDTs in DC mirrored the historical usage of DDTs in China, with erosion of soils and surface runoff from its drainage area the most likely routes of DDT introduction to the lake. Rapid urbanization and industrialization in its catchment, effective interception of point-source pollution, and changes in sources of energy during the last few decades have significantly influenced the vertical profiles of PAHs in DC.     

Arsenic stabilization by zero-valent iron,bauxite residue,and zeolite at a contaminated site planting Panax notoginseng

Panax notoginseng (Burk.) F.H. Chen, a rare traditional Chinese medicinal herb, is a widely used phytomedicine used all over the world. In recent years, the arsenic contamination of the herb and its relative products becomes a serious problem due to elevated soil As concentration. This study aimed to evaluate the effects of different types and dosages of amendments on As stabilization in soil and its uptake by P. notoginseng. Results showed that comparing to control treatment, the As concentrations of P. notoginseng declined by 49–63%, 43–61% and 52–66% in 0.25% zero-valent iron (Fe(0)), 0.5% bauxite residue, and 1% zeolite treatment, respectively; whereas the biomasses were elevated by 62–116%, 45–152% and 114–265%, respectively. The As(III) proportions of P. notoginseng increased by 8%, 9%, and 8%, and the transfer factors of As from root to shoot increased by 37%, 42% and 84% in the optimal treatments of Fe(0), bauxite residue, and zeolite. For soil As, all the three amendments could transform the non-specifically adsorbed As fraction to hydrous oxides Fe/Al fractions (by Fe(0) and red mud) or specifically adsorbed As fraction (by zeolite), therefore reduced the bioavailability of soil As. With a comprehensive consideration of stabilization efficiency, plant growth, environmental influence, and cost, Fe(0) appeared to be the best amendment, and zeolite could also be a good choice. In conclusion, this study was of significance in developing As contamination control in P. notoginseng planting areas, and even other areas for medicinal herb growing.     

腐熟蓝藻与厌氧污泥混合厌氧发酵特性

采用批次小试实验对不同腐熟程度的蓝藻进行厌氧发酵产沼气实验研究。结果表明,新鲜蓝藻在30-35℃时腐熟7 d后,可在35℃的厌氧温度下获得最高的产气速率和246 mL/g COD的产气量,产气潜力为354 mL/g（VS）。厌氧反应15 d后,累计产气量、COD和VFA浓度趋于稳定。淀粉酶和脱氢酶的活性在厌氧反应初期受到抑制,蛋白酶活性和辅酶F420浓度在厌氧系统中逐渐增加,分别在第6天达到27.66μmol/（g VS·min）和第15天达到0.62μmol/g（VS）。15-18d是腐熟蓝藻适宜的中温厌氧发酵时间,少于以新鲜蓝藻为基质的厌氧消化时间。蓝藻腐熟过程促进了厌氧反应,腐熟7 d的蓝藻厌氧系统具有更高的微生物活性和产甲烷能力。     

城市生活垃圾焚烧处理过程中重金属迁移规律研究

通过采集厦门2个垃圾焚烧发电厂进厂垃圾、渗滤液、飞灰、炉渣和烟气样品,分析垃圾组成成分及各组分的重金属含量,结果表明,垃圾中以厨余、橡塑类和纸类为主,共占到垃圾干基的78．08％,重金属含量大小次序为Zn〉Cu〉Pb〉Cr〉Ni〉Cd〉Hg;垃圾渗滤液中除Zn外,其他金属的含量都较低,一厂渗滤液中重金属Ni、Zn迁移量较大,分别达到24．46％和8．52％。二厂渗滤液中重金属的迁移有相同的趋势,但含量相对较高。垃圾焚烧后其重金属主要分布在飞灰和废渣中,烟气中的含量非常少,不同金属的含量均有差别,这与金属的性质有很大关系;通过浸出毒性分析,飞灰中重金属酸溶态含量多,容易浸出,属于危险废物。同时,不同烟气处理工艺产生的飞灰的重金属浸出量有很大差别。     

木浆清洁漂白废水中毒性物质的研究

为掌握木浆清洁漂白技术的毒性排放负荷及漂白废水的主要有机毒性成分,采用发光细菌急性毒性测试技术和GC/MS分析技术研究木浆清洁漂白废水的毒性及毒性物质.结果表明,木浆 OHMP漂白废水的总排放毒性因子(Toxicity Effluent Factor,TEF)为73.136TU·m3/t浆,其中H段废水TEF为48.356 TU·m3/t浆,占总量的66.1%;0段占总量的33.9%.木浆OHMP漂白总排放毒性当量约为7.314 g HgCl2/t浆.对漂白废水有机成分的分析表明,有机酸类约占H段废水检测总量的40.83%,烷烃类占13.62%.其中,氯代有机物3种(占检测总量的1.61%),分别为四氯化碳、2,2,2-三氯乙酸胺和2,4,6-三氯苯腈.与木浆CEH漂白相比,清洁漂白废水的毒性排放负荷小、有机毒性成份少,可以大力推广.     

青藏公路路堤边坡水土保持措施及效益分析

公路建设加速了区域的原有侵蚀,为了摸清公路边坡的侵蚀特征,寻找有效的防治措施,在青藏公路边坡布设不同水土保持措施的径流观测小区,进行了两年的观测（2003年和2004年）,结果表明：（1）工程措施具有较好的水土保持效益,其减流（减沙）效益在第一年和第二年分别达到3883％（8189％）和48.72％（9581％）,其中截排水措施的水土保持效益一方面说明公路路面来水也是边坡侵蚀的重要动力,有效拦截路面来水将会极大地减少径流和泥沙,另一方面也说明要提高公路边坡土壤侵蚀的预测能力,应该将路面来水作为重要的驱动力之一;（2）植被措施可以起到一定的减流减沙效果,其中人工植被措施有很大的潜力,其减蚀效益都在50％以上;（3）综合措施表现出了极好的水土保持效益（减流在40％以上,减沙在97％以上）,尤其土工格室+植被措施,兼具水土保持与景观双重效益。该研究可以为青藏高原地区的水土保持设计和生态环境保护规划提供数据支持。〖     

建筑物基底反力的实时监测与分析

以某大楼的基底反力监测为例 ,阐述了建筑物基底反力实时监测的原理与方法。监测分析结果表明 ,对在建建筑物进行的基底反力实时监测直接反映了土体受力状态 ,可间接得出桩基的受力情况。     

内乡-镇平4.7级地震及震后应急

内乡 -镇平 4 7级地震 ,是河南省解放以来唯一一次造成人员伤亡的地震事件。本文对这次地震的震害及烈度进行了考察评定 ,总结了有关部门的震后应急措施 ,讨论了从这次地震中应吸取的经验教训。