Compost impacts on dissolved organic carbon and available nitrogen and phosphorus in turfgrass soil

Compost application to turfgrass soils may increase dissolved organic C (DOC) levels which affects nutrient dynamics in soil. The objectives of this study were to investigate the influence of compost source and application rate on soil organic C (SOC), DOC, NO(3), and available P during 29 months after a one-time application to St. Augustinegrass [Stenotaphrum secundatum (Walt.) Kuntze] turf. Compost sources had variable composition, yet resulted in few differences in SOC, DOC, and NO(3) after applied to soil. Available NO(3) rapidly decreased after compost application and was unaffected by compost source and application rate. Available P increased after compost application and exhibited cyclical seasonal patterns related to DOC. Compost application decreased soil pH relative to unamended soil, but pH increased during the course of the study due to irrigation with sodic water. Increasing the compost application rate increased SOC by 3 months, and levels remained fairly stable to 29 months. In contrast, DOC continued to increase from 3 to 29 months after application, suggesting that compost mineralization and growth of St. Augustinegrass contributed to seasonal dynamics. Dissolved organic C was 75%, 78%, and 101% greater 29 months after application of 0, 80, and 160 Mg compostha(-1), respectively, than before application. Impacts of composts on soil properties indicated that most significant effects occurred within a few months of application. Seasonal variability of SOC, DOC, and available P was likely related to St. Augustinegrass growth stages as well as precipitation, as declines occurred after precipitation events.     

Use of Synthetic Aperture Radar for Selecting Alaskan Lakes for Winter Water Use1

Abstract: Water resources are limited in many areas of the North Slope, Alaska, particularly during winter. Water is used by the oil industry for ice road construction and maintenance, drilling and facility operations, and potable water supplies. The coastal plain between Teshekpuk Lake, in the National Petroleum Reserve‐Alaska (NPR‐A) and the Colville River has numerous shallow lakes, but further south in the northern foothills of the Brooks Range, and east to the Canning River, lakes are fewer. While many oil and gas lease sales have been conducted, or are proposed, access to the leases may be limited because of the lack of available water for ice road construction. Ice roads are the main means by which exploration is conducted in the Arctic, putting a stress on freshwater bodies that do not freeze to the lakebed in winter. Lakes that do not freeze to the lakebed also serve as overwintering habitat for fish. The purpose of this paper is to report on the potential distribution of water bodies that may provide overwinter water in selected areas from Teshekpuk Lake to the Canning River. The project used synthetic aperture radar (SAR) imagery to search for the presence of water in lakes in March 2006. In the Kuparuk and Canning SAR images, 52 and 61% of lakes were frozen to their beds by March 2006, accounting for 49 and 57% of the lake area in these study regions. Conversely, only 2% of the lakes in the Teshekpuk region were frozen to the bottom by March 2006. Unfrozen water was more available because of deeper and more numerous lakes in the Teshekpuk Lake region (west) than in the Canning River area (east). While only specific SAR tiles were analyzed herein, the method will be a useful tool for land managers who seek to evaluate the potential for ice road construction across the Arctic.     

Uranium removal from groundwater via in situ biostimulation: Field-scale modeling of transport and biological processes

During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to identify the dominant transport and biological processes controlling uranium mobility during biostimulation, and determine field-scale parameters for these modeled processes. The coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes based on the 2002 field experiment, that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of the bioavailable Fe(III) mineral threshold for the onset of sulfate reduction, and rates for the Fe(III), U(VI), and sulfate terminal electron accepting processes.     

Effects of development on runoff and pollutant export.

Runoff from two similar drainage areas in the Piedmont physiographic region of North Carolina was monitored simultaneously for 5.6 years. One of the drainage areas was developed as part of a large residential subdivision, while the other remained in woods and agricultural fields. Runoff volume was 68% greater for the developed compared with the undeveloped area, and baseflow as a percentage of overall discharge was approximately 0% compared with 25% for the undeveloped area. Overall annual export of sediment was 95% greater for the developed area, while export of nitrogen and phosphorus forms was 66 to 88% greater for the developed area. These results document the significant increases in runoff, sediment, and nutrient export associated with residential development.     

Guidance for the performance evaluation of three-dimensional air quality modeling systems for particulate matter and visibility

Guidance for the performance evaluation of three-dimensional air quality modeling systems for particulate matter and visibility is presented. Four levels are considered: operational, diagnostic, mechanistic, and probabilistic evaluations. First, a comprehensive model evaluation should be conducted in at least two distinct geographical locations and for several meteorological episodes. Next, streamlined evaluations can be conducted for other similar applications if the comprehensive evaluation is deemed satisfactory. In all cases, the operational evaluation alone is insufficient, and some diagnostic evaluation must always be carried out. Recommendations are provided for designing field measurement programs that can provide the data needed for such model performance evaluations.     

Activation energy for skeletal aragonite deposited by the hermatypic coral Platygyra spp.

Average radial growth rates of the hemispherical aragonite colonies deposited by the Indo-Pacific scleractinian reef coral Platygyra spp. were determined by measuring the thickness of density variations in the skeleton that are revealed by X-radiography. Ninety-one specimens from 21 localities were examined, but only 54 of these exhibited well-defined growth-banding. The apparent temperature dependence of growth rate is linear over the range 23.9° to 29.3°C, averaging 5.4±0.94 mm/year at 24°C, 8.0±0.42 mm/year at 27°C, and 9.7 ±0.58 mm/year at 29°C (90% confidence limits). Expression of the influence of temperature on growth rate in terms of the Arrhenius equation yields an activation energy of 20,680 cal/mole, which is comparable to values for typical biological reactions, but is only half that reported for skeletogenesis in another reef coral, Pocillopora damicornis, on the basis of controlled incubation studies involving ⁴⁵Ca uptake.     

The Sensitivity of Northern Groundwater Recharge to Climate Change: A Case Study in Northwest Alaska1

Clilverd, Hannah M., Daniel M. White, Amy C. Tidwell, and Michael A. Rawlins, 2011. The Sensitivity of Northern Groundwater Recharge to Climate Change: A Case Study in Northwest Alaska. Journal of the American Water Resources Association (JAWRA) 47(6):1228–1240. DOI: 10.1111/j.1752‐1688.2011.00569.x Abstract: The potential impacts of climate change on northern groundwater supplies were examined at a fractured‐marble mountain aquifer near Nome, Alaska. Well water surface elevations (WSE) were monitored from 2004‐2009 and analyzed with local meteorological data. Future aquifer response was simulated with the Pan‐Arctic Water Balance Model (PWBM) using forcings (air temperature and precipitation) derived from fifth‐generation European Centre Hamburg Model (ECHAM5) global circulation model climate scenarios for extreme and modest increases in greenhouse gases. We observed changes in WSE due to the onset of spring snowmelt, low intensity and high intensity rainfall events, and aquifer head recession during the winter freeze period. Observed WSE and snow depth compared well with PWBM‐simulated groundwater recharge and snow storage. Using ECHAM5‐simulated increases in mean annual temperature of 4‐8°C by 2099, the PWBM predicted that by 2099 later freeze‐up and earlier snowmelt will decrease seasonal snow cover by one to two months. Annual evapotranspiration and precipitation are predicted to increase 27‐40% (55‐81 mm) and 33‐42% (81‐102 mm), respectively, with the proportion of snowfall in annual precipitation decreasing on average 9‐25% (p < 0.05). The amount of snowmelt is not predicted to change significantly by 2099; however, a decreasing trend is evident from 2060 in the extreme ECHAM5 greenhouse gas scenario. Increases in effective precipitation were predicted to be great enough to sustain sufficient groundwater recharge.     

Evaluation of the SAPRC-07 mechanism against CSIRO smog chamber data

The updated SAPRC-07 mechanism was evaluated against data from experiments performed in the CSIRO smog chamber. The mechanism predictions have been compared to experimental results as well as predictions by SAPRC-99.Experiments were performed using either toluene or m-xylene in the presence of NO_x at sub-0.1 ppmv concentrations. For the majority of m-xylene experiments, the modelled Δ(O₃–NO) concentration was within 20% of observed values for both SAPRC mechanisms. However during the oxidation of toluene the production of radicals was poorly predicted, with final Δ(O₃–NO) concentration under-predicted by up to 60%. The predictions of major oxidants from isoprene oxidation were in good agreement with observed values. For the NO_x-limited conditions however, the ozone concentration predicted by both mechanisms were under-predicted by approximately 20% in the five experiments tested.The performance of the SAPRC-07 mechanism was also evaluated against twelve evaporated fuel experiments. Two types of evaporative mode experiments were performed: headspace evaporated fuel and wholly evaporated fuel. The major difference was a significantly higher concentration of aromatic hydrocarbons and larger alkane products in wholly evaporated fuels. For headspace evaporated fuel experiments both SAPRC mechanisms were in good agreement with experimental results. For wholly evaporated experiments the average Δ(O₃–NO) model error was ?25% with SAPRC-07 compared to less than ?5% for SAPRC-99. Updates to the photolysis data for dicarbonyls, the light source used and the experimental conditions under which these experiments were performed are possible causes for the discrepancy between SAPRC-99 and -07 predictions for wholly evaporated experiments.