Changes in contaminant mass discharge from DNAPL source mass depletion: evaluation at two field sites

Changes in contaminant fluxes resulting from aggressive remediation of dense nonaqueous phase liquid (DNAPL) source zone were investigated at two sites, one at Hill Air Force Base (AFB), Utah, and the other at Ft. Lewis Military Reservation, Washington. Passive Flux Meters (PFM) and a variation of the Integral Pumping Test (IPT) were used to measure fluxes in ten wells installed along a transect down-gradient of the trichloroethylene (TCE) source zone, and perpendicular to the mean groundwater flow direction. At both sites, groundwater and contaminant fluxes were measured before and after the source-zone treatment. The measured contaminant fluxes (J; ML(-2)T(-1)) were integrated across the well transect to estimate contaminant mass discharge (M(D); MT(-1)) from the source zone. Estimated M(D) before source treatment, based on both PFM and IPT methods, were approximately 76 g/day for TCE at the Hill AFB site; and approximately 640 g/day for TCE, and approximately 206 g/day for cis-dichloroethylene (DCE) at the Ft. Lewis site. TCE flux measurements made 1 year after source treatment at the Hill AFB site decreased to approximately 5 g/day. On the other hand, increased fluxes of DCE, a degradation byproduct of TCE, in tests subsequent to remediation at the Hill AFB site suggest enhanced microbial degradation after surfactant flooding. At the Ft. Lewis site, TCE mass discharge rates subsequent to remediation decreased to approximately 3 g/day for TCE and approximately 3 g/day for DCE approximately 1.8 years after remediation. At both field sites, PFM and IPT approaches provided comparable results for contaminant mass discharge rates, and show significant reductions (>90%) in TCE mass discharge as a result of DNAPL mass depletion from the source zone.     

Zinc and cobalt phytoextraction by different plant species

Plant species sorghum (Sorghum vulgar L.), clover (Trifolium pratense L.), panikum (Panicum antidotal), and canola (Brassica napus) were tested to determine their phytoremediation potential. After a period of about 90 days, plant samples (shoots and roots) and soil samples (before and after cultivation) were collected for zinc and cobalt analyses using atomic absorption spectrometry. The highest zinc uptake was observed in canola, while panikum grass showed a high zinc accumulation affinity compared to sorghum and clover. Calculation of the recovery percentage, based on the amount of zinc removed from the soil after cultivation, ranged between 12.8 and 36.3 percent of the total initial zinc. Canola shoots exhibited the highest cobalt uptake compared to the other plant species. Calculation of the recovery percentage based on cobalt removed from the soil after cultivation ranged between 10.1 and 40.7 percent of the total initial cobalt concentration. © 2007 Wiley Periodicals, Inc. *

1 This article is a U.S. Government work and, as such, is in the public domain of the United States of America.

     

Search and rescue in collapsed structures: engineering and social science aspects

This paper discusses the social science and engineering dimensions of search and rescue (SAR) in collapsed buildings. First, existing information is presented on factors that influence the behaviour of trapped victims, particularly human, physical, socioeconomic and circumstantial factors. Trapped victims are most often discussed in the context of structural collapse and injuries sustained. Most studies in this area focus on earthquakes as the type of disaster that produces the most extensive structural damage. Second, information is set out on the engineering aspects of urban search and rescue (USAR) in the United States, including the role of structural engineers in USAR operations, training and certification of structural specialists, and safety and general procedures. The use of computational simulation to link the engineering and social science aspects of USAR is discussed. This could supplement training of local SAR groups and USAR teams, allowing them to understand better the collapse process and how voids form in a rubble pile. A preliminary simulation tool developed for this purpose is described.     

Persistence of airline accidents

This paper expands on air travel accident research by examining the relationship between air travel accidents and airline traffic or volume in the period from 1927–2006. The theoretical model is based on a representative airline company that aims to maximise its profits, and it utilises a fractional integration approach in order to determine whether there is a persistent pattern over time with respect to air accidents and air traffic. Furthermore, the paper analyses how airline accidents are related to traffic using a fractional cointegration approach. It finds that airline accidents are persistent and that a (non‐stationary) fractional cointegration relationship exists between total airline accidents and airline passengers, airline miles and airline revenues, with shocks that affect the long‐run equilibrium disappearing in the very long term. Moreover, this relation is negative, which might be due to the fact that air travel is becoming safer and there is greater competition in the airline industry. Policy implications are derived for countering accident events, based on competition and regulation.     

Jailed resources: conservation of resources theory as applied to burnout among prison guards

This study evaluates a salutogenic perspective of the burnout process. Building upon Hobfoll's ( 1989 ) Conservation of Resources theory, it proposes a simultaneous test of three hypothesized resources‐based models. These competing models test the structure of burnout in relation to depleted resources (e.g., lack of skill utilization, of participation, of co‐worker support, and of professional worth) and negative correlates (e.g., absenteeism and depression). SEM results provide equally good support for two resource‐based models, although each of them proceeds from two different approaches (Leiter vs. Golembiewski). Of all burnout components, personal accomplishment is found to be least related to resources depletion, while emotional exhaustion is the most related to absenteeism and depression. Results are analyzed in light of existing literature and of the specific nature of the sample, a large population of French correctional officers (n = 707). Implications for burnout theory and human resource management are discussed. Copyright © 2006 John Wiley & Sons, Ltd.     

Character in organizational research: past directions and future prospects

Character (ethos) refers to those interpenetrable habitual qualities within individuals, and applicable to organizations that both constrain and lead them to desire and pursue personal and societal good. In our Incubator article, we undertake two objectives. First, we provide our conceptualization of character; briefly specifying what character is and is not. Second, we introduce several promising directions for organizationally based research on character. Copyright © 2008 John Wiley & Sons, Ltd.     

Model Development and Calibration of a Saltwater Intrusion Model in Southern California1

Abstract: A nine‐layered confined‐unconfined flow and transport model is developed for the Alamitos saltwater intrusion barrier in Southern California. The conceptual model is based on the geological structure of the coastal aquifer system. The key parameters in the flow and transport models are calibrated using a two‐phase procedure which matches the types of data available for calibration. Because of the abundance of point measurements of hydraulic conductivity, the heterogeneous and random hydraulic conductivity field for each of the five aquifers is estimated by the geostatiscal method of natural‐neighbor‐kriging in Phase 1. In Phase 2, the longitudinal and transverse dispersivities in the transport model are estimated by a traditional inverse procedure that minimizes the least‐squares error for concentration (LSE‐CON). The minimum LSE‐CON is achieved near 15.2 and 1.52 m for the longitudinal and transverse dispersivities, respectively. Additional simulations with increasing transport parameter complexity did not yield significant improvements in LSE‐CON. Also, tracking least‐squares error for head while parametrically varying the transport parameters revealed there is a negligible interaction between predicted head and transport parameters.     

Nonparametric Monte Carlo Simulation for Flood Frequency Curve Derivation: An Application to a Korean Watershed1

Abstract: A mix of causative mechanisms may be responsible for flood at a site. Floods may be caused because of extreme rainfall or rain on other rainfall events. The statistical attributes of these events differ according to the watershed characteristics and the causes. Traditional methods of flood frequency analysis are only adequate for specific situations. Also, to address the uncertainty of flood frequency estimates for hydraulic structures, a series of probabilistic analyses of rainfall‐runoff and flow routing models, and their associated inputs, are used. This is a complex problem in that the probability distributions of multiple independent and derived random variables need to be estimated to evaluate the probability of floods. Therefore, the objectives of this study were to develop a flood frequency curve derivation method driven by multiple random variables and to develop a tool that can consider the uncertainties of design floods. This study focuses on developing a flood frequency curve based on nonparametric statistical methods for the estimation of probabilities of rare floods that are more appropriate in Korea. To derive the frequency curve, rainfall generation using the nonparametric kernel density estimation approach is proposed. Many flood events are simulated by nonparametric Monte Carlo simulations coupled with the center Latin hypercube sampling method to estimate the associated uncertainty. This study applies the methods described to a Korean watershed. The results provide higher physical appropriateness and reasonable estimates of design flood.