全文获取类型
收费全文 | 8170篇 |
免费 | 726篇 |
国内免费 | 3349篇 |
专业分类
安全科学 | 743篇 |
废物处理 | 425篇 |
环保管理 | 645篇 |
综合类 | 5343篇 |
基础理论 | 1295篇 |
环境理论 | 2篇 |
污染及防治 | 2562篇 |
评价与监测 | 443篇 |
社会与环境 | 373篇 |
灾害及防治 | 414篇 |
出版年
2024年 | 50篇 |
2023年 | 222篇 |
2022年 | 495篇 |
2021年 | 508篇 |
2020年 | 454篇 |
2019年 | 369篇 |
2018年 | 374篇 |
2017年 | 453篇 |
2016年 | 482篇 |
2015年 | 597篇 |
2014年 | 655篇 |
2013年 | 873篇 |
2012年 | 754篇 |
2011年 | 713篇 |
2010年 | 603篇 |
2009年 | 569篇 |
2008年 | 548篇 |
2007年 | 449篇 |
2006年 | 459篇 |
2005年 | 342篇 |
2004年 | 230篇 |
2003年 | 248篇 |
2002年 | 243篇 |
2001年 | 212篇 |
2000年 | 195篇 |
1999年 | 167篇 |
1998年 | 168篇 |
1997年 | 130篇 |
1996年 | 125篇 |
1995年 | 131篇 |
1994年 | 110篇 |
1993年 | 73篇 |
1992年 | 74篇 |
1991年 | 48篇 |
1990年 | 42篇 |
1989年 | 26篇 |
1988年 | 13篇 |
1987年 | 10篇 |
1986年 | 13篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
281.
282.
283.
284.
为了科学评估京津冀区域燃煤发电行业特别排放限值和超低排放相关要求实施后的大气污染物减排效果,以行业调查数据为基础,建立了2013年和2015年京津冀区域燃煤发电行业大气污染物排放清单,分析了装机容量与SO_2、NO_x和烟尘排放量的时空耦合关系,讨论了国家相关政策和标准的实施效果。结果显示:区域内2015年燃煤机组装机容量与2013年相比略有下降,SO_2、NO_x和烟尘排放量分别下降75.95%、83.09%和71.20%,减排效果明显。2015年100 MW以下等级机组3种污染物排放总量位居各机组首位,建议通过多种合理方式压减小型燃煤发电机组数量和排放浓度。 相似文献
285.
This study aimed to reveal how amoxicillin(AMX) affected the microbial community and the spread mechanism of antibiotic resistance genes(ARGs) in the AMX manufacture wastewater treatment system. For this purpose, a 1.47 L expanded granular sludge bed(EGSB) reactor was designed and run for 241 days treating artificial AMX manufacture wastewater. 454 pyrosequencing was applied to analyze functional microorganisms in the system. The antibiotic genes OXA_(-1), OXA_(-2), OXA_(-10), TEM_(-1), CTX-M_(-1), class I integrons(intI1) and 16 SrRNA genes were also examined in sludge samples. The results showed that the genera Ignavibacterium, Phocoenobacter,Spirochaeta, Aminobacterium and Cloacibacillus contributed to the degradation of different organic compounds(such as various sugars and amines). And the relative quantification of eachβ-lactam resistance gene in the study was changed with the increasing of AMX concentration.Furthermore the vertical gene transfer was the main driver for the spread of ARGs rather than horizontal transfer pathways in the system. 相似文献
286.
Sulfur poisoning of V_2O_5/BaSO_4–TiO_2(VBT),V_2O_5/WO_3–TiO_2(VWT) and V_2O_5/BaSO_4–WO_3–TiO_2(VBWT) catalysts was performed in wet air at 350℃ for 3 hr,and activities for the selective catalytic reduction of NO_x with NH_3 were evaluated for 200–500℃.The VBT catalyst showed higher NO_x conversions after sulfur poisoning than the other two catalysts.The introduction of barium sulfate contributed to strong acid sites for the as-received catalyst,and eliminated the redox cycle of active vanadium oxide to some extent,which resulted in a certain loss of activity.Readily decomposable sulfate species formed on VBT-S instead of inactive sulfates on VWT-S.These decomposable sulfates increased the number of strong acid sites significantly.Some sulfate species escaped during catalyst preparation and barium sulfate was reproduced during sulfur poisoning,which protects vanadia from sulfur oxide attachment to a great extent.Consequently,the VBT catalyst exhibited the best resistance to sulfur poisoning. 相似文献
287.
Yunan Chen Yi Yang Bolong Xu Shunhao Wang Bin Li Juan M Jie Gao Yi Y. Zuo Sijin Liu 《环境科学学报(英文版)》2017,29(12):100-114
Environmental exposure and health risk upon engineered nanomaterials are increasingly concerned. The family of mesoporous carbon nanomaterials(MCNs) is a rising star in nanotechnology for multidisciplinary research with versatile applications in electronics,energy and gas storage, and biomedicine. Meanwhile, there is mounting concern on their environmental health risks due to the growing production and usage of MCNs. The lung is the primary site for particle invasion under environmental exposure to nanomaterials. Here, we studied the comprehensive toxicological profile of MCNs in the lung under the scenario of moderate environmental exposure. It was found that at a low concentration of 10 μg/mL MCNs induced biophysical inhibition of natural pulmonary surfactant. Moreover, MCNs at similar concentrations reduced viability of J774 A.1 macrophages and lung epithelial A549 cells.Incubating with nature pulmonary surfactant effectively reduced the cytotoxicity of MCNs.Regarding the pro-inflammatory responses, MCNs activated macrophages in vitro, and stimulated lung inflammation in mice after inhalation exposure, associated with lung fibrosis.Moreover, we found that the size of MCNs played a significant role in regulating cytotoxicity and pro-inflammatory potential of this nanomaterial. In general, larger MCNs induced more pronounced cytotoxic and pro-inflammatory effects than their smaller counterparts. Our results provided valuable information on the toxicological profile and environmental health risks of MCNs, and suggested that fine-tuning the size of MCNs could be a practical precautionary design strategy to increase safety and biocompatibility of this nanomaterial. 相似文献
288.
Ruyuan Jiao Rolando Fabris Christopher W.K. Chow Mary Drikas John van Leeuwen Dongsheng Wang Zhizhen Xu 《环境科学学报(英文版)》2017,29(7):238-245
Minimizing particles in water is a key goal for improving drinking water quality and safety.The media filtration process,as the last step of the solid–liquid separation process,is largely influenced by the characteristics of flocs,which are formed and controlled within the coagulation process.In a laboratory-based study,the impacts of the physical characteristics of flocs formed using aluminum sulfate on the filtration treatment of two comparative water samples were investigated using a photometric dispersion analyzer and a filterability apparatus.In general,the optimum dosage for maximizing filterability was higher than that for minimizing turbidity under neutral p H conditions.For a monomeric aluminum-based coagulant,the charge neutralization mechanism produced better floc characteristics,including floc growth speed and size,than the sweep flocculation mechanism.In addition,the charge neutralization mechanism showed better performance compared to sweep flocculation in terms of DOC removal and floc filterability improvement for both waters,and showed superiority in turbidity removal only when the raw water had high turbidity.For the different mechanisms,the ways that floc characteristics impacted on floc filterability also differed.The low variation in floc size distribution obtained under the charge neutralization mechanism resulted in the flocs being amenable to removal by filtration processes.For the sweep flocculation mechanism,increasing the floc size improved the settling ability of flocs,resulting in higher filter efficiency. 相似文献
289.
为了识别恶臭污染源排放特征以及了解不同行业恶臭物质排放差异,对恶臭污染排放源指纹谱指标物质进行了筛选,并依据筛选结果对6家典型恶臭排放企业进行样品采集及分析,绘制了各家企业的指纹谱图.结果表明:①通过物质嗅觉阈值与AMGE(ambient multimedia environmental goals,周围环境目标值)和RfC(reference concentration,健康风险参考浓度)对比以及结合国内外恶臭标准受控物质和现有的标准检测方法,最终确定了包括三甲胺、硫化氢、甲硫醇等典型恶臭物质在内的19种物质作为指纹谱指标物质.②依据我国现行的标准监测分析方法对19种恶臭指标物进行检测,初步得到了各家企业的恶臭物质指纹谱数据,绘制了各家企业的指纹谱图.③指纹谱成分分析结果显示,污水处理厂主要的恶臭物质是硫化氢,ρ(硫化氢)为44.566 mg/m3;涂料企业ρ(甲基乙基酮)、ρ(丁醛)和ρ(乙酸乙酯)较高,分别为39.037、28.757、27.840 mg/m3;制药企业ρ(丙醛)较高,为4.791 mg/m3;汽车和家具制造企业ρ(二甲苯)较高,分别为15.209和2.081 mg/m3.④应用分歧系数法分析不同企业指纹谱之间的相似程度,分析结果显示,分歧系数在0.331~0.809之间,不同企业之间指纹谱存在较大差异.研究显示,建立恶臭污染排放源指纹谱可进行恶臭源排放特征识别,为恶臭污染溯源提供基础数据和科学依据. 相似文献
290.