全文获取类型
收费全文 | 8114篇 |
免费 | 733篇 |
国内免费 | 3071篇 |
专业分类
安全科学 | 743篇 |
废物处理 | 425篇 |
环保管理 | 645篇 |
综合类 | 5295篇 |
基础理论 | 1295篇 |
环境理论 | 2篇 |
污染及防治 | 2284篇 |
评价与监测 | 442篇 |
社会与环境 | 373篇 |
灾害及防治 | 414篇 |
出版年
2024年 | 40篇 |
2023年 | 178篇 |
2022年 | 482篇 |
2021年 | 489篇 |
2020年 | 439篇 |
2019年 | 354篇 |
2018年 | 359篇 |
2017年 | 424篇 |
2016年 | 390篇 |
2015年 | 536篇 |
2014年 | 651篇 |
2013年 | 869篇 |
2012年 | 750篇 |
2011年 | 712篇 |
2010年 | 602篇 |
2009年 | 569篇 |
2008年 | 548篇 |
2007年 | 449篇 |
2006年 | 459篇 |
2005年 | 342篇 |
2004年 | 230篇 |
2003年 | 248篇 |
2002年 | 243篇 |
2001年 | 212篇 |
2000年 | 195篇 |
1999年 | 167篇 |
1998年 | 168篇 |
1997年 | 130篇 |
1996年 | 125篇 |
1995年 | 131篇 |
1994年 | 110篇 |
1993年 | 73篇 |
1992年 | 74篇 |
1991年 | 48篇 |
1990年 | 42篇 |
1989年 | 26篇 |
1988年 | 13篇 |
1987年 | 10篇 |
1986年 | 13篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 427 毫秒
751.
Gas/particle partitioning of atmospheric PCDD/Fs in a satellite town in Eastern China 总被引:3,自引:0,他引:3
Meng-xia Xu Jian-hua Yan Sheng-yong Lu Xiao-dong Li Tong Chen Ming-jiang Ni Hui-fen Dai Fei Wang Ke-fa Cen 《Chemosphere》2009,76(11):1540-1549
Gas/particle partitioning of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in ambient air was investigated in a satellite town in Eastern China from April 2007 to January 2008 comprehending large temperature variations (from 3 to 34 °C, daily average). Molecular weight, molecular structure and ambient temperatures are the three major factors that govern the gas/particle partitioning of atmospheric PCDD/Fs throughout the year. Generally, good agreements were obtained (except for winter) between measured particulate fractions and theoretical estimates of both the Junge–Pankow adsorption model and Harner Bidleman absorption model using different sets of subcooled liquid vapor pressure and octanol–air partition coefficient (Koa), respectively. Models utilizing estimates, derived from gas chromatographic retention indices (GC-RIs), are more accurate than that of entropy-based. Moreover, during winter, the Koa-based model using the GC-RIs approach performs better on lower chlorinated PCDD/Fs than that of -based. Furthermore, possible sources of mismatch between measured and predicted values in winter (3–7 °C) were discussed. Gas adsorption artifact was demonstrated to be of minor importance for the phenomena observed. On the other hand, large deviations of slopes (mr) and intercepts (br) in logKp vs. plots from theoretical values are observed in the literature data and these are found to be linearly correlated with ambient temperatures (P<0.001) in this study. This indicates that the non-equilibrium partitioning of PCDD/Fs in winter may be significantly influenced by the colder temperatures that may have slowed down the exchange between gaseous and particulate fractions. 相似文献
752.
As one of China’s great metropolises, Taiyuan is affected by heavy chemical industry and manufacture of chemical products, and faces pollution from polychlorinated biphenyls (PCBs). Therefore, this study was conducted to determine the PCB concentrations in various environmental media in Taiyuan. We collected 15 soil samples, 34 respirable particulate matter (PM) samples (17 of PM2.5 and 17 of PM10) from urban areas of Taiyuan, and measured a total of 144 PCB congeners (including some coeluting PCB congeners). The total PCB concentrations were 51–4.7 × 103 pg g−1 in soil, 27–1.4 × 102 pg m−3 in PM2.5 and 16–1.9 × 102 pg m−3 in PM10. Of the PCB homologues, the dominant PCBs detected in the various media were all tri-CBs. Soil was relatively the most polluted media. Furthermore, principal-component analysis revealed that the major PCB source in Taiyuan may be associated with the main commercial PCB through long-range transmission. Toxic equivalency (TEQ) concentrations (based on ten dioxin-like PCBs) ranged from N.D. to 5.9 × 10−3 pg-WHO TEQ g−1 in soil, 2.0 × 10−4–3.4 × 10−3 pg-WHO TEQ m−3 and 1.0 × 10−4–1.2 × 10−3 pg-WHO TEQ m−3 in PM2.5 and PM10, respectively. In previous studies, PCBs were not a severe component of contaminant in Taiyuan; however, this study suggested there is a potential threat of human exposure to PCBs for residents of Taiyuan. 相似文献
753.
Qiu Cai Mei-Li Long Ming Zhu Qing-Zhen Zhou Ling Zhang Jie Liu 《Environmental pollution (Barking, Essex : 1987)》2009,157(11):3078-3082
Cadmium (Cd) and Lead (Pb) are environmental pollutants. Environmental samples and bovine tissues were collected from the areas around a lead–zinc smelter in Guizhou, China for Cd, Pb, zinc (Zn) and copper (Cu) analysis. Cd in soil (10 mg/kg) and feed (6.6 mg/kg) from the polluted areas was 10 times higher than the Chinese Standards, resulting in higher Cd in bovine kidney (38 mg/kg) and liver (2.5 mg/kg). Pb in feed (132 mg/kg) from the polluted area was much higher than unpolluted areas, causing higher Pb levels in bovine tissues. Environmental Zn was elevated, but bovine tissue Zn was normal. Cu in bovine liver decreased with increased Cd and Pb. Metals in drinking water and in bovine muscle were within the Standard range. Thus, in the areas of this lead–zinc smelter, the environment has been contaminated with Cd and Pb, which has been transferred to cattle through the food chain. 相似文献
754.
Chaosheng Zhang Ya Tang Lin Luo Weilin Xu 《Environmental pollution (Barking, Essex : 1987)》2009,157(11):3083-3090
Outliers in urban soil geochemical databases may imply potential contaminated land. Different methodologies which can be easily implemented for the identification of global and spatial outliers were applied for Pb concentrations in urban soils of Galway City in Ireland. Due to its strongly skewed probability feature, a Box–Cox transformation was performed prior to further analyses. The graphic methods of histogram and box-and-whisker plot were effective in identification of global outliers at the original scale of the dataset. Spatial outliers could be identified by a local indicator of spatial association of local Moran's I, cross-validation of kriging, and a geographically weighted regression. The spatial locations of outliers were visualised using a geographical information system. Different methods showed generally consistent results, but differences existed. It is suggested that outliers identified by statistical methods should be confirmed and justified using scientific knowledge before they are properly dealt with. 相似文献
755.
756.
氟化铝是铝电解生产的主要原料之一,它的品质好坏直接影响着生产过程中污染物氟化氢的产生量。文章通过分析干、湿法氟化铝在铝电解生产使用中分别对氟化氢产生量的影响,建议推广干法氟化铝在铝电解生产中的应用,从而实现经济效益和环境效益双赢的目标。 相似文献
757.
认真落实科学发展观,以科学发展观统领工会工作,必须体现在党对工会工作的要求上,体现在准确全面履行好工会的职责上,从而充分发挥工会在支持改革开放、促进经济发展、推动社会进步中的积极作用。 相似文献
758.
微波无极紫外光催化-内电解协同降解活性艳红X-3B 总被引:5,自引:1,他引:4
采用微波无极紫外光源,以活性炭作为光催化剂TiO2的载体,与外加铁屑构成内电解反应,处理活性艳红X-3B模拟废水.实验结果表明,微波无极紫外光催化-内电解法对活性艳红X-3B的降解速率是微波无极紫外光催化和微波-内电解法单独作用时降解速率之和的2倍.在活性艳红X-3B模拟废水初始pH为7、空气曝气量为0.50 L/min、铁屑加入量为5 g/L、反应温度为40~45℃的最佳条件下,微波无极紫外光催化-内电解法的活性艳红X-3B模拟废水色度去除率达100%,TOC和可吸附有机卤化物的去除率分别为69.5%和81.8%. 相似文献
759.
NaCl和KCl对厌氧污泥抑制的动力学研究 总被引:2,自引:0,他引:2
在厌氧颗粒污泥和厌氧絮状污泥系统中,进行盐质量浓度(NaCl或KCl质量浓度,下同)对厌氧污泥抑制动力学的研究,得到不同拟合的COD降解动力学方程及参数.实验结果表明:当盐质量浓度为10~30 g/L时,KCl对厌氧污泥的COD比降解速率的抑制程度大于NaCl;当盐质量浓度由0 g/L增至10 g/L时,半速率常数逐渐增加;当盐质量浓度由10 g/L增至30 g/L时,半速率常数逐渐减小;在厌氧污泥系统中,NaCl抑制作用下的盐抑制常数高于KCl,且颗粒污泥的盐抑制常数高于絮状污泥. 相似文献
760.