全文获取类型
收费全文 | 8114篇 |
免费 | 733篇 |
国内免费 | 3071篇 |
专业分类
安全科学 | 743篇 |
废物处理 | 425篇 |
环保管理 | 645篇 |
综合类 | 5295篇 |
基础理论 | 1295篇 |
环境理论 | 2篇 |
污染及防治 | 2284篇 |
评价与监测 | 442篇 |
社会与环境 | 373篇 |
灾害及防治 | 414篇 |
出版年
2024年 | 40篇 |
2023年 | 178篇 |
2022年 | 482篇 |
2021年 | 489篇 |
2020年 | 439篇 |
2019年 | 354篇 |
2018年 | 359篇 |
2017年 | 424篇 |
2016年 | 390篇 |
2015年 | 536篇 |
2014年 | 651篇 |
2013年 | 869篇 |
2012年 | 750篇 |
2011年 | 712篇 |
2010年 | 602篇 |
2009年 | 569篇 |
2008年 | 548篇 |
2007年 | 449篇 |
2006年 | 459篇 |
2005年 | 342篇 |
2004年 | 230篇 |
2003年 | 248篇 |
2002年 | 243篇 |
2001年 | 212篇 |
2000年 | 195篇 |
1999年 | 167篇 |
1998年 | 168篇 |
1997年 | 130篇 |
1996年 | 125篇 |
1995年 | 131篇 |
1994年 | 110篇 |
1993年 | 73篇 |
1992年 | 74篇 |
1991年 | 48篇 |
1990年 | 42篇 |
1989年 | 26篇 |
1988年 | 13篇 |
1987年 | 10篇 |
1986年 | 13篇 |
1985年 | 7篇 |
1984年 | 3篇 |
1983年 | 5篇 |
1982年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 312 毫秒
891.
892.
Climate change and human disturbance drive catchment erosion and increase riverine sediment load sensitively in small and
medium-sized watersheds. This is not always true in large basins, where aggregation and buffering effects have dampen the
ability to determine the driving forces of sedimentation. Even though there are significant responses to sedimentation in
large river basins, it is difficult to get a precise quantitative assessment of specific drivers. This paper develops a methodology
to identify driving forces that change suspended sediment load in the Upper Yangtze river. Annual runoff and sediment load
data from 1954 to 2005 at the Yichang gauging station in the Upper Yangtze basin, daily precipitation data from 60 meteorological
stations, and survey data on reservoir sediment were collected for the study. Sediment load/rainfall erosivity (S/R), is a
new proxy indicator introduced to reflect human activities. Since the mid-1980s, S/R in the Upper Yangtze has dramatically
declined from 0.21 to 0.03 (×1010 t ha h MJ−1 mm−1), indicating that human activity has played a key role in the decline of the suspended sediment load. Before the mid-1980s,
a higher average S/R is attributed to large-scale deforestation and land reclamation. A significant sediment decrease occurred
from 1959 to 1961 during an extreme drought condition, and an increase in sedimentation in 1998 coincided with an extreme
flood event, which was well recorded in the S/R curve. This indicates that the S/R proxy is able to distinguish anthropogenic
from climate impacts on suspended sediment load, but is not necessarily indicatory in extreme climate events. In addition,
typical drivers of riverine sediment load variation including soil conservation projects, reservoirs construction, and land
use/cover change are discussed. 相似文献
893.
This study projected responses of forest net primary productivity (NPP) to three climate change scenarios at a resolution
of 5 km × 5 km across the state of Louisiana, USA. In addition, we assessed uncertainties associated with the NPP projection
at the grid and state levels. Climate data of the scenarios were derived from Community Climate System Model outputs. Changes
in annual NPP between 2000 and 2050 were projected with the forest ecosystem model PnET-II. Results showed that forest productivity
would increase under climate change scenarios A1B and A2, but with scenario B1, it would peak during 2011–2020 and then decline.
The projected average NPP under B1 over the years from 2000 to 2050 was significantly different from those under A1B and A2.
Forest NPP appeared to be primarily a function of temperature, not precipitation. Uncertainties of the NPP projection were
due to large spatial resolution of the climate variables. Overall, this study suggested that in order to project effects of
climate change on forest ecosystem at regional level, modeling uncertainties could be reduced by increasing the spatial resolution
of the climate projections. 相似文献
894.
Salicylic acid involved in the regulation of nutrient elements uptake and oxidative stress in Vallisneria natans (Lour.) Hara under Pb stress 总被引:1,自引:0,他引:1
In this study, the alterations in nutrient elements content, reactive oxygen species level and antioxidant response were studied in leaves of Vallisneria natans (Lour.) Hara exposed to salicylic acid (SA, 10 or 100 μM), or Pb (50 μM) or their combinations for 4 d. No significant alterations in Mn and Ca content were observed but content of Cu, Zn, Fe and P decreased in plants exposed to SA alone. SA application inhibited the uptake of Pb and partially reversed Pb-induced the alterations in Mn, Ca and Fe content in leaves of V. natans exposed to 50 μM Pb. The decreased chlorophyll (a + b) and increased malondialdehyde and O2− and H2O2 content were detected in plants exposed to 100 μM SA, 50 μM Pb, 10 μM SA + 50 μM Pb or 100 μM SA + 50 μM Pb. Application SA partially inhibited Pb-induced the increase of malondialdehyde, O2− and H2O2 content. 100 μM SA decreased the activity of NADH oxidase and the content of non-protein thiols, carotenoids and ascorbic acid and increased the content of dehydroascorbate in plants treated with or without Pb. SA alone decreased the ascorbate peroxidase activity and increased the catalase and peroxidase activity, while SA application increased catalase activity but had no significant effect on ascorbate peroxidase and peroxidase activity in V. natans exposed to Pb. The results indicate that SA involves in the regulation of Pb uptake, nutrient balance and oxidative stress. 相似文献
895.
Chlortoluron chlorination is studied in the pH range of 3-10 at 25 ± 1 °C. The chlorination kinetics can be well described by a second-order kinetics model, first-order in chlorine and first-order in chlortoluron. The apparent rate constants were determined and found to be minimum at pH 6, maximum at pH 3 and medium at alkaline conditions. The rate constant of each predominant elementary reactions (i.e., the acid-catalyzed reaction of chlortoluron with HOCl, the reaction of chlortoluron with HOCl and the reaction of chlortoluron with OCl−) was calculated as 3.12 (± 0.10) × 107 M−2 h−1, 3.11 (±0.39) × 102 M−1 h−1 and 3.06 (±0.47) × 103 M−1 h−1, respectively. The main chlortoluron chlorination by-products were identified by gas chromatography-mass spectrometry (GC-MS) with purge-and-trap pretreatment, ultra-performance liquid chromatography-electrospray ionization-MS and GC-electron capture detector. Six volatile disinfection by-products were identified including chloroform (CF), dichloroacetonitrile, 1,1-dichloropropanone, 1,1,1-trichloropropanone, dichloronitromethane and trichloronitromethane. Degradation pathways of chlortoluron chlorination were then proposed. High concentrations of CF were generated during chlortoluron chlorination, with maximum CF yield at circumneutral pH range in solution. 相似文献
896.
The Quick Easy Cheap Effective Rugged and Safe multiresidue method (QuEChERS) has been validated for the extraction of 15 organochlorine pesticides (OCPs) in completely different matrices of traditional Chinese medicine (TCM). The method employed a rapid, simple and cost-effective procedure. The spiking levels for the recovery experiments were 0.1, 0.5 and 2.0 mg kg−1. Mean recoveries mostly ranged between 76.0% and 114.0% (96.0% on average), and relative standard deviations (RSD) were generally below 10% (4.72% on average). Based on these results, the methodology has been proven to be highly efficient and robust and thus suitable for monitoring the MRL compliance of a wide range of commodity. The contamination status of 15 OCPs on 80 different TCMs marketed in China, and a total of 400 samples were also performed using a previously validated method. 15 OCPs were benzene hexachloride (BHC, including α-BHC, β-BHC, γ-BHC, δ-BHC), hexachlorobenzene, heptachlor, heptachlor epoxide, aldrin, p, p′-DDE, p, p′-DDD, o, p′-DDT, p, p′-DDT, mirex, endrin, dieldrin. This study indicates that the proposed method is useful for analyzing OCPs in TCM. 相似文献
897.
898.
899.
900.