粉状活性焦在双层滤料颗粒床中的脱硫试验研究

在双层滤料颗粒床模型试验台上对粒径为300～400目的粉状活性焦进行了脱硫试验,研究了温度、O2和水蒸气体积分数、气体流速、再生次数对脱硫效果的影响.试验结果表明.温度为120℃、O2体积分数为8%、水蒸气体积分数为10%条件下,脱硫效果最好;粉状活性焦在双层滤料颗粒床中经过7次重复吸附.达到硫饱和吸附量为66.2 mg/g.粉状活性焦再生试验表明,随着再生次数的增加.粉状活性焦的脱硫性能呈下降趋势.     

铜氰溶液的电子束辐照降解

研究了铜氰溶液中总氰初始浓度、pH、铜浓度等对总氰降解效率的影响,比较了KCN溶液和铜氰溶液的总氰降解率,初步推断了铜氰溶液在辐照过程中的降解机制.实验结果表明,在同样的辐照剂量下,随着总氰初始浓度的增加,总氰降解率降低,相应的总氰降解G值增大;铜浓度越低,总氰降解率越高;pH越小的铜氰溶液总氰降解率越高.电子束辐照KCN溶液和铜氰溶液的总氰降解反应属于表观一级反应.在相同的辐照剂量下,KCN溶液的总氰降解率比铜氰溶液要高得多.铜氰溶液的电子束辐照降解过程非常复杂,主要是铜氰络合离子逐步离解出的CN-与·OH的反应.     

公路地表灰尘及径流中颗粒物附着重金属对比研究

对北京城区北三环上北太平桥以西约300 m处路段地表灰尘及径流中不同粒径颗粒物附着重金属载荷进行对比研究.结果表明:(1)随着颗粒物粒径的增大,地表灰尘中颗粒物附着重金属浓度总体上逐渐降低;地表灰尘中<40.00 μm颗粒物附着重金属浓度最高;重金属载荷分布集中度不强,但主要集中在地表灰尘中<300.00 μm的颗粒物L.(2)地表径流中大部分重金属附着在<125.00 μm颗粒物上;0.45～10.00 μm颗粒物附着重金属载荷最高;0.45～40.00 μm颗粒物附着重金属载荷平均为77.1%.(3)地表灰尘中<40.00 μm的颗粒物的潜在水环境风险不太突出,但是其实际水环境影响却起主导作用.(4)进入水体的小粒径颗粒物质量分数升高是地表灰尘和径流重金届载荷随颗粒物粒径分布不同的重要原因之一;大气湿沉降对小粒径颗粒物重金属载荷可能会有一定的影响.     

竹炭-微生物联合法对沼液中氨氮的去除

采用竹炭-微生物联合法,考察了竹炭用量、菌液用量、进水氨氮浓度、pH、DO、HRT等因素对氨氮废水处理效果的影响;同时采用对比实验,初步探讨了竹炭-微生物联合法处理沼液的作用机理。结果表明,竹炭-微生物法去除沼液氨氮的最优条件推荐为:竹炭用量30 g/L,微生物活性液用量3%,pH 7.0～8.0,DO为2 mg/L,HRT为48 h。竹炭-微生物法对沼液氨氮的去除过程可用一级反应动力学模型C=272.56e-0.0148描述,其去除效果来源于竹炭吸附和生物降解的协同作用,协同程度为48.45%。     

表面活性剂加强动电技术去除污泥中铜和镉

以实际城市污泥为研究对象,通过采用表面活性剂作为阴极液,并考虑阴极液pH值、表面活性剂类型和电压3种因素对动电技术去除污泥中重金属(铜和镉)的影响,选用正交试验确定最佳试验条件.结果表明,采用表明活性剂作为阴极液加强动电技术去除污泥中重金属足可行的,铜和镉的去除率分别达到11.1%～52.6%和9.1%～46.7%.通过对正交试验结果进行极差和方差分析,试验的最佳条件为:电压为20 V,阴极液加入十六烷基三甲基氯化铵并控制pH值为4～6.表面活性剂的类型对动电技术去除镉具有显著影响.其中,表面活性剂类型对动电过程的影响最大,阴极液pH值次之,电压影响最小.     

The sedimentation capabilities of hexadecyltrimethylammonium-modified montmorillonites

Natural montmorillonite was modified with a quaternary ammonium compound, hexadecyltrimethylammonium (HDTMA). The sedimentation capabilities of unmodified and modified montmorillonites were then investigated. The sedimentation velocity of modified montmorillonites increased if the amounts of adsorbed HDTMA were from 0.3 to 1.0 times the cation exchange capacitity (CEC). It also emerged that the sedimentation capability of modified montmorillonites was improved and that the variously CEC-modified montmorillonites had similar sedimentation capabilities after they had sorbed organic matter from oily wastewater. Thus, modified montmorillonites (especially 0.5 CEC treatment) had good sedimentation capabilities for sorbing organic substance and can act as carriers in wastewater biotreatment.     

污水低氧脱氮机制及其应用研究进展

阐述了污水低氧脱氮的基本原理,即抑制或去除亚硝酸盐氧化菌(NOB),同时保留氨氧化菌(AOB),并保持其活性;探讨了污水低氧脱氮实现途径;详细介绍了几种典型的污水低氧脱氮工艺(短程硝化(SHARON)工艺、厌氧氨氧化(ANAMMOX)工艺、好氧反氨化(DEMON)工艺、低氧自养硝化反硝化(OLAND)工艺、甲烷营养型硝化反硝化工艺和亚硝酸盐型完全自养脱氮(CANNON)工艺)的应用研究进展;最后对污水低氧脱氮处理工艺的工程运用进行了展望.     

二段生物接触氧化工艺在中水回用中的特性研究

以规模小区生活污水为水源,对采用聚丙烯网状填料和强化炉渣组合填料的二段生物接触氧化工艺（以下简称二段法）进行了试验研究,试验针对本工艺的各项技术指标、影响因素以及各相关参数进行了较系统的试验测试。结果表明,反应器在第一接触氧池HRT为20 min、气水比为6∶1和第二接触氧池HRT为25 min、气水比为5∶1条件下,接触氧化池达到最佳降碳条件;反应器在第一接触沉池上升流速5.5 m/h和第二接触沉池上升流速4.5 m/h条件下,接触沉淀池达到最佳处理条件。     

重铬酸钾─三氯化钛法测定水中溶解氧

介绍了三氯化钛（ＴｉＣｌ３）与氧反应，以钨酸钠（Ｎａ２ＷＯ４）作指示剂，用重铬酸钾溶液滴定过剩三氯化钛来测定水中溶解氧的方法。本法与碘量法比较，结果表明方法准确、快速，适合于水样中溶解氧的测定     

Adsorption-desorption characteristics of mercury in paddy soils of China

Mercury (Hg) has received considerable attention because of its association with various human health problems. Adsorption-desorption behavior of Hg at contaminated levels in two paddy soils was investigated. The two representative soils for rice production in China, locally referred to as a yellowish red soil (YRS) and silty loam soil (SLS) and classified as Gleyi-Stagnic Anthrosols in FAO/UNESCO nomenclature, were respectively collected from Jiaxin County and Xiasha District of Hangzhou City, Zhejiang Province. The YRS adsorbed more Hg(2+) than the SLS. The characteristics of Hg adsorption could be described by the simple Langmuir adsorption equation (r2 = 0.999 and 0.999, P < 0.01, respectively, for the SLS and YRS). The maximum adsorption values (Xm) that were obtained from the simple Langmuir model were 111 and 213 mg Hg(2+) kg(-1) soil, respectively, for the SLS and YRS. Adsorption of Hg(2+) decreased soil pH by 0.75 unit for the SLS soil and 0.91 unit for the YRS soil at the highest loading. The distribution coefficient (kd) of Hg in the soil decreased exponentially with increasing Hg(2+) loading. After five successive desorptions with 0.01 mol L(-1) KCl solution (pH 5.4), 0 to 24.4% of the total adsorbed Hg(2+) in the SLS soil was desorbed and the corresponding value of the YRS soil was 0 to 14.4%, indicating that the SLS soil had a lower affinity for Hg(2+) than the YRS soil at the same Hg(2+) loading. Different mechanisms are likely involved in Hg(2+) adsorption-desorption at different levels of Hg(2+) loading and between the two soils.