Managing agricultural emissions to the atmosphere: state of the science, fate and mitigation, and identifying research gaps

The impact of agriculture on regional air quality creates significant challenges to sustainability of food supplies and to the quality of national resources. Agricultural emissions to the atmosphere can lead to many nuisances, such as smog, haze, or offensive odors. They can also create more serious effects on human or environmental health, such as those posed by pesticides and other toxic industrial pollutants. It is recognized that deterioration of the atmosphere is undesirable, but the short- and long-term impacts of specific agricultural activities on air quality are not well known or understood. These concerns led to the organization of the 2009 American Chemical Society Symposium titled . An outcome of this symposium is this special collection of 14 research papers focusing on various issues associated with production agriculture and its effect on air quality. Topics included emissions from animal feeding operations, odors, volatile organic compounds, pesticides, mitigation, modeling, and risk assessment. These papers provide new research insights, identify gaps in current knowledge, and recommend important future research directions. As the scientific community gains a better understanding of the relationships between anthropogenic activities and their effects on environmental systems, technological advances should enable a reduction in adverse consequences on the environment.     

Overview of state approaches to vapor intrusion

A large number of states have issued guidance addressing the vapor intrusion pathway making it difficult to keep up with various policies and requirements. We have compiled and reviewed guidance from 35 states, half of which have issued documents within the last three years. A comparison of policies among states shows reasonable consistency in some areas—for example, 20 of 23 states that provide an exclusion distance for subsurface sources of chlorinated volatile organic compounds (VOCs) use a distance of 100 feet. However, more commonly, the policy decisions vary widely. Among states, indoor air screening concentrations for the same VOC vary by more than 2,000 times and subsurface screening concentrations vary by more than 2,000,000 times. These wide discrepancies suggest a need for communication and consensus building in order to increase consistency in the management of the vapor intrusion pathway. © 2012 Wiley Periodicals, Inc.     

Estimating the effectiveness of vegetated floodplains/ wetlands as nitrate-nitrite and orthophosphorus filters

The role of vegetated floodplains/wetlands on the stream water quality of agro-ecosystems in the Coastal Plain region of the southeastern United States is reported. Water-borne nitrate plus nitrite nitrogen budgets and orthophosphate phosphorus budgets from a cropped agricultural area were compared with those of a watershed with alluvial forests below the cropped areas. Analyses were made to determine if observed differences in nutrient concentrations and loads were the result of dilution of cropped area runoff by flows from non-cropped areas. Reductions in the observed levels of nitrate plus nitrite nitrogen and orthophosphate phosphorus between upland cropped areas and watershed outlets exceed reductions that would be caused by dilution effects. Significant portions of the observed nutrients leaving cropped areas were retained, utilized and/or transformed in the vegetated floodplains/wetlands characteristic of these Coastal Plain watersheds.     

Effects of environmental factors on 1,3-dichloropropene hydrolysis in water and soil

Hydrolysis is the major pathway for fumigant 1,3-dichloropropene (1,3-D) degradation in water and soil, yet the process is not well understood. Experiments were conducted to investigate the effect of various environmental factors on the rate of 1,3-D hydrolysis. Cis-, trans-1,3-D and their isomeric mixture were spiked into water and Arlington soil (coarse-loamy, mixed, thermic Haplic Durixeralfs) and incubated under different conditions. The rate of 1,3-D hydrolysis in water and soil were evaluated based on its residual amount and Cl- release, respectively. 1,3-D hydrolyzed rapidly in deionized water, with a half-life of 9.8 d at 20 degrees C. The hydrolysis was pH dependent, with low pH inhibiting and high pH favoring the reaction. Other factors such as isomeric differences, photo irradiation, suspended particles, and small amounts of co-solutes had little effect on the reaction. In soil, 1,3-D hydrolyzed following pseudo first-order kinetics. The hydrolysis rate constant increased with soil moisture content and decreased with the initial 1,3-D concentration. At 20 degrees C, > 60% of the 1,3-D applied at < 0.61 g kg(-1) in 10% moisturized soil hydrolyzed within 30 d. The soil particle size and mineralogy had little effect on the reaction rate. Organic matter promoted 1,3-D degradation via direct substitution reactions, and the trans-isomer showed preference over the cis- to react with certain organic molecules. Microbial contributions were initially insignificant, and became important as soil microorganisms adapted to the fumigant. The results suggest that to accelerate 1,3-D degradation, pH, soil moisture, and organic amendment should be considered.     

Chlorinated solvents: will the alternatives be safer?

Over the next decade, use of chlorinated solvents, a widely employed class of chemicals, will decline significantly because of increasingly stringent environmental regulations. These solvents pose certain health and environmental problems and they have been heavily scrutinized. The alternatives to the solvents are being adopted without controls. In some cases, these substances will pose other health and environmental problems that are likely to be as serious; in other cases, the alternatives have not been examined for their health and environmental effects at all. This case study demonstrates that regulations on chlorinated solvents and their potential alternatives are inconsistent with one another and conflicting.     

Modeling economy-wide climate change impacts on Egypt: A case for an integrated approach

This study looks at the role of biophysical sectors and world markets on an integrated economic assessment of climate change impacts on Egypt. Using the outcome from Global Circulation Models (GCMs) and a global model of world food trade (the Basic Linked System; BLS) — changes in crop yields; crop water demands; water and land resource availability; and world market prices were applied to a dynamic, computable general equilibrium model of Egypt (the Standard National Model of the BLS). Modeling results consistently showed that the net effect of climate change on the macro indicator of per capita GDP was not great — regardless of the level of integration. This outcome was only realized through autonomous economic adjustments which implied significant socio-economic and structural change. Including or excluding certain biophysical sectors and world markets influenced the development path and the nature of the autonomous adjustments. The importance of a particular biophysical sector or of world markets was also dependent upon the specific climate change scenario.