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821.
三峡工程运用后洞庭湖水沙情势变化及其影响初步分析 总被引:3,自引:0,他引:3
采用原型资料分析、长河段一维数学模型计算等手段,分析和预测了三峡工程运用对洞庭湖水沙与冲淤影响,研究了三峡工程运用对洞庭湖出口水位的影响,在此基础上初步分析了三峡工程运用对湖区防洪与生态环境影响。研究成果表明:三峡水库运用后30 a末,荆江三口年均分流量和分沙量比多年平均值分别减少43%和73%,三口分流道的河床相应发生冲淤变化;三峡工程运用后,受荆江三口分流比减少影响,洞庭湖区泥沙淤积显著减少,对增强洞庭湖区调蓄功能、延长洞庭湖寿命有利;受三峡水库调度运用与长江干流河道冲刷影响,洞庭湖出口水位以下降为主,汛期水位的下降将对湖区防洪有利,而枯期水位的下降将对湖区水资源利用及生态环境带来一定不利影响。 相似文献
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823.
不同混合比牛粪玉米秸中温干发酵产沼性能 总被引:4,自引:1,他引:3
设置5组牛粪和玉米秸的混合物(干物质比为0∶1、1∶0、1∶1、1∶2、2∶1),研究其在中温35℃下干发酵产沼性能,以产沼性能最好实验组的实验数据为基础,对比研究了两类产气模型。研究结果显示:玉米秸与牛粪的混合干发酵运行效果较好;其中,牛粪和玉米秸干物质比为2∶1时产沼效果最好,产气量最高为81 209 mL,干物质产气率为0.312 m3/kg,整个发酵过程中产气量和甲烷的含量比较稳定,CH4含量最高达56.59%,总固体、挥发性固体的去除率相对较高,分别为26.11%和34.27%。一级动力学模型与多项式函数方程2个产气模型拟合检验结果显示,应用简单的多项式函数即可对产气情况进行相对准确的预测。 相似文献
824.
825.
Selective redox degradation of chlorinated aliphatic compounds by Fenton reaction in pyrite suspension 总被引:1,自引:0,他引:1
Selective redox degradation of chlorinated aliphatics by Fenton reaction in pyrite suspension was investigated in a closed system. Carbon tetrachloride (CT) was used as a representative target of perchlorinated alkanes and trichloroethylene (TCE) was used as one of highly chlorinated alkenes. Degradation of CT in Fenton reaction was significantly enhanced by pyrite used as an iron source instead of soluble Fe. Pyrite Fenton showed 93% of CT removal in 140 min, while Fenton reaction with soluble Fe(II) showed 52% and that with Fe(III) 15%. Addition of 2-propanol to the pyrite Fenton system significantly inhibited degradation of TCE (99% to 44% of TCE removal), while degradation of CT was slightly improved by the 2-propanol addition (80-91% of CT removal). The result suggests that, unlike oxidative degradation of TCE by hydroxyl radical in pyrite Fenton system, an oxidation by the hydroxyl radical is not a main degradation mechanism for the degradation of CT in pyrite Fenton system but a reductive dechlorination by superoxide can rather be the one for the CT degradation. The degradation kinetics of CT in the pyrite Fenton system was decelerated (0.13-0.03 min−1), as initial suspension pH decreased from 3 to 2. The formation of superoxide during the CT degradation in the pyrite Fenton system was observed by electron spin resonance spectroscopy. The formation at initial pH 3 was greater than that at initial pH 2, which supported that superoxide was a main reductant for degradation of CT in the pyrite Fenton system. 相似文献
826.
Sanctorum H Elskens M Leermakers M Gao Y Charriau A Billon G Goscinny S De Cooman W Baeyens W 《Chemosphere》2011,85(2):203-209
PAHs, PCDD/Fs and non-ortho PCBs have been assessed in Yser and Upper-Scheldt river sediments. Higher contamination levels were observed in the Upper-Scheldt sediments: maximum concentrations for the 16 US-EPA PAHs, PCDD/Fs and non-ortho PCBs respectively amount to 8.9 mg kg−1, 12 ng TEQ kg−1 and 5.1 ng TEQ kg−1. Diagnostic PAH ratios in sediments and atmospheric samples suggest that the PAH compounds are from pyrolytic origin, more specifically combustion processes. The huge consumption of coal in cokes-ovens and smelters and its use for house-heating in Northern France, although decreasing during the last decades, are in support of that suggestion. PCDD/F fingerprints in sediments and deposition material indicate that OCDD is the dominant congener. In addition use of pentachlorophenol (PCP) in the past led to a minor contribution of PCDD/Fs in our sediment samples. Non-ortho PCBs form a substantial fraction of the total TEQ concentrations observed in the sediments. Since the 1980s and 1990s a substantial reduction of the PCDD/F sediment concentrations is observed, but this is not the case for the PAHs. 相似文献
827.
828.
829.
830.
Fan Li Yue Zhan Dandan Liu Dongbo Liu Hongmei Xia Shan Chen 《Journal of Polymers and the Environment》2013,21(4):1143-1149
The fermentation conditions for poly(l-lactide) (PLA)-degrading enzyme production by Amycolatopsis orientalis ssp. orientalis were statistically optimized by response surface methodology. The optimal value of the most important factors was 0.39 % PLA and 0.34 % gelatin for 2.81 days of cultivation. Under these conditions, the model predicted a PLA-degrading activity of 155.30 U/l. The verification showed the production amount of 154.2 U/l. The crude enzyme from A. orientalis ssp. orientalis showed potent PLA-degrading ability, which is efficient for the biological recycling of PLA. Up to 4,000 mg/l of PLA granule was completely degraded within 5 days at 45 °C by the crude enzyme. l-lactic acid (600 mg/l) was obtained as a degradation product of PLA after only 2 h of incubation. The results indicated that the crude PLA-degrading enzyme from A. orientalis ssp. orientalis has the potential to degrade PLA to lactic acid for the recycling of PLA industry and waste disposal. 相似文献