鄱阳湖主要入湖口重金属的分布及潜在风险评价

于2011年5月在鄱阳湖的主要入湖口采集了水样和表层沉积物,测定并分析了其中Cu、Zn、Pb、Cd 4种重金属元素的含量和分布。同时采用地积累指数法、潜在生态危害指数法和生态毒性效应等评价方法对沉积物中重金属的污染状况进行了分析评价。结果显示：鄱阳湖主要入湖口水体重金属Cu、Zn、Pb、Cd含量均符合国家渔业水质标准要求,除修河的Pb和信江、饶河入湖口的Cd含量属于国家地表水Ⅱ类水质外,其它所有样地的4种重金属含量均低于国家地表水I类标准限值。沉积物中4种重金属含量均超过鄱阳湖相应背景值且呈积累富集的趋势,其中信江入湖口、饶河入湖口以及三江口已受到重金属的严重污染,潜在生态危害均为中等,而污染最轻的区域为南主湖区。揭示重金属污染程度顺序为Cu＞Zn＞Pb＞Cd;单个重金属潜在生态风险顺序为Cd＞Cu＞Pb＞Zn。进一步的生态毒性效应评价结果表明,虽然鄱阳湖主要入湖口沉积物已经受到重金属污染,但对多数底栖生物未产生明显毒害     

红阳猕猴桃和葛根配方的解酒保肝与抗氧化作用研究

研究红阳猕猴桃、葛根及其配方组合物的解酒保肝与抗氧化作用。采用乙醇所致小鼠自主活动减少和小鼠共济失调实验评价解酒作用;采用小鼠酒精性肝损伤模型评价保肝作用,采用ELISA测定大鼠尿液中8-羟基脱氧鸟苷酸（8-hydroxy-2-deoxyguanosine,8-OHdG）和乙酰—赖氨酸加合物（hexanoyl-lysine adduct,HEL）,以了解配方组合物对DNA过氧化和脂质过氧化的影响。结果表明,红阳猕猴桃—葛根配方可减轻酒精所致小鼠行为抑制和共济失调,提示具有解酒作用;对酒精所致小鼠肝脏MDA、TG水平升高和GSH水平降低有明显改善,提示具有保护化学性肝损伤作用;降低正常和酒精损伤大鼠尿液中过氧化生物标志物水平,提示具有较好的抗氧化作用。红阳猕猴桃—葛根配方具有快速解酒作用,且可持续2—4h;对酒精性肝损伤有一定的保护作用,其机制与抗氧化有关。     

Study of nitro-polycyclic aromatic hydrocarbons in particulate matter in Dongguan

Total suspended and size-segregated atmospheric particles were collected in four seasons at three representative points in different functional areas of Dongguan City. The detailed size distributions of six nitro-PAHs [2-nitrofluorene (2-NF), 9-nitroanthracene, 2-nitrofluoranthene (2-NFL), 3-nitrofluoranthene, 1-nitropyrene, and 2-nitropyrene (2-NP)] were determined by high-performance liquid chromatography (HPLC) with UV detection using a binary elution gradient (methanol and water). We used a toxicity assessment based on potency equivalency factors (PEFs) to estimate the inhalation risk of the particulate matter. The results showed that, aside from 2-NF and 2-NFL, the content of the other four nitro-PAHs in the microparticles (<0.4 μm) were more than 20 %, a percentage significantly higher than other fractions of particulate matter. The seasonal distribution of nitro-PAHs shows that their concentrations were higher in the winter, while the PAH concentrations were higher in the summer. The study found that secondary formation (2-NFL and 2-NP) had a positive correlation with NO _x and NO₂, but a negative correlation with O₃. The benzo[a]pyrene equivalent (BaPeq) toxicity of particulate matter in Dongguan City ranged from 0.04 to 2.63 ng m^?3, and the carcinogenic index ranged from 0.04?×?10^?6 to 2.39?×?10^?6. These values do not represent a serious threat to human health.     

Optimization of esterification of fatty acid rubber seed oil for methyl ester synthesis in a plug flow reactor

To date, non-food vegetable oil has been considered as the primary source for biodiesel production. Rubber seed oil has high acid value (34 mgKOH/g) and can be used for biodiesel synthesis. The purpose of this study was to investigate esterification of fatty acid, which derived from rubber seed oil, in a plug flow reactor system at high temperature and low methanol consumption. Response surface methodology was applied for design experiment and optimization of esterification reaction. Temperature, methanol consumption, and sulfuric acid were chosen as variables to examine their influence in a conversion to methyl ester. At 140°C, at 5:1 methanol to fatty acid ratio (by mole), H₂SO₄ 1.5 (%v/w), and space time 20 min, the conversion to methyl ester attained 98.2%. Fourier transform infrared spectroscopy (FTIR) and gas chromatography-Mass spectrometry (GC-MS) were used for analysis and to confirm the formation of methyl ester. Methyl ester was characterized for biodiesel fuel properties in accordance to ASTM standard.     

微污染矿井水中微絮体的形成及分形特征

利用分形理论阐述了微污染矿井水中微絮体形成的分形生长特征,考察了微絮体形成过程中的影响因素,探讨了微絮凝机理,利用絮体的分形维数表征各影响因素对微絮体形态的作用结果,结果表明,微絮体形态与其分形维数之间具有良好的相关性,且分形维数越大,微絮体更加紧实,越易于沉降,滤后水的浊度越小;同时考察了微量铁锰离子对微絮体形态的影响,为微絮凝深床过滤工艺参数的改进提出了建议.     

铁碳微电解-Fenton法预处理苯胺基乙腈生产废水

采用铁碳微电解-Fenton法对苯胺基乙腈生产废水进行预处理实验。通过静态实验确定铁碳微电解最佳条件为铁屑投加量300 g/L,Fe/C质量比为2∶3,反应75 min,不需要调节进水pH;Fenton反应最佳条件为铁碳微电解出水pH=4,30%H2O2投加量15 mL/L,在搅拌条件下反应60 min;然后沉淀反应时调节pH为9,混凝沉淀75 min。在上述条件下通过动态实验得到系统连续反应在48 h内废水的COD和苯胺去除率在50%和70%以上,可生化性BOD5/COD也保持在0.3以上,为后续生物处理创造了良好条件。     

宁镇扬地区优良级旅游资源空间结构对比研究

利用Stephen Smith总结和提出的旅游区域研究方法,以2007年江苏省旅游资源普查的数据资料为基础,运用AreGIS空间分析的相关工具,对宁镇扬地区的优良级旅游资源的空间结构作了对比研究。结果显示,扬州、镇江具有较典型的金字塔形旅游资源等级结构;宁镇扬3个城市的优良级旅游资源分布都属于集聚型分布,尤以南京的集聚程度最高。在阐述传统通达度计算方法缺陷的基础上,通过权距离修正和扩大网络范围修正之后的通达度分析结果显示,宁镇扬地区是江苏省旅游交通最为发达的区域,尤以南京的通达程度最高。     

沸腾炉大气污染物初始排放因子的研究

以20台沸腾炉(≤60MW)的燃料特性分析数据和大气污染物的排放实测数据为基础,研究了颗粒物(PM)、SO2和NOX初始排放因子EFP0M、EF0SO2、EF0NOX的变化规律,并利用SPSS13.0统计分析软件,分析了EFP0M、EFS0O2、EF0NOX与影响因子间的相关性。结果表明,在沸腾炉运行负荷≥80%的条件下,EF0PM基本不受锅炉出力(W)、燃煤灰分质量分数(Aar)及过量空气系数(α)的影响,EFP0M与W、Aar、α不具有相关性;EF0SO2主要受燃煤硫质量分数(Sar)的影响,两者具有显著正相关关系;W、α、燃煤干燥基挥发分质量分数(Vdaf)对EF0NOX具有显著影响,EF0NOX与α具有显著正相关关系,而EF0NOX与W、Vdaf具有显著负相关关系;EFS0O2和EF0NOX影响因子由强到弱的顺序为:①EFS0O2:SarαW;②EF0NOX:VdafαW燃煤氮质量分数(Nar)。     

Environmental regulatory failure and metal contamination at the Giap Lai pyrite mine, Northern Vietnam

The causes for the failure in enforcement of environmental regulations at the Giap Lai pyrite mine in northern Vietnam are considered and the environmental impacts that are associated with this mine are evaluated. It is shown that sulphide-rich tailings and waste rock in the mining area represent significant sources of acid rock drainage (ARD). The ARD is causing elevated metal levels in downstream water bodies, which in turn, represent a threat to both human health and to aquatic ecosystems. Metal concentrations in impacted surface waters have increased after mine closure, suggesting that impacts are becoming progressively more serious. No post-closure, remediation measures have been applied at the mine, in spite of the existence of environmental legislation and both central and regional institutions charged with environmental supervision and control. The research presented here provides further emphasis for the recommendation that, while government institutions may need to be strengthened, and environmental regulations need to be in place, true on the ground improvement in environmental quality in Vietnam and in many other developing countries require an increased focus on promoting public awareness of industrial environmental issues.     

基于OMI数据的成渝城市群对流层NO2浓度遥感监测

利用Aura卫星的OMI（Ozone Monitoring Instrument）传感器最新版对流层NO2垂直柱浓度数据产品,结合线性拟合、趋势分析和空间自相关分析等方法,系统分析了2005~2017年成渝城市群对流层NO2垂直柱浓度的时空特征及变化趋势。结果表明：OMI对流层NO2柱浓度数据与成渝城市群NO2地面监测数据变化趋势基本一致,且存在良好的相关性;时间上,2005~2012年NO2年均柱浓度增加明显,增幅达52.38%,2012年后呈下降趋势。NO2柱浓度季节变化明显,浓度水平基本为：冬季>秋季>春季>夏季。NO2柱浓度月均值具有类似于正弦函数的周期性,1年一个周期,低值出现在每年的7、8月,高值出现在11、12和1月;空间上,经济较发达地区的NO2浓度大于经济欠发达地区。2005~2012年99.58%的区域NO2浓度上升,2012~2017年80.50%的区域NO2下降,但是成渝城市群边缘的山区NO2浓度依然呈增长趋势。成都、重庆对流层NO2柱浓度具有明显的局部空间正相关特性。