环境中总石油烃的气相色谱分析测定

将总石油烃划分为挥发性汽油类(C6～C10)、可萃取柴油和重油类(C10～C40)两部分,分别建立了通过吹扫捕集、液液萃取和超声溶剂萃取分离富集,气相色谱-火焰离子化检测器(GC-FID)测定环境水体和土壤中总石油烃的分析方法。以汽油、柴油、润滑油标准溶液进行外标校正,以色谱出峰总面积进行定量。汽油类(C6～C10)的检出限分别为0.04mg/L和0.42mg/kg,柴油和重油类(C10～C40)的检出限分别为0.06mg/L和4.9mg/kg。方法的精密度和准确度均良好。     

工业园区环境风险源识别与分级研究

以多年来中国各行业突发环境事故统计数据为基础,选取了对于企业突发环境事件有重大影响的7个因子以及17个指标,采用指标因子分析法对其进行定量,应用层次分析法确定各因子的权重,从而确定企业环境风险水平值。基于"危险物质水平—企业环境风险水平—周边环境受体状况"体系,构建了环境风险源分级矩阵,形成了包括"环境风险源初筛","环境风险源分级"的两步工业园区环境风险源识别与分级方法。该方法提出的工业园区环境风险源识别与分级体系具有科学性和可行性,能为工业园区环境风险管理提供依据。     

Characteristics and assessment of phthalate esters in urban dusts in Guangzhou city, China

Phthalate esters (PAEs) were examined in indoor and outdoor dust samples from the subtropical city of Guangzhou, China. The ∑(16)PAEs concentrations ranged from 121 to 3,223 μg g(-1) dust, with the median concentration of 840 μg g(-1) dust. Significantly higher concentrations of PAEs in dust samples were found in offices where electrical and electronic devices, carpet pads, and office furniture were widely used. Of the 16 PAEs, diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), and di(2-ethylhexyl) phthalate (DEHP) dominated the PAEs in indoor and outdoor dust samples, and accounted for >96.8% and >93.1% of the ∑(16)PAEs concentrations, respectively. The median daily inhalation exposure of ∑(16)PAEs were 3.53 and 0.247 μg kg(-1) body weight day(-1), and at the 95(th) percentile were 7.62 and 0.530 μg kg(-1) body weight day(-1), up on the measured concentrations and estimated dust ingestion rates, respectively, for toddles and adults. The ubiquitous distribution of PAEs as noted in this study suggests the need for detailed assessment of PAEs concentrations using more sites and to further investigate the factors influencing PAEs exposure in China.     

“十一五”期间重点流域化学需氧量排放及减排潜力分析

根据"十一五"期间七大流域化学需氧量(COD)排放总量、工业COD排放量及生活COD排放量的变化情况对各流域的减排幅度进行了综合评价,根据单位水资源COD负荷、单位工业产值COD排放强度及人均生活COD排放强度对各流域的污染压力进行了综合评价,以七大流域的减排幅度和污染压力为基础分析了各流域COD的减排潜力,并对各流域的重点防控领域和配套减排措施等方面提出了政策建议。     

底质农残测定中固相柱净化体系的选择

使用固相柱对底质中的7种农残进行净化。结果表明,在相同淋洗条件下,使用氟罗里硅土柱比硅胶柱净化效果好。比较了不同溶剂体系、不同溶剂配比下2种萃取柱的净化效果,选择乙醚-正己烷(体积比1∶2)或丙酮-正己烷(体积比1∶4)作为净化溶剂,较小的收集体积都可满足所有目标化合物的回收率要求;相比较而言,丙酮-正己烷(体积比1∶4)作为净化溶剂,洗脱液的杂质干扰更小,净化效果更好。使用氟罗里硅土柱和丙酮-正己烷(体积比1∶4)对样品净化,方法简单,快速,净化效果好,适合大批量底质样品的前处理净化过程。     

青岛市主干道沿线高层建筑的交通噪声研究

采用A计权网络对青岛市东西快速路沿线高层建筑进行监测。利用Grapher软件,以Leq为监测值的基准值绘制连续线状图,分析城市主干道周边高层建筑上交通噪声的峰值点。根据道路中心线到高层建筑的距离信息,得出高层建筑交通噪声峰值点与道路中心线的连线与水平地面间的角度约为30°。     

Characteristic, composition, and sources of TSP investigated by HRTEM/EDS and ESEM/EDS

Total suspended particle (TSP) collected at the fifth floor of House Dust in Hunan University, China, was analyzed in terms of microscopic morphology and chemical composition. The fine particles (50?nm-2?μm) in the TSP were analyzed by a high-resolution transmission electron microscope equipped with an energy-dispersive X-ray analyzer (HRTEM/EDS). Results showed that the particles were in shapes of plate, irregular and agglomerate. Based on EDS results, these fine particulate matter was primarily composed of Fe-rich (35.82-61.29%), Ca-rich (30.18-36.77%) and Si-rich (18.95-32.28%) particles. Other elements mainly including Mg (0.47-4.97%), Al (0.45-14.57%), S (0.45-4.73%), K (1.13-2.13%) and Zn (0.67-3.85%) were also observed. The sources analysis indicated that the HRTEM particles mainly originated from coal combustion, traffic emission, vehicles exhaust emission and fugitive soil or cement particulate matter. The coarse particles (4-50?μm) were detected by environmental scanning electron microscopy coupled with energy-dispersive X-ray detector (ESEM/EDS). Based on a simple algorithm, ESEM particles were categorized into five groups: C-bearing (46.15%, 67% and 86.98%), Si + Ca-bearing (21.48?+?11.80%, 16.51?+?10.81% and 16.32?+?10.62%), Si + Al-bearing (20.06?+?12.40%, 20.16?+?11.22% and 15.31?+?11.25%), Si-bearing (34.40%, 26.92% and 27.15%) particles and aggregates, most of which exhibit obvious crystalline structure, and these ESEM particles mainly derived from vehicles exhaust emission, coal combustion, soil, and biomass burning, while the aggregates are indicative of atmospheric reaction progress. HRTEM/EDS and ESEM/EDS are mutual complementary in analyzing the characteristic and determining the sources of TSP.     

南京南湖底泥疏浚后水质演化规律调查

对疏浚后的南京南湖底泥的TP、TN和COD释放规律、补水后的水质状况以及藻类演替规律进行了调查。结果表明,上覆水中TP平均质量浓度基本不随自来水补入量的增加而发生变化,TN和COD质量浓度随自来水补入量的增加而增大;水体中的TP、TN和COD含量总体呈上升趋势;从2005年3月中旬起,出现藻类的大量繁殖,在2005年7月发生水华,藻类优势种由裸藻、隐藻和小环藻演替为裸藻、栅藻和韦斯藻,藻类总量由2005年3月的3.7×106L-1上升到2006年4月的1.5×107L-1。     

南京市地铁车站氡浓度水平的初步调查

采用静电收集氡子体法对南京市地铁车站环境中氡浓度进行了调查,初步掌握了南京市地铁站重点区域的氡浓度放射性水平,按照联合国原子辐射效应科学委员会推荐的评价方法估算氡浓度对地铁内工作人员人均年有效照射剂量。对地铁站新建和扩建项目的机械通风设计,为工作人员和公众的内照射剂量水平估算等提供依据。     

中美环境监测体制之比较

对中美环境监测体制进行对比性评述,指出了中国环境监测行业存在的分析标准滞后、体制不完善、人员匮乏等问题,提出借鉴美国经验,完善法律体系,引入市场机制,逐步培育竞争有序、监管到位的环境监测行业的建议。