A study of diffusion models applied to dust emissions from industrial complexes

Industrial complexes may release dust emissions through several to up to tens of stacks, as well as via fugitive area sources. Several diffusion models for small-scale fugitive dust sources have been developed and combined with a point source model to form a series of models for industrial complexes. The applicable area of these models and the methods for obtaining the main parameters in the models have been tested and verified using measurement data gained from several field experiments. The models developed in this paper can give quite satisfactory results when compared to other current models.     

Contamination of Oxygen-Consuming Organics in the Yellow River of China

Contamination of oxygen-consuming organics (OCOs) was one of the most serious problems in the Yellow River of China. This study was conducted to analyze monitoring of the data on OCOs contamination for the river in 1980 and during 1992–1999 as well as examining the effect of suspended solids (SS) on chemical oxygen demand (COD_Mn) and biochemical oxygen demand (BOD₅) of river water. Several significant results have arisen from the study. First, COD_Mn and BOD₅ of the river water showed an increasing trend from the upper to the lower reaches of the mainstream. BOD₅ values of river water in 1992 were significantly higher than those in 1980 and showed an increasing trend during 1992–1999. Second, OCOs in river water of the mainstream was attributed mainly to point sources; the ratio of point to non-point sources of BOD₅ was about 2.81. The load from point sources showed an increasing trend during 1992–1998. In contrast, the load from non-point sources manifested a decreasing trend during this period; this was caused by the decreasing trend of SS content in river water. The total load of BOD₅ from point and non-point sources displayed an increasing trend during 1992–1998. Third, as the humic substances in SS can hardly be biologically oxidized in natural conditions but can be oxidized by chemical oxidants such as potassium permanganate, COD_Mn was not suitable for being regarded as a parameter reflecting the pollution degree of OCOs in river water with a high SS content.     

土酸化学刺激剂提高花岗岩渗透率的试验研究

增强型地热系统(EGS)是通过人工形成地热储层而从低渗透性岩体中经济地采出热能的地热系统。为了提高热储层的渗透率,需要对热储层实施化学刺激,增加深部岩体中地热能的采收率。以采自青海共和盆地的花岗岩样品(与盆地基底干热岩体的岩性相同)为研究对象,选用10%HCl+3%HF的土酸为化学刺激剂,在不同温度和试验时间反应条件下开展了花岗岩化学刺激试验,研究了土酸化学刺激剂对实际EGS储层的化学刺激效果以及溶蚀特征。结果表明:土酸刺激后花岗岩的渗透率明显提高,且其渗透率的提高倍数随温度的升高和时间的延长而增大;化学刺激试验中发现花岗岩化学组成中石英和长石发生溶蚀,而且还生成了氟铝酸钾、氟硅酸钾和石英蚀变矿物。     

环境准入门槛设置与指标体系构建实证

根据统筹协调、生态优先、地域差异、管理可行性等原则,从前置性和控制性两个方面,选取包括时序、空间、容量、投资规模、排放总量与强度以及资源、能源消耗标准等要素指标,建立环境准入指标体系;并以江苏省为例,根据指标门槛设置的标准和依据,进行指标门槛的定量测算。初步得到:重点企业最低投资准入、重点区域和重点污染行业环境准入指标测算值,以期为政策制定者提供可资借鉴的依据。     

高科技污染问题及驱动力模型研究

高科技产生的污染包括产品生产、消费过程中及废弃时产生的污染。这些特点又加重了高科技的污染程度。高科技污染的各种特点，包括扩散快、产品回收难、污染类型多及隐蔽性强等。以江苏省高科技企业为例，研究企业隶属、资产组成以及经营能力和科技水平等企业性质指标与企业有毒有害原辅料消耗量的相关性，并做出高科技企业污染的驱动模型。根据所得研究结果，分析总结影响高科技企业有毒有害原辅料消耗量的主要因素，认为企业的性质间接作用于企业，最终形成了高科技污染。并据此提出治理高科技污染的建议，即完善污染治理法律体系、探索废旧产品回收途径、发展清洁生产技术、探索针对高科技企业的环境管理模式。     

化学沉淀组合电催化氧化处理脱硫废液技术研究

真空碳酸钾脱硫工艺碱洗段废液因含有高浓度硫化物、COD等有毒成分而影响焦化废水后续生物处理。以焦化企业实际碱洗段废液为研究对象,选用化学沉淀和电催化氧化的组合方式对其进行预处理。结果表明,室温下当氧化铜的投加量为65 g/L、反应时间60 min时废液中S2-去除率可达93%,且经过高温灼烧可实现Cu O沉淀剂的再生使用。沉淀后出水经电催化氧化处理,在电流10 A、电压4.9 V、电解时间120 min的条件下,出水COD可降至2 400 mg/L,满足常规生化系统进水的要求。     

铬渣中铬的浸出行为

采用BCR法连续浸提研究铬渣中铬的存在形态,结果表明:铬渣中总铬和六价铬主要以残渣态和可氧化态形式存在;通过铬渣动态连续浸提实验与静态浸提实验研究了浸提剂和活性炭对铬渣中铬浸出行为的影响,研究发现p H值为3.1的醋酸浸提剂浸出液中铬浓度最低,且添加活性炭后的静态浸出液中铬的浓度有不同程度降低。     

690V变频器在造纸厂的应用

在大型造纸厂经常会遇到使用200~1 000 k W变频电动机的情况。因为0.38 k V电机生产工艺的原因不可能做到很大功率,而中压(10 k V,6 k V)的变频器因为价格、安全与稳定性的原因也有其缺陷,所以0.69 k V这个电压等级的变频器就有了用武之地。