Atmospheric depositional fluxes and sources apportionment of organochlorine pesticides in the Pearl River Delta region, South China

Organochlorine pesticides (OCPs) have variously been phased out in agricultural activities, but they are still widely detected in air, water, and soil systems due to their recalcitrant nature in the environment. The purposes of this study were to assess potential OCP pollution via dry and wet deposition over the fast developing Pearl River Delta area with 41,700 km², where the main effort has been focused on emerging pollutants such as petroleum hydrocarbons and PM2.5. We quantified both the dry and wet deposition fluxes of 19 OCPs including dichlorodiphenyltrichloroethanes (DDTs), endosulfans (Endos), and hexachlorocyclohexanes (HCHs). The results showed that each year about 67.4, 42.0, 15.0, and 8.07 kg of total OCPs, DDTs, Endos, and HCHs were returned to the ground, among which 11.7, 10.4, 0.84, and 0.16 kg were in the dry deposition forms. The large spatial variations in OCP deposition fluxes indicated that OCP pollution in the air is mainly influenced on local scales because evaporation from local soil is likely the major source of the phased out OCPs. Source analysis indicated that DDTs may be still in use as antifouling agent and/or dicofol, but Endos and HCHs were mainly derived from the residual of historical usage. The study suggests that the historical OCP pollutants are persistent at high levels in this area and should not be overlooked, while we tackle emerging pollutants.     

Effect of heavy metals (Cu, Pb, and As) on the ultrastructure of Sargassum pallidum in Daya Bay, China

Concentrations of Cu, Pb, and As were determined in seawater, surface sediment, Sargassum pallidum collected from the Daya Bay, China. The influence of metal contamination on the marine alga was investigated at chemical and ultrastructural level. Mean concentrations of Cu (19.44 mg kg^?1) and Pb (33.99 mg kg^?1) were found to be high in sediment, whereas concentration of As (122.29 mg kg^?1) in S. pallidum was higher than that in water and sediment. The ultrastructure of S. pallidum cells was anomalous and aberrant. Energy-dispersive x-ray spectroscopic analysis revealed that the nanometal particles in the form of comparatively high-electron density substance diffused in the cell structures constituted by Cu, Pb, As, etc. There is a remarkable similarity or correspondence in the anomalous elements between the geochemistry and the botanic cell, and the heavy metals have potential hazardous effect on the ocean ecology system in Daya Bay.     

Penicillin fermentation residue biochar as a high-performance electrode for membrane capacitive deionization

● We have provided an activated method to remove the toxicity of antibiotic residue. ● PFRB can greatly improve the salt adsorption capacity of MCDI. ● The hierarchical porous and abundant O/N-doped played the key role for the high-capacity desalination. ● A new field of reuse of penicillin fermentation residue has been developed. Membrane capacitive deionization (MCDI) is an efficient desalination technology for brine. Penicillin fermentation residue biochar (PFRB) possesses a hierarchical porous and O/N-doped structure which could serve as a high-capacity desalination electrode in the MCDI system. Under optimal conditions (electrode weight, voltage, and concentration) and a carbonization temperature of 700 °C, the maximum salt adsorption capacity of the electrode can reach 26.4 mg/g, which is higher than that of most carbon electrodes. Furthermore, the electrochemical properties of the PFRB electrode were characterized through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) with a maximum specific capacitance of 212.18 F/g. Finally, biotoxicity tests have showed that PFRB was non-biotoxin against luminescent bacteria and the MCDI system with the PFRB electrode remained stable even after 27 adsorption–desorption cycles. This study provides a novel way to recycle penicillin residue and an electrode that can achieve excellent desalination.     

四川彭县银厂沟峡谷自然景观成因初探

四川省彭县银厂沟峡谷全长21公里,峡谷和原始森林保存完整。时隐时现的“彩虹”出现于峡谷两岸的瀑布上。区内自然景观丰富多彩。本文根据旅游地质调查工作成果,对自然景观的成因作了初步探讨。     

DEBRIS FLOW IN WEST DEVELOPMENT

ＴｈｅｗｅｓｔｅｒｎｒｅｇｉｏｎｓｏｆＣｈｉｎａ (ｏｒＷｅｓｔＣｈｉｎａ)ｉｎｃｌｕｄｅ 1 2 ｐｒｏｖｉｎｃｅｓ/ａｕｔｏｎｏｍｏｕｓｒｅ ｇｉｏｎｓ/ｍｕｎｉｃｉｐａｌｉｔｉｅｓ:Ｑｉｎｇｈａｉ,Ｇａｎｓｕ ,Ｓｈａａｎｘｉ,Ｓｉｃｈｕａｎ ,Ｙｕｎｎａｎ ,Ｇｕｉｚｈｏｕ ,Ｘｉｎｊｉａｎｇ ,Ｔｉ ｂｅｔ ,Ｎｉｎｇｘｉａ ,Ｇｕａｎｇｘｉ,ＩｎｎｅｒＭｏｎｇｏｌｉａａｎｄＣｈｏｎｇｑｉｎｇ .ＳｉｎｃｅｔｈｅＰｌｅｉｓｔｏｃｅｎｅｏｆｔｈｅＱｕａｔｅｒ ｎａｒｙＰｅｒｉｏｄ ,ｔｈｅｍｏｕｎｔａｉｎｓｉｎｔｈｅｗｅ…     

韶钢新石灰窑烟气除尘技术的应用

韶钢新石灰窑烟气除尘系统要用旋风除尘器、金属管式换热器、高效陶瓷多管除尘器的组合方式。介绍了该系统的设计参数、工艺流程、主要设备及其功能。     

隧洞施工通风系统事故树分析

在采矿、铁路、公路及水利水电工程中，常常采用长距离隧洞或隧道来穿越高山。而隧洞的施工以其施工技术复杂、难度大、风险高，经常成为控制工程工期的主要环节，隧洞施工中的通风换气系统，关系到施工能否顺利进行和施工作业人员的人身安全，根据隧洞施工通风系统的运行特点，采用安全系统分析中的事故树（FTA）方法，对隧洞施工中通风系统的安全性进行定性分析，找出影响通风安全的主要因素，并提出了通风安全管理对策，可以保证施工作业的顺利进行和人身安全，提高整个施工作业的安全度。     

有机废气的臭氧化过程降解及其动力学

实验研究了有机废气中的1.1-二氧乙烯（CH2=CCl2）在101.3kPa和288～308K下气相臭氧化降解过程及其反应动力学。结果表明，总的反应级数是2级，相对于臭氧和二氯乙烯浓度均为1级。反应速率常数可用方程Arrhenius（k2=8.32exp[-389.7/T]）表示。     

桥梁实用延性抗震设计方法研究

针对铁路桥梁中应用广泛的单柱式桥墩 ,考虑多种跨度 ,多种墩高和多种场地及多种地震烈度的情况 ,在进行大量的桥墩结构线性和非线性弹塑性动力计算分析的基础上 ,通过对大量数据的统计分析 ,得到桥墩线弹性最大弯矩比和非线性位移延性比参数的变化规律 ,基于概率性的结构随机地震反应理论 ,建立了由线弹性动力分析结果来估算桥墩结构的位移延性响应的方法。