利用膜进样质谱连续走航测定表层海水O2/Ar比值和pCO2

利用HIDEN公司HPR40溶解气体质谱分析仪,通过实验探索和实际应用,建立了连续走航高频率同时测定海水中O₂、Ar和CO₂等多种气体的分析方法。通过选择硅树脂膜的循环水取样器、进样流量为220 mL/min、进样平衡温度低于海水2℃等实验条件,建立了船载连续走航系统,实现了利用膜进样质谱仪（MIMS）连续走航测定表层海水O₂/Ar比值和pCO₂。所用仪器稳定性良好,连续测定12 h大气鼓泡48 h后的海水样品获得O₂、Ar和CO₂的精密度分别为1.57%、3.75%和2.21%,O₂/Ar的精密度为2.61%;该方法的重复性好,10 d内绘制7条CO₂工作曲线斜率的相对标准偏差RSD=4.18%。应用该方法在南海北部陆坡19.8°N～20.8°N,114.7°E～115°E断面进行调查并取得了很好的效果,结果表明:该调查断面的生物氧过饱和量Δ（O₂/Ar）为0.56%±1.02%,其变化范围为-2.52%至3.34%,调查断面的pCO₂值为361.53±40.46μatm。该方法具有直接、快速、高时空分辨率测定多种溶解气体的优点,为认识多组分气体的高分辨时空分布格局,深入开展我国陆架边缘海生物过饱和氧、海洋群落净生产力和pCO₂动力学研究提供了新方法。     

基于MCDA模型的危险废物填埋场地下水污染风险分级

基于对风险全过程控制的思想,利用层次分析法,构建了综合考虑危险废物填埋场自身属性、污染场地水文地质条件以及污染受体等因素的危险废物填埋场地下水污染风险分级指标体系,该体系共包括14项指标;并采用MCDA(multi-criteria decision analysis,多准则决策分析)模型,对我国37个危险废物填埋场(不包括港澳台数据,下同)地下水污染风险进行了分级研究. 结果表明:14项风险分级指标之间具有很好的独立性,指标体系能够较为完整、准确地反映危险废物填埋场对地下水的污染风险程度;37个危险废物填埋场地下水污染风险可分为高、中、低3个级别,其中81%处于中、低级风险级别;地下水中特征污染物ρ(Cr)监测值与风险分级分值的距平指数为0.802 9,验证了风险分级结果的可靠性;同时采用MDCA模型对风险分级指标权重的敏感性进行分析,验证了风险分级过程中指标权重赋值的准确性,并降低了指标权重赋值过程中的不确定性,进一步提高了分级结果的可靠性.风险分级结果在一定程度上可为危险废物填埋场地下水污染风险管理提供依据.      

pH值和离子强度对针铁矿吸附磺胺二甲基嘧啶的影响机制

磺胺二甲基嘧啶作为普遍使用的抗生素代表,可通过动物粪便施肥及药物不规范使用进入到环境中.针铁矿是土壤中分布广泛且活性较高的一种矿物,会对磺胺二甲基嘧啶的环境行为产生一定的影响.为了正确评估磺胺二甲基嘧啶的环境风险,本文考察了溶液pH值、离子强度对针铁矿吸附磺胺二甲基嘧啶的影响.结果表明:磺胺二甲基嘧啶在针铁矿上的吸附具有明显的非线性,且吸附具有明显的滞后现象,吸附等温线可以用Freundlich模型较好的拟合(R~2=0.991);磺胺二甲基嘧啶在针铁矿上的吸附随着pH值的增加先增加后减小,随着离子强度的增加开始有微弱的增加然后保持不变;在酸性和中性条件下,表面络合作用是主导磺胺二甲基嘧啶在针铁矿表面上吸附的主要机制,在碱性条件下静电斥力是主导吸附的主要作用力.因此,在评估抗生素的环境行为时,应该考虑不同的环境条件对针铁矿吸附磺胺二甲基嘧啶的影响.     

Estimating Floodwater Depths from Flood Inundation Maps and Topography

Information on flood inundation extent is important for understanding societal exposure, water storage volumes, flood wave attenuation, future flood hazard, and other variables. A number of organizations now provide flood inundation maps based on satellite remote sensing. These data products can efficiently and accurately provide the areal extent of a flood event, but do not provide floodwater depth, an important attribute for first responders and damage assessment. Here we present a new methodology and a GIS‐based tool, the Floodwater Depth Estimation Tool (FwDET), for estimating floodwater depth based solely on an inundation map and a digital elevation model (DEM). We compare the FwDET results against water depth maps derived from hydraulic simulation of two flood events, a large‐scale event for which we use medium resolution input layer (10 m) and a small‐scale event for which we use a high‐resolution (LiDAR; 1 m) input. Further testing is performed for two inundation maps with a number of challenging features that include a narrow valley, a large reservoir, and an urban setting. The results show FwDET can accurately calculate floodwater depth for diverse flooding scenarios but also leads to considerable bias in locations where the inundation extent does not align well with the DEM. In these locations, manual adjustment or higher spatial resolution input is required.     

县域农用地生态价值评估研究 ——以玉山县为例

针对当前农用地估价工作中存在的重社会经济价值评价,轻生态价值评价,长期缺乏农用地价值的完整认识,直接导致农用地被低价转为建设用地的问题,本研究将采用农用地生态价值估价新方法——吸碳制氧法来测算玉山县农用地生态价值,并与玉山县各乡镇农用地经济价值比较分析,以说明农用地生态价值评估在农用地估价工作中的重要性.研究结果表明,农用地生态价值的评估可以用于指导农用地外部合理流转,有利于农用地的保护,同时,对退耕还林、退田还湖也具有一定的指导意义,因此农用地生态价值评估是非常必要的.     

聚丙烯料仓静电爆炸事故原因分析及设备改造效果

聚丙烯生产中,物料利用空气送至料仓,为了产品均化,在料仓内还需进行掺混,在这一过程中会造成静电积聚,进而形成静电放电引起爆炸事故。分析了聚丙烯装置料仓静电爆炸事故原因,介绍了采取消静电设备后的应用数据和效果。     

超声辅助生物淋滤废旧Zn-C电池锌锰溶出的研究

以氧化硫硫杆菌(A.thiooxidans)为淋滤菌株对废旧Zn-C电池电极材料中的Zn、Mn进行了生物浸提,比较研究了化学浸提、生物淋滤和不同超声辅助方法生物淋滤体系下的Zn、Mn的溶出效率及溶出动力学.结果表明:不同超声辅助方法中,超声+生物淋滤体系Zn、Mn溶出最优,Zn、Mn的最大溶出率分别为94.2%和65.5%,并提高了溶释速率.此外,对于Mn的溶出,化学淋滤体系符合边界层扩散控制模型,生物淋滤和超声+生物淋滤体系符合收缩核Stoke's regime模型,而Zn的溶出均符合化学反应控制模型.     

不同判别方法下四川霾日的气候变化特征

根据近34年(1981—2014年)156个四川地面站的地面观测资料,对比分析了在3种霾日判别方法下霾日的空间分布、季节变化、年代际变化特征以及气候趋势系数的分布特征.利用Morlet小波分析法比较了霾日的周期变化特点.结果表明:1原始观测霾日集中于四川盆地的北部;方法一霾日集中于盆地中南部和东部;方法二霾日集中于盆地地区,无代表高值区;方法三分布类似于方法一.2在季节变化上:不同判别方法下霾日的季节变化类似,秋冬霾日多于春夏.3霾日年代际变化明显.原始观测霾日2013年始出现突增;方法二霾日从2001年始有明显增长;方法一与方法三的年代际变化特征相似.4气候趋势系数上:原始观测变化特征不明显;方法一的系数呈现出南北反向变化;方法二与方法一的分布相似;方法三中系数的正负值区较为集中.5小波变化上:原始观测中霾日无明显周期变化,判别方法一、二、三均有各自的周期变化特点.     

Estimation of bioaccessibility and potential human health risk of mercury in Chinese patent medicines

Mercury(Hg), mainly in cinnabar species, has been used in medicine for thousands of years in China, and worldwide concern has been raised on its toxicity. In this work, the amount of bioaccessible mercury in 16 Chinese patent medicines(CPMs) was measured by using an in vitro simulated digestion system, consisting of simulated gastric and intestinal fluid, to investigate the bioavailability of mercury in CPMs and evaluate its potential risk to human health. Total mercury and mercury in the gastrointestinal extracts were measured by inductively coupled plasma mass spectrometry(ICP-MS). The levels of total Hg in 16 CPMs ranged from not detected to 11.89 mg/g, with a mean value of 1.13 mg/g, while the extractable Hg ranged from not detected to 4.37 μg/g, with a mean value of 0.42 μg/g.Mercury bioaccessibility varied significantly in the investigated CPMs, depending on the ingredient. Compared to the CPMs without cinnabar(2.5%–30.9%), the percentage of mercury in the gastrointestinal supernatants for CPMs with cinnabar was quite a bit lower(0.037%). By comparing with the Food and Agricultural Organization/World Health Organization Joint Expert Committee on Food Additives(FAO/WHO) safety guideline, the average daily intake dose(ADD) of Hg in the medicines was then calculated to access the risk of mercury to human health from taking CPMs.     

Regeneration of commercial selective catalyst reduction catalysts deactivated by Pb and other inorganic elements

The regeneration of commercial SCR(Selective Catalyst Reduction) catalysts deactivated by Pb and other elements was studied.The deactivated catalyst samples were prepared by chemical impregnation with mixed solution containing K_2SO_4,Na_2SO_4,CaSO_4,Pb(NO_3)_2and NH_4H_2PO_4.A novel method combining Ethylenediaminetetraacetic acid disodium salt(EDTA-2Na) and H_2SO_4solution(viz.catalysts treated by dilute EDTA-2Na and H_2SO_4 solution in sequence) was used to recover the activity of deactivated samples,and the effect was compared with single H_2SO_4,oxalic acid,acetic acid,EDTA or HNO_3 solutions.The surface structure,acidity and reducibility of samples were characterized by N_2adsorption–desorption,inductively coupled plasma optical emission spectrometer(ICP-OES),scanning electron microscopy(SEM),X-ray diffraction(XRD),X-ray fluorescence(XRF),H-2-temperature programmed section(H_2-TPR),NH3-temperature programmed desorption(NH3-TPD) and in situ DRIFTS.Impurities caused a decrease of specific surface area and surface reducibility,as well as Br?nsted acid sites,and therefore led to severe deactivation of the SCR catalyst.The use of an acid solution alone possibly eliminated the impurities on the deactivated catalyst to some extent,and also increased the specific surface area and Br?nsted acid sites and promoted the surface reducibility,thus recovered the activity partially.The combination of EDTA-2Na and H_2SO_4 could remove most of the impurities and improve the activity significantly.The removal of Pb should be an important factor for regeneration.Due to a high removal rate for Pb and other impurities,the combination of EDTA-2Na and H_2SO_4 solutions provided the best efficiency.