首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   598篇
  免费   28篇
  国内免费   252篇
安全科学   34篇
废物处理   30篇
环保管理   57篇
综合类   353篇
基础理论   137篇
污染及防治   194篇
评价与监测   16篇
社会与环境   33篇
灾害及防治   24篇
  2023年   17篇
  2022年   27篇
  2021年   24篇
  2020年   21篇
  2019年   29篇
  2018年   23篇
  2017年   31篇
  2016年   27篇
  2015年   29篇
  2014年   48篇
  2013年   54篇
  2012年   47篇
  2011年   57篇
  2010年   47篇
  2009年   44篇
  2008年   52篇
  2007年   38篇
  2006年   23篇
  2005年   26篇
  2004年   20篇
  2003年   17篇
  2002年   26篇
  2001年   15篇
  2000年   9篇
  1999年   18篇
  1998年   20篇
  1997年   30篇
  1996年   10篇
  1995年   5篇
  1994年   9篇
  1993年   11篇
  1992年   6篇
  1991年   5篇
  1989年   1篇
  1988年   1篇
  1987年   2篇
  1986年   2篇
  1984年   1篇
  1983年   2篇
  1982年   2篇
  1981年   2篇
排序方式: 共有878条查询结果,搜索用时 531 毫秒
71.
农药水环境化学行为研究进展   总被引:7,自引:0,他引:7  
农药在水中的环境化学行为包括农药的光化学降解、水化学降解和农药对水生生物的毒性。结合国内外在农药水环境化学行为的研究进展,讨论了农药在水中的直接光解和间接光解行为;农药水化学降解的机理以及pH、温度对农药水化学降解的影响,并以藻类、鱼类等为例阐述了农药对水生动植物及水生生物群落的毒性。  相似文献   
72.
Design of a novel non-equilibrium plasma-based water treatment reactor   总被引:1,自引:0,他引:1  
Zhang Y  Zheng J  Qu X  Chen H 《Chemosphere》2008,70(8):1518-1524
A novel non-equilibrium plasma-based water treatment reactor consisting of high voltage multi-needle electrode submerged in aqueous phase and reticulated ground electrode suspended in gas phase above water was developed and applied to treat low concentrations of methyl orange (MO). The electrode configuration was optimized. Higher number and more uniform distribution of streamers were produced in gas phase when parallel five-needle configuration with needle spacing of 10mm for high voltage electrode, macroporous ground electrode with mesh size of 0.42mm, and electrode gap of 17mm were adopted. This case corresponds to the largest amount of hydrogen peroxide and ozone produced in aqueous phase and gas phase, respectively, and air flow rate presents an economical value. The injection of wastewater above ground electrode for pretreatment and the design of fixed mesh barriers further increase the amount of ozone dissolved in aqueous solution. The conversion of MO presents a positive correlation with input voltage and the increase of pulse repetition rate is conducive for the conversion. In addition, the effect of initial solution concentration and treating volume on the conversion, energy yield and COD removal was evaluated.  相似文献   
73.
Xiao H  Liu R  Zhao X  Qu J 《Chemosphere》2008,72(7):1006-1012
Mineralization of 2,4-dichlorophenol (DCP) was studied by ozone with Mn(2+) as an ozonation catalyst. Laboratory scale semi-batch ozonation experiments were conducted at room temperature. The results showed that trace amount of Mn(2+) accelerated the mineralization of DCP. Total organic carbon removal rate was independent on Mn(2+) dosage at its range of 0.1-0.5 mgL(-1). Dissolved ozone concentration in the solution remained low level in the catalytic ozonation process, which indicated that Mn(2+) catalyzed decomposition of ozone. DCP mineralization was inhibited in catalytic ozonation by the addition of carbonate. Electron spin resonance/spin-trapping technique was used to determine hydroxyl radicals, and the results showed that larger amounts of hydroxyl radicals were produced in catalytic ozonation system than those of single ozonation. Intermediates mainly including aliphatic carboxylic acids were determined qualitatively and semi-quantitatively by GC-MS. And, a general pathway for mineralization of DCP was proposed.  相似文献   
74.
浅谈外墙保温材料对建筑防火的影响   总被引:1,自引:0,他引:1  
曲毅  仝艳时 《安全》2008,29(11):6-8
本文通过对几种外墙保温材料及国内外外墙保温技术的介绍,从中分析出引起建筑耐火极限降低的原因,找到在目前条件下,最适合外墙保温的材料及技术,以降低火灾的发生。  相似文献   
75.
钯离子液相催化氧化低浓度磷化氢   总被引:1,自引:0,他引:1  
采用Pd^2+液相催化氧化低浓度PH3,考察了Pd^2+浓度、O2体积分数、PH3质量浓度、混合气流量、反应温度等因素对Pd^2+吸收液去除低浓度PH3效果的影响。实验结果表明,采用10mL Pd^2+浓度为0.112mol/L的水溶液作为吸收液净化含低浓度PH3的混合气,在反应温度22℃、O2体积分数5%、PH3质量浓度850mg/m^3、混合气流量190mL/min的条件下,印min之内PH3去除率保持在90%以上。Pd^2+浓度越高、O2体积分数越大、反应温度越高,PH3去除率越高;混合气流量越大,PH3去除率越低;反应温度越低、O2体积分数越大,PH3去除率的下降速率越小。  相似文献   
76.
Odorous air samples collected from several sources were presented to an olfactometer, an electronic nose, a hydrogen sulfide (H(2)S) detector and an ammonia (NH(3)) detector. The olfactometry measurements were used as the expected values while measurements from the other instrumentation values became input variables. Five hypotheses were established to relate the input variables and the expected values. Both linear regression and artificial neural network analyses were used to test the hypotheses. Principal component analysis was utilized to reduce the dimensionality of the electronic nose measurements from 33 to 3 without significant loss of information. The electronic nose or the H(2)S detector can individually predict odor concentration measurements with similar accuracy (R (2) = 0.46 and 0.50, respectively). Although the NH(3) detector alone has a very poor relationship with odor concentration measurements, combining the H(2)S and NH(3) detectors can predict odor concentrations more accurately (R (2) = 0.58) than either individual instrument. Data from the integration of the electronic nose, H(2)S, and NH(3) detectors produce the best prediction of odor concentrations (R (2) = 0.75). With this accuracy, odor concentration measurements can be confidently represented by integrating an electronic nose, and H(2)S and NH(3) detectors.  相似文献   
77.
Concentrations of six heavy metals (Cu, Ni, Zn, Cd, Cr, and Pb) in sediments and fine roots, thick roots, branches, and leaves of six mangrove plant species collected from the Futian mangrove forest, South China were measured. The results show that both the sediments and plants in Futian mangrove ecosystem are moderately contaminated by heavy metals, with the main contaminants being Zn and Cu. All investigated metals showed very similar distribution patterns in the sediments, implying that they had the same anthropogenic source(s). High accumulations of the heavy metals were observed in the root tissues, especially the fine roots, and much lower concentrations in the other organs. This indicates that the roots strongly immobilize the heavy metals and (hence) that mangrove plants possess mechanisms that limit the upward transport of heavy metals and exclude them from sensitive tissues. The growth performance of propagules and 6-month-old seedlings of Bruguiera gymnorhiza in the presence of contaminating Cu and Cd was also examined. The results show that this plant is not sufficiently sensitive to heavy metals after its propagule stage for its regeneration and growth to be significantly affected by heavy metal contamination in the Futian mangrove ecosystem. However, older mangrove seedlings appeared to be more metal-tolerant than the younger seedlings due to their more efficient exclusion mechanism. Thus, the effects of metal contamination on young seedlings should be assessed when evaluating the risks posed by heavy metals in an ecosystem.  相似文献   
78.
Environmental Geochemistry and Health - Based on 1625 data collected from the published literature, the geochemistry of tin (Sn) in Chinese coals, including the abundance, distribution, modes of...  相似文献   
79.
Utilizing stable carbon isotope data to account for aceticlastic and non-aceticlastic pathways of methane generation, a model was created to describe laboratory batch anaerobic decomposition of cellulosic materials (office paper and cardboard). The total organic and inorganic carbon concentrations, methane production volume, and methane and CO2 partial pressure values were used for the model calibration and validation. According to the fluorescent in situ hybridization observations, three groups of methanogens including strictly hydrogenotrophic methanogens, strictly aceticlastic methanogens (Methanosaeta sp.) and Methanosarcina sp., consuming both acetate and H2/H2CO3 as well as acetate-oxidizing syntrophs, were considered. It was shown that temporary inhibition of aceticlastic methanogens by non-ionized volatile fatty acids or acidic pH was responsible for two-step methane production from office paper at 35 °C where during the first and second steps methane was generated mostly from H2/H2CO3 and acetate, respectively. Water saturated and unsaturated cases were tested. According to the model, at the intermediate moisture (150%), much lower methane production occurred because of full-time inhibition of aceticlastic methanogens. At the lowest moisture, methane production was very low because most likely hydrolysis was seriously inhibited. Simulations showed that during cardboard and office paper biodegradation at 55 °C, non-aceticlastic syntrophic oxidation by acetate-oxidizing syntrophs and hydrogenotrophic methanogens were the dominant methanogenic pathways.  相似文献   
80.
说明目前乡镇工业企业中职业安全卫生问题十分突出。据调查,厂矿工伤事故发生率为8.23%,每千名职工的工伤发生率为2.66人,每十万名职工的工伤死亡率为7.02人。通过对事故的原因进行分析,提出了加强监督管理的建议。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号