Phosphate recovery with granular acid-activated neutralized red mud: Fixed-bed column performance and breakthrough curve modelling

Granular acid-activated neutralized red mud (AaN-RM) has been successfully prepared with good chemical stability and physical strength. However, its potential for industrial application remains unknown. Therefore, the performance of granular AaN-RM for phosphate recovery in a fixed-bed column was investigated. The results demonstrated that the phosphate adsorption performance of granular AaN-RM in a fixed-bed column was affected by various operational parameters, such as the bed depth, flow rate, initial solution pH and initial phosphate concentration. With the optimal empty-bed contact time (EBCT) of 24.27 min, the number of processed bed volumes and the phosphate adsorption capacity reached 496.95 and 84.80 mg/g, respectively. Then, the saturated fixed-bed column could be effectively regenerated with a 0.5 mol/L HCl solution. The desorption efficiency remained as high as 83.45% with a low weight loss of 3.57% in the fifth regeneration cycle. In addition, breakthrough curve modelling showed that a 5-9-1 feed-forward artificial neural network (ANN) could be effectively applied for the optimization of the fixed-bed adsorption system; the coefficient of determination (R²) and the root mean square error (RMSE) evaluated on the validation-testing data were 0.9987 and 0.0183, respectively. Therefore, granular AaN-RM fixed-bed adsorption exhibits promising potential for phosphate removal and recovery from polluted water.     

试论我国陆地再生能源资源及其特征

在世界矿物能源资源日趋减少的今天,再生能源资源引起人们广泛的兴趣,特别是陆地再生能源资源更是如此。本文对我国陆地再生能源资源——太阳能、风能、水能、生物质能——中的前两种能源资源进行了分区及分省计算,并依据全国已有的调查及普查资料,对后两种源能资源进行了分省及分区统计,在此基础上又对全国陆地再生能源资源的数量、分布及特征进行了对比分析,并从宏观上提出了开发利用我国陆地再生能源资源的建议和设想。     

内电解组合工艺处理重度富营养化水体的初步中试试验

采用催化铁内电解-沸石床-生物活性炭组合工艺进行了处理重度富营养化水的中试试验.通过对进水与出水浊度、TP、CODMn、UV254、总铁、NH3-N、和NO2--N的监测,研究了本组合工艺对重度富营养化水体的处理性能.试验期间,水温约在10℃.初步结果表明,本组合工艺对浊度、TP、CODMn和UV254均有较好的去除作用,平均去除率达到50%以上,出水中铁含量均低于进水.由于水温过低,未观察到氨氮和亚硝酸盐氮的明显变化.     

宁夏盐池县社会经济与环境协调发展的策略分析

本文通过分析宁夏盐池县的自然条件、自然资源以及社会经济发展与环境的关系,应用权图影响结构模型对该县社会经济与环境系统进行了定量的分析与研究。建立了7个模型,并通过预测、比较实施不同发展策略后各模型的系统状态,找出了使系统优化运行的灵敏调控点,分析了各分项调整策略之间相互制约、相互促进的关系,提出了使该县社会经济与环境协调发展的策略。     

Characterization of a novel marine aerobic denitrifier Vibrio spp. AD2 for efficient nitrate reduction without nitrite accumulation

Environmental Science and Pollution Research - Aerobic denitrifiers have the potential to reduce nitrate in polluted water under aerobic conditions. A salt-tolerant aerobic denitrifier was newly...     

1025t/h四角切圆煤粉炉内空气过量系数对NO生成的影响

文章采用计算流体力学软件Fluent数值模拟了1 025 t/h四角切圆煤粉炉内的湍流扩散燃烧,分析了空气过量系数对炉内烟气速度、烟气温度和氮氧化物组分的影响。结果表明:空气过量系数会对炉内流场的空气动力学特性和温度场分布均匀性产生显著影响。煤粉炉膛最佳空气过量系数为1.07,此时炉内温度场、速度场和浓度场的分布可使燃烧中间产物HCN和NH_3较好的将燃料型NO还原为N_2,来充分发挥空气分级燃烧降低NO排放的功效。     

石化管道储运员工心理评估结果分析

目的:了解石油管道储运员工的心理健康现状,建立管道储运员工症状自评量表(SCL-90)的群体常模。方法:运用整群抽样方法和症状自评量表(SCL-90)对5544名中国石化管道储运公司员工进行心理健康状况调查,将SCL-90结果与中国常模比较。结果:本次调查心理健康状况好3947人,占71.2%;心理健康状况良好1299人,占23.4%;心理健康状况一般238人,占4.3%;心理健康状况异常60人,占1.1%;石化管道储运员工在躯体化、焦虑、精神病性、阳性项目数均分显著高于全国常模;人际关系、敌对、偏执和精神病性因子均分男性显著高于女性,恐怖因子均分女性显著高于男性;35岁及以上组的躯体化、强迫、抑郁、焦虑、敌对、恐怖、精神病性以及阳性项目数的因子均分均高于35岁以下组;大专组和高中及以下组各项因子均分均显著高于本科及以上组。结论:管道储运员工心理健康状况低于一般人群。年龄相对较大以及学历相对较低员工的心理健康状况是企业关注的重点。     

焦化废水处理工程调试运行研究

针对焦化废水处理调试运行存在的问题,以实际运行中的焦化废水处理工程为例,介绍了其调试运行过程.指出焦化废水调试及稳定运行的控制要点,并提出调试运行过程中可能出现的问题及解决措施,为同类废水的调试和运行提供参考.     

Preparation and microwave absorbing properties of the core-nanoshell composite absorbers with the magnetic fly-ash hollow cenosphere as core

Electromagnetic (EM) wave pollution has become the chief physical pollution for environment. The core-nanoshell composite absorbers with magnetic fly-ash hollow cenosphere as core and nanocrystalline magnetic material as shell were prepared by high-energy ball milling. The results of X-ray diffraction analysis (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and vector network analyzer (VNA) analysis indicated that perfect-crystalline nanomagnetic material coating was gotten with a particle size of 12 nm, being dried at 60°C for 2 hr and calcined at 400°C for 1 hr after ball milling. The exchange-coupling interaction happened between ferrite of cenosphere and soft magnet γ-Fe₂03 coating, it enhances magnetic loss of composite absorbers. In the frequency between 1 MHz and 1 GHz, the absorbing effectiveness of the core-nanoshell composite absorbers can achieve ?30 dB, it is better than single material and is consistent with requirements of the microwave absorbing material at the low-frequency absorption.     

基于流域视角的水环境综合治理规划研究——以江苏省淀山湖为例

以流域为单元进行水资源综合规划和管理是实现水环境改善的重要途径。本文以太湖流域第二大省界湖泊—淀山湖为例,在综合分析流域水环境质量基础上,利用GIS 分析工具划分流域治理片区并制定分区管控策略。根据流域所含骨干河流流向、骨干河流与淀山湖交汇特点、上中下游不同河段及镇域行政边界,将淀山湖流域分为吴淞江流域、千灯浦- 淀山湖流域、昆南湖荡流域、元荡湖荡流域、太浦河流域五大片区138 个子评价单元。通过水环境容量与压力两类空间叠加分析,构建形成污染重点减排区、污染综合治理区、产业绿色化提升区、生态环境保育区等四个类型区域,并提出差异化的产业准入和环境治理措施。本研究不仅为以流域为治理单元的水环境治理规划提供了较为可行的技术体系,而且为太湖流域水环境综合整治思路创新提供了可借鉴的案例。