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251.
Li YX Han W Yang M Feng CH Lu XF Zhang FS 《Environmental monitoring and assessment》2012,184(8):5035-5041
Concentrated animal feeding operations have been recognized as one of the most important contributors of natural estrogens which show significant endocrine-disrupting properties in aquatic environments. In this study, the concentrations of 17α-estradiol (17α-E2), 17β-estradiol (17β-E2), estrone (E1), and estriol (E3) in several matrices, including soils (surface and deep), sediments (surface and deep), and groundwaters, around a typical dairy farm were surveyed using gas chromatography/mass spectrometry. Of the two farmlands, surface and subsurface sediments in waste lagoon and along effluent drainage drench, the concentrations of 17α-E2, 17β-E2, and E1 ranged from below detection limit to the highest level of 6.60 μg/kg, except that E3 was not detectable. Three estrogens of 17α-E2, 17β-E2, and E1 with the concentrations of 3.18-31.61 ng/L were observed in two groundwater samples. The results clearly demonstrated the vertical migration and horizontal transport of estrogens in the investigated area. Within 750-m distance, it was observed the attenuation of 17α-E2, 17β-E2, and E1 along the effluent route and the horizontal migration of estrogens was less than 1,350 m in this survey. 相似文献
252.
The presence of the anesthetic lidocaine (LDC), the analgesic tramadol (TRA), the antidepressant venlafaxine (VEN) and the metabolites O-desmethyltramadol (ODT) and O-desmethylvenlafaxine (ODV) was investigated in wastewater treatment plant (WWTP) effluents, in surface waters and in groundwater. The analytes were detected in all effluent samples and in only 64% of the surface water samples. The mean concentrations of the analytes in effluent samples from WWTPs with wastewater from only households and hospitals were 107 (LDC), 757 (TRA), 122 (ODT), 160 (VEN) and 637 ng L(-1) (ODV), while the mean concentrations in effluents from WWTPs treating additionally wastewater from pharmaceutical industries as indirect dischargers were for some pharmaceuticals clearly higher. WWTP effluents were identified as important sources of the analyzed pharmaceuticals and their metabolites in surface waters. The concentrations of the compounds found in surface waters ranged from 相似文献
253.
Toda K Tokunaga W Gushiken Y Hirota K Nose T Suda D Nagai J Ohira S 《Journal of environmental monitoring : JEM》2012,14(5):1462-1472
A micro-gas analysis system (μGAS) was developed for mobile monitoring and continuous measurements of atmospheric HCHO. HCHO gas was trapped into an absorbing/reaction solution continuously using a microchannel scrubber in which the microchannels were patterned in a honeycomb structure to form a wide absorbing area with a thin absorbing solution layer. Fluorescence was monitored after reaction of the collected HCHO with 2,4-pentanedione (PD) in the presence of acetic acid/ammonium acetate. The system was portable, battery-driven, highly sensitive (limit of detection = 0.01 ppbv) and had good time resolution (response time 50 s). The results revealed that the PD chemistry was subject to interference from O(3). The mechanism of this interference was investigated and the problem was addressed by incorporating a wet denuder. Mobile monitoring was performed along traffic roads, and elevated HCHO levels in a street canyon were evident upon mapping of the obtained data. The system was also applied to stationary monitoring in a forest in which HCHO formed naturally via reaction of biogenic compounds with oxidants. Concentrations of a few ppbv-HCHO and several-tens of ppbv of O(3) were then simultaneously monitored with the μGAS in forest air monitoring campaigns. The obtained 1 h average data were compared with those obtained by 1 h impinger collection and offsite GC-MS analysis after derivatization with o-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBOA). From the obtained data in the forest, daily variations of chemical HCHO production and loss are discussed. 相似文献
254.
Ali-Khodja H Belaala A Demmane-Debbih W Habbas B Boumagoura N 《Environmental monitoring and assessment》2008,138(1-3):219-231
Total suspended particulate matter and deposition fluxes of particles were investigated in the town of Didouche Mourad which
is located 13 km north of Constantine. Samples of air particulate matter were collected at one site located in the heart of
the town and situated 3 km north of a cement plant. Samples were collected from 2 November 2002 to 28 April 2003 every 3 days
using a high volume air sampler. Sampling intervals were 24 h in all cases. During the same period, samples of dust fallout
were collected at the same site. Samples were collected at 30-day intervals. Lead, chromium, manganese, nickel, copper, cobalt
and cadmium deposition fluxes were measured and both the soluble and insoluble fractions were determined. Furthermore, the
information gathered by this study was correlated with the corresponding hourly weather data provided by a weather station
installed at the study station. The possible sources for dust and trace metals were analyzed by comparing average contributions
of wind aspects to the concentrations and depositions of mass and chemical species with the average frequencies of wind direction.
The mean concentration was 300 μg/m3. The average dust deposition rate through the period of study was 221 mg/(m2.day). Results indicate that anthropogenic sources contribute greatly to trace elements. An exposure assessment to the heavy
metals taking into account the inhalation route and soil dust ingestion was carried out and allowed direct comparison of trace
metal intakes via these routes. 相似文献
255.
Pesch R Pehlke H Jerosch K Schröder W Schlüter M 《Environmental monitoring and assessment》2008,136(1-3):313-325
In this article a concept is described in order to predict and map the occurrence of benthic communities within and near the
German Exclusive Economic Zone (EEZ) of the North Sea. The approach consists of two work steps: (1) geostatistical analysis
of abiotic measurement data and (2) calculation of benthic provinces by means of Classification and Regression Trees (CART)
and GIS-techniques. From bottom water measurements on salinity, temperature, silicate and nutrients as well as from punctual
data on grain size ranges (0–20, 20–63, 63–2,000 μ) raster maps were calculated by use of geostatistical methods. At first
the autocorrelation structure was examined and modelled with help of variogram analysis. The resulting variogram models were
then used to calculate raster maps by applying ordinary kriging procedures. After intersecting these raster maps with punctual
data on eight benthic communities a decision tree was derived to predict the occurrence of these communities within the study
area. Since such a CART tree corresponds to a hierarchically ordered set of decision rules it was applied to the geostatistically
estimated raster data to predict benthic habitats within and near the EEZ. 相似文献
256.
An enzyme-limited immunosorbent assay (ELISA) was used to monitor spatial and temporal variation of microcystins (MCs) in Lake Taihu. MC concentrations were higher in summer and autumn than in other seasons. Maximal MC concentration was 15.6 mug L(-1). Compared to central Lake Taihu and Wuli Bay, Meiliang Bay had higher MC concentrations due to high biomass of Microcystis. 相似文献
257.
Tao Y Yao S Xue B Deng J Wang X Feng M Hu W 《Journal of environmental monitoring : JEM》2010,12(12):2282-2289
Sources, partitioning and toxicological risk of 15 priority polycyclic aromatic hydrocarbons (PAHs) in surface sediments from drinking water sources of Taihu Lake, with an area of 2428 km(2) located in the most developed and populated area of China, were studied, and the results were compared with those in other lakes of China and the USA. Concentrations of the 15 PAHs in sediments ranged from 436.6 to 1334.9 ng g(-1) (dw). Gasoline combustion, coal combustion, diesel combustion from shipping and spillage of petroleum were apportioned to be the main sources of PAHs in this area by principal component analysis, which contributed 35.19%, 26.43%, 25.41% and 12.97% to the PAH sources estimated by further multiple linear regression. Levels of PAHs in sediments were negatively correlated with contents of clay and fine silt (<16 μm), while positively with contents of medium silt, coarse silt and sand (>16 μm). Humin with size larger than 16 μm contained the largest part of the burden of PAHs in sediments, but the specific partitioning domain (bound humic acid, lipid or insoluble residue) depended on properties of organic matter reflected by optical absorbance at 465 and 665 nm. Total toxic benzo[a]pyrene equivalent (TEQ(carc)) of the carcinogenic PAHs in sediments varied from 31.8 to 209.3 ngTEQ(carc) g(-1). Benzo[a]pyrene and dibenzo[a,h]anthracene contributed 45.36 and 25.31% to total TEQ(carc), posing high toxicological risk to this area. 相似文献
258.
通过对昌吉州农田地膜使用现状进行调查,阐述了地膜污染的危害,并提出了适期揭膜、残膜回收、推广新型生物膜等措施与防治对策。 相似文献
259.
Spatial and seasonal distribution of nitrogen in marsh soils of a typical floodplain wetland in Northeast China 总被引:3,自引:0,他引:3
Bai J Wang Q Deng W Gao H Tao W Xiao R 《Environmental monitoring and assessment》2012,184(3):1253-1263
Horizontal and profile distributions of nitrogen in marsh soils in different seasons were studied in a typical site within
the Erbaifangzi wetland in Northeast China. Results showed that there was higher spatial heterogeneity for nitrate nitrogen
(NO3--_{3}^{-}-N) and ammonium nitrogen (NH4+_{4}^{+}–N), as well as available nitrogen (AN), in surface soils in July compared to that in September. Relative to July, the mean
nitrogen contents in surface soils were slightly higher in September; however, in November, soils contained significantly
lower NO3--_{3}^{-}-N and NH4+_{4}^{+}–N, higher AN, organic nitrogen (Org-N), and total nitrogen (TN). Except for mineral nitrogen, no significant differences
were observed between Org-N and TN contents in September and November. Nitrogen contents generally declined exponentially
with depth along soil profiles in three sampling dates (July, September, and November), except for a significant accumulation
peak of NO3--_{3}^{-}-N at the 20–30 cm depth in September. However, NH4+_{4}^{+}–N contents showed a vertical alternation of “increasing and decreasing” in both July and September, while nearly kept constant
with depth in November. The depth ranking of nitrogen showed the shallowest distribution for AN, followed by Org-N and TN,
while deeper distributions for NO3--_{3}^{-}-N and NH4+_{4}^{+}–N. TN, Org-N, and AN were significantly correlated with soil organic matter and total phosphorus. Soil pH values were significantly
correlated with TN and AN contents in surface soils. Clay contents showed significant correlations with nitrogen contents
except for NO3--_{3}^{-}-N in surface soils and NH4+_{4}^{+}–N in profile soils. However, soil moisture was not significantly correlated with nitrogen contents among all soil samples. 相似文献
260.
Wang M Markert B Chen W Peng C Ouyang Z 《Environmental monitoring and assessment》2012,184(10):5889-5897
In order to evaluate the current state of the environmental quality of soils in Beijing, we investigated contents of 14 metals in Beijing urban soils inside the 5th ring road by even grids sampling. Statistic analyses were conducted to identify possible heavy metal pollutants, as well as the effects of land uses on their accumulation. Our results revealed that the urban soils in Beijing were contaminated by Cd, Pb, Cu, and Zn. Land uses and urbanization ages affected the accumulation of the four heavy metals in soils significantly. Soils in industrial areas have the highest average Cu and Zn contents, while Pb contents in park areas and Cd in agricultural areas are the highest. The accumulations of Pb and Zn in urban soils increase significantly with sampling plots approaching the city center. And Pb, Cd, and Zn contents in soils in traffic areas also tend to increase in the city center. However, residential areas have the lowest contents of all the four heavy metals. 相似文献