Pennsylvania’s Compuiterized Air Monitoring System

The Pennsylvania Air Pollution Commission has developed a regulatory program based upon the control of local air pollution problems and reduction of pollutant levels in air basins. The geographical boundaries of 10 air basins have been established. The Commission’s air basin regulations will provide for the reduction of over-all pollutant levels and for emergency procedures in the event of adverse meteorological conditions. The paper discusses the format and objectives of the program.

In order to effectively enforce the air basin regulations and maintain the necessary surveillance of the state’s air quality, a "computerized real time on-line integrated air monitoring-data handling system" has been designed. The system will incorporate a network to constantly monitor the air in each air basin.The primary objectives of the system are: 1. Constant surveillance of air pollution in the air basins.

2. Provide information on air pollution potential alerts.

3. Aid in further development of air quality criteria and regulations.

The air monitoring network is estimated to include approximately 25 remote stations. Each remote will contain air pollution and meteorological sampling equipment and hardware to telemeter to a central station. The data will be transmitted over leased telephone lines. The central station in Harrisburg will contain the necessary hardware to receive and process data, calculate and display results and permit supervisory control of the network. Output options will include immediate display of edited data, command and alarm information, and presentation of statistical results.

Although the air monitoring system is one of the principle ingredients of the program, the air basin concept encompasses other component systems designed to knit together the entire air pollution control program in Pennsylvania.     

The Continuous Analysis of Sulfur Dioxide in Gaseous Samples

Sulfur dioxide is quantitatively scrubbed from atmospheric and stack gas samples through the use of a unique rotary scrubber which provides collection efficiencies in excess of 97% in the PPB through PPM range. The scrubber in addition permits the use of water as a scrubbing vehicle which, when combined with a bleached pararosanaline reagent, provides high specificity and sensitivity for the analysis. By the elimination of the tetrachloromercurate solution, cell staining is eliminated and the stability required for continuous analysis by the reagent is achieved.     

Annotated Bibliography for Air Pollution Meteorology

This annotated bibliography was prepared for the purpose of directing interested persons to some of the more helpful references in the field of air pollution meteorology. It obviously is not a complete listing. The reader who requires more information is directed to the references in the articles listed.     

A Comparative Study of Particulate Loadings in Plumes Using Multiple Sampling Devices

Particle size distributions, particulate concentrations, and particle identities must be known to relate effluents to reduction in visibility and soiling. Similar types of emissions were measured with cascade impactor, membrane filter, and rotorod samplers. The different particle size distributions, concentrations, and identifications are reported. Discussion of and recommendations for utilization of these three methods of sampling are made.     

Recent Electrostatic Precipitator Experience with Ammonia Conditioning of Power Boiler Flue Gases

Motivated by heightened recent interest, Koppers Co. has been experimenting with ammonia conditioning of power boiler flue gases for the purpose of improving the precipitability of the emitted fly ash. Chemical reactions resulting from ammonia injection are postulated. Measurements on three pulverized coal and two cyclone fired boilers, all of which emit acidic ash, are described. In all five cases, considerable but varying, increase in precipitator power input and collection efficiency resulted when gaseous ammonia in the amount of 1 5 ppm was injected between the economizer and air preheater. The conditioned fly ash showed decreased acidity and inconsistent change in electrical resistivity. Unless air heater temperatures were unusually high (>400°F), tendency of the air heater to plug was an additional, but unwanted, result. At one station with high air heater outlet temperature ammonia injection has been adopted as a permanent solution to community pressure for reduction of stack discharge. Ammonia injection downstream of the air heater produced no effect. Future plans are presented to continue the program beyond results described here.     

A Model for Gaseous Pollutant Sorption by Leaves

A model simulating pollutant exchange with isolated leaves that integrates factors which have been found to be important in regulating pollutant uptake by leaves is presented. The model is patterned after an electrical analogue simulator and was designed to emphasize the effects of pollutant and leaf properties on the process. The article discusses the relative significance of factors affecting gas transfer, sorption of pollutants by leaf surfaces, and pollutant solubility and fate on the uptake process. Data is presented showing uptake of ozone by exposed mesophyll and several epidermal surfaces chosen for their different surface characteristics. The model was used to derive a mathematical expression for the exchange process which was rearranged to define internal (average) pollutant solute concentration in terms of external concentration, leaf and boundary layer diffusion resistance, surface sorption and pollutant solubility. The importance of estimating internal solute concentration is discussed.     

Determination of Oxides of Nitrogen in Combustion Effluents with a Nitrate Ion Selective Electrode

The nitrate ion selective electrode was investigated as an alternative approach to the present colorimetric determination of nitrate resulting from oxidative absorption of nitrogen oxides from combustion effluents. The electrode offers advantages of speed and relatively simple experimental procedure. Replicate measurements of 10^?4–10^?2M nitric acid solutions using bracketing standards show that the electrode approach is capable of good precision (coefficient of variation = ±4%). Comparison of a method utilizing the nitrate electrode with the more laborious phenol disulfonic acid method for the measurement of nitrogen oxides in both oil and gas fired combustion effluents showed agreement within 4% of the mean even in the presence of high levels of SO₂. The correlation coefficient found for PDS vs nitrate electrode is 0.987.     

Sulfur Dioxide Fumigation of Soybeans: Effect on Yield

In order to determine the influence of SO₂ fumigation of soybean plants on yield, a three-year experiment was conducted on 485 plois of soybeans. Single fumigations of S0₂ were applied at 10 different stages of growth in 1968-69 and 7 stages of growth in 1970. A linear relationship was found to exist beiween the percent of leaf area destroyed and ihe percent crop loss with a significant regression coefficient of b = —0.659, or iwo-thirds of one percent crop loss for each percent of area destroyed. No definite significant stage-of-growth effect was found and no treatment effects were significant for the early stages of growth from the 3-leaf to the 15-leaf stage, nor was there any loss in yield without visible leaf injury.