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991.
This work investigated the degradation of a natural estrogen (17beta-estradiol) and the removal of estrogenic activity by the ozonation process in three different pHs (3, 7 and 11). A recombinant yeast assay (YES assay) was employed to determine estrogenic activity of the ozonized samples and of the by-products formed during the ozonation. Ozonation was very efficient for the removal of 17beta-estradiol in aqueous solutions. High removals (>99%) were achieved with low ozone dosages in the three different pHs. Several by-products were formed during the ozonation of 17beta-estradiol. However, only a few compounds could be identified and confirmed. Different by-products are formed at different pHs, which is probably due to different chemical pathways and different oxidants (O(3) and OH radical). The by-products formed at pH 11 were 10epsilon-17beta-dihydroxy-1, 4-estradieno-3-one (DEO) and 2-hydroxyestradiol, which were not formed in pH 3. Only testosterone could be observed in pH 3, whereas at pH 7 all three by-products were found. At pH 7 and 11 the applied ozone dosages were not enough to remove all the estrogenicity from samples, even though the 17beta-estradiol residual concentration for these two pHs was lower than at pH 3. Higher estrogenicity was detected at pH 11. An explanation to this fact may be that oxidation via OH radical forms more by-products with estrogenic activity. Probably, the formation of 2-hydroxyestradiol at pHs 7 and 11 is contributing to the residual estrogenicity of samples ozonized at these pHs. In this work, complete removal of estrogenic activity was only obtained at pH 3. 相似文献
992.
Cyclic voltammetry and spectral FTIR studies of the influence of activated carbon surface modification on the co-adsorption of metal cation (lead or iron) and phenol from aqueous acidic solution were carried out. The diversity in surface chemical structure was achieved by applying different procedures of inorganic matter removal and by modifying the carbon samples in various ways: heating under vacuum, aminoxidation in an ammonia-oxygen atmosphere, oxidation with concentrated nitric acid. The quantities of adsorbed metal ions (Pb(2+) or Fe(3+)) and phenol from solutions containing cation or phenol separately or in a mixture were determined. The adsorption capacity from acidic aqueous acidic solution depends on the chemical properties of the activated carbon surface (e.g., decrease in phenol adsorption with relative lower basicity of the adsorbent). The electrochemical parameters of electrodes made from the carbon samples were estimated, and some possible electrochemical reactions were determined from voltammograms recorded in acid electrolyte solution containing adsorbed species (separately or as a mixture). Relationships were found between metal ion adsorption and electrochemical behavior of Pb(2+)/Pb(4+) and Fe(3+)/Fe(2+) couples on the one hand, and the presence of phenol in the solutions tested and the influence of surface chemistry of the carbon electrodes on electrochemical processes on the other. The changes in adsorption capacity with respect to the adsorbates used and the changes in FTIR spectra of the carbons as a result of adsorption and/or coupling phenol molecules are discussed. 相似文献
993.
Bioremediation process on Brazil shoreline 总被引:1,自引:0,他引:1
GOAL, SCOPE AND BACKGROUND: Bioremediation technique can be considered a promising alternative to clean oil spills using microbial processes to reduce the concentration and/or the toxicity of pollutants. To understand the importance of this work we must know that there is only little research performed to date using bioremediation techniques to clean oil spills in tropical countries. So, the main objective of this work is to analyze the behavior of a laboratory's bioremediation test using nutrients on coastal sediments. METHODS: The bioremediation process is followed through geochemical analysis during the tests. This organic material is analyzed by medium pressure liquid chromatography (MPLC), gas chromatography/flame ionization detection (GC/FID) and gas chromatography/ mass spectrometry. By microbial counting, the number of total bacteria and degrading bacteria is determined during the experiments, in order to confirm the effectiveness of the bioremediation process. The seawater obtained throughout the bioremediation process is analyzed for nutrients grade (phosphate and ammonium ions) and also for its toxicity (Microtox tests) due the presence of hydrocarbons and fertilizer. RESULTS: The results from the geochemical analyses of the oil show a relative decrease in the saturated hydrocarbon fraction that is compensated by a relative enrichment on polar compounds. It's confirmed by the fingerprint evaluation where it is possible to see a complete reduction of the normal alkanes followed by isoprenoids. Seawater analysis done by toxicity and nutrients analysis, such as microbial counting (total and degrading bacteria), confirm the fertilizer effectiveness during the bioremediation process. DISCUSSION: Results from simulating test using NPK, a low-price plant fertilizer, suggest that it's able to stimulate the degradation process. Results from medium pressure liquid chromatography (MPLC), done at two different depths (surface and subsurface), show different behavior during the biodegradation process where the later is seen to be more susceptible to microbial attack. Data from bioremediation unit shows a bigger reduction of the saturated fraction, followed by some smaller reduction of aromatic fractions, compensated by a relative increase from polar compounds (NSO). n-C17/pristane, n-C18/ fitane and pristane/fitane rates show constant values for the unity control, different from bioremediation samples which have a significant reduction, especially on subsurface areas, where a strong fall in the rates, seen to be reduced to zero over twenty days, had occurred during the first ten days. However, sample surfaces are reduced to zero in thirty days of experiments, proving that biodegradation is better on subsurfaces. Gaseous chromatography/mass spectrometry (CG/MS) analysis shows constant values to cyclic biomarker rates and aromatic compounds, suggesting that the biodegradation process is not strong enough to reduce these composites. Microbial analysis shows a reduction on heterotrophic (total bacteria) number from control unit, probably because the bacteria uses the spill oil like carbon source and energy. However, the number increases on bioremediation unit, because it uses NPK like a biostimulator. The hydrocarbonoclastic number isn't enough on the first moment, but it's detected after 30 days and quantified in all units, showing big values especially in bioremediation. Toxicity tests confirm that NPK fertilizer does not intoxicate the shoreline during the application of the bioremediation technique. Some nutrient concentration shows high values of ammonium and phosphate per bioremediation unit, reducing by the end of the experiment. CONCLUSIONS: Results reached the goal, finding a proper nutrient (NPK fertilizer) to stimulate the biodegradation process, growing bacteria responsible for reducing impact-contaminated coast ambient by oil spills. Chemical analysis of oil shows a reduction in the saturated fraction with a relative enrichment in polar composites (NSO) and the aromatic fraction from oil remaining constant. Subsurface samples show more biodegradation than surface samples, probably because the first one has higher humidity. Linear alcanes are more biodegraded than isoprenoids, confirming the biodegradation susceptibility order. Saturated cyclic biomarkers and aromatic compounds show constant behavior maybe because the nutrients or time was not enough for microorganismic attack. Fertilizer does not demonstrate any toxic effects in local biota so that it does not compromise the technique applicability and the environment is not saturated by nutrients during the simulation, especially since the coastal environment is an open system affected daily by tides. Therefore, bioremediation tests can be classified as moderate, reaching level 5 in the classification scale by Peters & Moldowan (1993). RECOMMENDATIONS AND PERSPECTIVES: The use of marine environment by the petroleum industry on exploration, production and transportation operation, transform this oil to become the most important pollutant in the oceans. Bioremediation is an important technique used to clean spilled oil impacting on shorelines, accelerating the biodegradation process by using fertilizer growing the microorganisms responsible for decontaminating the environment. We recommend confirming the efficiency of NPK nutrient used on bioremediation simulating experiments on beaches, while monitoring the chemical changes long-term. NPK fertilizer can be used to stimulate the biodegradation process on shoreline impacted by spilled oil. 相似文献
994.
Paz-Alberto AM Sigua GC Baui BG Prudente JA 《Environmental science and pollution research international》2007,14(7):498-504
Background, Aims and Scope The global problem concerning contamination of the environment as a consequence of human activities is increasing. Most of
the environmental contaminants are chemical by-products and heavy metals such as lead (Pb). Lead released into the environment
makes its way into the air, soil and water. Lead contributes to a variety of health effects such as decline in mental, cognitive
and physical health of the individual. An alternative way of reducing Pb concentration from the soil is through phytoremediation.
Phytoremediation is an alternative method that uses plants to clean up a contaminated area. The objectives of this study were:
(1) to determine the survival rate and vegetative characteristics of three grass species such as vetivergrass, cogongrass
and carabaograss grown in soils with different Pb levels; and (2) to determine and compare the ability of the three grass
species as potential phytoremediators in terms of Pb accumulation by plants.
Methods The three test plants: vetivergrass (Vetiveria zizanioides L.); cogongrass (Imperata cylindrica L.); and carabaograss (Paspalum conjugatum L.) were grown in individual plastic bags containing soils with 75 mg kg−1 (37.5 kg ha−1) and 150 mg kg−1 (75 kg ha−1) of Pb, respectively. The Pb contents of the test plants and the soil were analyzed before and after experimental treatments
using an atomic absorption spectrophotometer. This study was laid out following a 3 × 2 factorial experiment in a completely
randomized design.
Results On the vegetative characteristics of the test plants, vetivergrass registered the highest whole plant dry matter weight (33.85–39.39
Mg ha−1). Carabaograss had the lowest herbage mass production of 4.12 Mg ha−1 and 5.72 Mg ha−1 from soils added with 75 and 150 mg Pb kg−1, respectively. Vetivergrass also had the highest percent plant survival which meant it best tolerated the Pb contamination
in soils. Vetivergrass registered the highest rate of Pb absorption (10.16 ± 2.81 mg kg−1). This was followed by cogongrass (2.34 ± 0.52 mg kg−1) and carabaograss with a mean Pb level of 0.49 ± 0.56 mg kg−1. Levels of Pb among the three grasses (shoots + roots) did not vary significantly with the amount of Pb added (75 and 150
mg kg−1) to the soil.
Discussion Vetivergrass yielded the highest biomass; it also has the greatest amount of Pb absorbed (roots + shoots). This can be attributed
to the highly extensive root system of vetivergrass with the presence of an enormous amount of root hairs. Extensive root
system denotes more contact to nutrients in soils, therefore more likelihood of nutrient absorption and Pb uptake. The efficiency
of plants as phytoremediators could be correlated with the plants’ total biomass. This implies that the higher the biomass,
the greater the Pb uptake. Plants characteristically exhibit remarkable capacity to absorb what they need and exclude what
they do not need. Some plants utilize exclusion mechanisms, where there is a reduced uptake by the roots or a restricted transport
of the metals from root to shoots. Combination of high metal accumulation and high biomass production results in the most
metal removal from the soil.
Conclusions The present study indicated that vetivergrass possessed many beneficial characteristics to uptake Pb from contaminated soil.
It was the most tolerant and could grow in soil contaminated with high Pb concentration. Cogongrass and carabaograss are also
potential phytoremediators since they can absorb small amount of Pb in soils, although cogongrass is more tolerant to Pb-contaminated
soil compared with carabaograss. The important implication of our findings is that vetivergrass can be used for phytoextraction
on sites contaminated with high levels of heavy metals; particularly Pb.
Recommendations and Perspectives High levels of Pb in localized areas are still a concern especially in urban areas with high levels of traffic, near Pb smelters,
battery plants, or industrial facilities that burn fuel ending up in water and soils. The grasses used in the study, and particularly
vetivergrass, can be used to phytoremediate urban soil with various contaminations by planting these grasses in lawns and
public parks.
ESS-Submission Editor: Dr. Willie Peijnenburg (wjgm.peijnenburg@rivm.nl) 相似文献
995.
Relation of waste generation and composition to socio-economic factors: a case study 总被引:3,自引:0,他引:3
Bandara NJ Hettiaratchi JP Wirasinghe SC Pilapiiya S 《Environmental monitoring and assessment》2007,135(1-3):31-39
To develop an effective waste management strategy for a given region, it is important to know the amount of waste generated
and the composition of the waste stream. Past research has shown that the amount of waste generated is proportional to the
population and the average mean living standards or the average income of the people. In addition, other factors may affect
the amount and composition of waste. These are climate, living habits, level of education, religious and cultural beliefs,
and social and public attitudes. This paper presents the findings of a study carried out in a suburban municipal area in Sri
Lanka to determine the solid waste generation rate and waste composition based on field surveys and to determine the related
socio-economic factors. A database was developed that included information on the quantity and composition of waste generated
in a sample of households in the study area over a time period. The collected data was analysed to relate waste generation
and composition data to various socio-economic factors. Over 400 sample households were selected for the study using a stratified
random sampling methodology based on municipal wards and property values. A technique that considers both the number of households
in a particular income group (property value range) and the standard deviation of property values within a given income group
was used to determine the appropriate sample size for each municipal ward. Through category and regression analyses, the quantities
of waste and waste composition were related to several socio-economic factors. The paper describes the basis for the sample
selection, the methodology adopted for data collection, the socio-economic parameters used for the analysis, and the relationships
developed from the analysis. 相似文献
996.
Previous work has shown that arsenic can accumulate in drinking water distribution system (DWDS) solids (Lytle et~al., 2004) when arsenic is present in the water. The release of arsenic back into the water through particulate transport and/or
chemical release (e.g. desorption, dissolution) could result in elevated arsenic levels at the consumers' tap. The primary
objective of this work was to examine the impact of pH and orthophosphate on the chemical release (i.e. desorption) of arsenic
from nine DWDS solids collected from utilities located in the Midwest. Arsenic release comparisons were based on the examination
of arsenic and other water quality parameters in leach water after contact with the solids over the course of 168~hours. Results
showed that arsenic was released from solids and suggested that arsenic release was a result of desorption rather than dissolution.
Arsenic release generally increased with increasing initial arsenic concentration in the solid and increasing pH levels (in
the test range of 7 to 9). Finally, orthophosphate (3 and 5 mg PO4/L) increased arsenic release at all pH values examined. Based on the study results, utilities with measurable levels of arsenic
present in their water should be aware that some water quality changes can cause arsenic release in the DWDS potentially resulting
in elevated levels at the consumer's tap. 相似文献
997.
Current demand analysis methods do not formally cover the case of chronic deficits in quantity or quality of water and sanitation
services. These services include drinking water supply (DWS), wastewater and sewage treatment (WST), and municipal solid waste
management (MSW). Formal analysis of this case would, at minimum, define the deficit state and evaluate appropriate options
for reducing it. This paper proposes for a formal analytical model for municipal sanitation systems (MSS) that operate with
deficits in at least one of the constituent services of DWS, WST, or MSW. The model introduces definitions and notation for
describing the deficit state for conducting demand analysis on municipal sanitation systems. This model of demand analysis
for systems with chronic deficits will hereinafter be referred to as deficit analysis. A case study for Bacoor, Philippines is presented as an example. 相似文献
998.
Almeida CA Quintar S González P Mallea MA 《Environmental monitoring and assessment》2007,133(1-3):459-465
A study of the water quality of the Potrero de los Funes River (San Luis – Argentina) was carried out in order to evaluate
the possible effect of the anthropogenic activities on the river developed in the homonymous town. Samples were collected
during the period March 2000–November 2005 at three selected sampling sites (RP1, RP2 and RP3). Different physicochemical and bacteriological parameters (turbidity, pH, conductivity, suspended solids, alkalinity, potassium,
sodium, calcium, magnesium, chlorides, nitrates, phosphates, sulphates, chemical oxygen demand (COD), 5-day biological oxygen
demand (BOD5), dissolved oxygen, total coliforms, Escherichia coli and total heterotrophic bacteria) were analysed according to the Standard Method for the Examination of Water and Wastewater.
When comparing the values of total coliforms, E. coli, total heterotrophic bacteria, COD, BOD5 and phosphates from the zone without anthropogenic influence (RP1) and the urban zones (RP2 and RP3) an important variation in the parameters was observed. These results indicate that the urban activity produces a serious
and negative effect on the water quality, thus constituting a sanitary risk and may have a major impact on the trophic status
of the Potrero de los Funes dam. As case study, we report on the use of General Quality Index (GQI) to evaluate spatial and
seasonal changes in the water quality of Potrero de los Funes River. Results revealed a significant degradation of the water
quality at RP2 and RP3. 相似文献
999.
Oritani Marsh in the Hackensack Meadowlands of urbanized northeastern New Jersey USA was assessed in 2000 for vegetation,
soil/sediment chemistry, abundance/diversity of benthic invertebrates, and bird and mammal usage. Vegetatively, both marsh
and uplands are dominated by tall, dense Phragmites australis. Small patches (less than 2 hectares total) dominated by Spartina spp. were found at the lowest elevations. Soil/sediment cores were sliced into 5 intervals and analyzed for metals, pesticides
and volatile/semivolatile organic compounds. Thirteen locations had at least one chemical above Long et al.’s [Environmental Management, 19, 1995, 81--97] “Effects Range-Median” (ERM). Seven metals and nine organics exceeded ERM in at least one sample, with mercury
showing the most exceedances. The surface 15 cm interval was generally more contaminated with metals than the 15 to 30 cm
interval; the reverse was true for semivolatile organic compounds. Twenty taxa of benthic macroinvertebrates were collected,
with each location producing from 1 to 9 taxa. Abundance ranged from 11 to 3,889 individuals/m2. Number of taxa was moderately (r
2 between 0.40 and 0.70) negatively correlated with zinc, beryllium, nickel and arsenic concentrations; no other chemical’s
r
2 was above 0.25. Diversity was moderately negatively correlated with arsenic and beryllium. These correlations were unexpected:
zinc, beryllium, nickel and arsenic were not the chemicals found at the highest concentrations relative to benchmarks. Number
of taxa, abundance and diversity were moderately (negatively) correlated with elevation; organic carbon was moderately (positively)
correlated with abundance. All other correlations were weak (r
2 < 0.35). Live traps captured only one mammal species, the meadow jumping mouse. Bird observations revealed 39 species, dominated
by a few common species. 相似文献
1000.
Individual specimens of Salmo trutta were captured, from four sampling sites in Galician rivers (NW Spain) affected by different types of contamination: diffuse urban waste, run-off from an unrestored dump at a copper mine and waste from a fish farm. The ages of the captured trouts were established and only those belonging to the 1+ age class were selected for study. The liver and kidney were removed from each fish and analysed to determine the tissue concentrations of Cu, Fe and Zn. The results obtained showed that: (i) the use of 1+ individuals allowed differentiation of contamination scenarios on the basis of the tissue concentrations of metal; (ii) the use of 1+ individuals allowed standardization of the time of exposure, which was sufficiently long for differential uptake to have taken place; (iii) liver tissue provided the best results as, less effort was required than for processing kidney tissue, and significant differences between sampling sites were detected because the intrapopulational variability in metal levels was lower than for kidney, and (iv) the levels of elements detected were not affected by basal tissue concentrations or residual concentrations due to past contamination, which older trouts may have been exposed to. In addition, the use of 1+ trout may provide better results in annual environmental sampling surveys. 相似文献