全文获取类型
收费全文 | 14884篇 |
免费 | 41篇 |
国内免费 | 972篇 |
专业分类
安全科学 | 346篇 |
废物处理 | 590篇 |
环保管理 | 1442篇 |
综合类 | 3785篇 |
基础理论 | 1074篇 |
污染及防治 | 5912篇 |
评价与监测 | 1634篇 |
社会与环境 | 905篇 |
灾害及防治 | 209篇 |
出版年
2023年 | 27篇 |
2022年 | 39篇 |
2020年 | 52篇 |
2019年 | 25篇 |
2018年 | 30篇 |
2017年 | 55篇 |
2016年 | 40篇 |
2015年 | 94篇 |
2014年 | 44篇 |
2013年 | 41篇 |
2012年 | 1231篇 |
2011年 | 1658篇 |
2010年 | 177篇 |
2009年 | 416篇 |
2008年 | 1505篇 |
2007年 | 1465篇 |
2006年 | 1158篇 |
2005年 | 1034篇 |
2004年 | 876篇 |
2003年 | 870篇 |
2002年 | 776篇 |
2001年 | 578篇 |
2000年 | 367篇 |
1999年 | 188篇 |
1998年 | 51篇 |
1997年 | 69篇 |
1996年 | 71篇 |
1995年 | 129篇 |
1994年 | 76篇 |
1993年 | 122篇 |
1992年 | 113篇 |
1991年 | 132篇 |
1990年 | 148篇 |
1989年 | 113篇 |
1988年 | 211篇 |
1987年 | 253篇 |
1986年 | 127篇 |
1985年 | 241篇 |
1984年 | 218篇 |
1983年 | 199篇 |
1982年 | 166篇 |
1981年 | 144篇 |
1980年 | 133篇 |
1979年 | 84篇 |
1978年 | 81篇 |
1977年 | 37篇 |
1976年 | 62篇 |
1975年 | 47篇 |
1974年 | 69篇 |
1973年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
961.
这项研究采用生命周期分析来探讨加拿大1990~2000年间泥炭工业温室气体(GHG)净排放量.GHG交换通过土地利用变化、泥炭开采、处理、运输到市场,以及开采的泥炭原地分解来估算.根据一个累积GHG计算模型估计显示,1990年泥炭开采生命周期中排放GHG 0.54×106t,到2000年,增加到O.89×106t(以CO2当量表示,在100年时间水平下).与最终利用相关的泥炭分解是GHG最大的排放源,在11年中,占总排放量的71%.土地利用变化导致了泥炭田由GHG汇转变为源,占了15%的份额.泥炭运输占据了GHG总排放量的10%,开采和加工占4%.如果泥炭田恢复成功,并且被完全开采了的泥炭田重新成为净碳汇,碳库恢复到原来水平也大概得需要2000年时间. 相似文献
962.
近来巴西大豆生产的增长引发了环境保护团体以及一些学者对于亚马孙盆地的热带自然环境正在向大豆种植地转换的关注.大豆生产的支持者则认为大豆是区域的一种可行性农产品;对于环境的关注是没有根据的,因为新的大豆种植地正在替代已经被砍伐的林地或者是转换了的土地.两种观点虽被提出却都没有对大豆生产扩充区的土地利用与土地覆被(LULC)状况进行过综合研究与估量.本案例研究是在巴西的朗多尼亚州,亚马孙盆地西南部的维列纳市(Vimena),通过遥感手段对1996~2001年以来该市大豆种植面积的大幅度增加所伴随的土地利用与土地覆被变化状况进行评估.结果表明虽然森林变成了大豆生产基地,但是大部分的大豆生产的增长归功于对已有土地的微量扩充、已伐林地的转换以及更高的单位产量. 相似文献
963.
YU Guang-ning ZHANG Chun-hui SU Zhong-jie FAN Xue-li PAN Yong-zhan LIU Fu-shun . Civil engineering institute Qingdao Technological University Qingdao . Engineering college Ocean University of China Qingdao . Liaoning Technical University Fuxin 《地球与环境》2005,33(Z1):17-26
<正>To control land surface subsidence caused the underground mineral exploitation and the catastrophic phenomena such as serious damage of buildings, waterbodies, cultivated lands, railways, bridges caused by land subsidence, bed separation grouting technology of overburden is put forward. To provide theoretical support for the technology, the characteristics and the mechanics mechanism of mining overburden from layer-split to formation of bed separation are studied. On the basis of elastic sheet board theory, calculation formula of rock sheet deflection is presented, and the mechanics criteria of the separation formation and the calculation formula of bed separation volume are set up. Finally, the applications and technics of bed separation grout technology of mining overburden to control land subsidence in china are introduced. 相似文献
964.
Romário J. da Silv Lizeth Carolina Mojica-Sánchez Filipe D.S. Gorz Graciela C. Pedro Bruna G. Maciel Gabriela P. Ratkovski Hérica D. da Roch Kamila T.O. do Nascimento Juan C. Medina-Llamas Alicia E. Chávez-Guajardo José J. Alcaraz-Espinoz Celso P. de Melo 《环境科学学报(英文版)》2021,33(2):62-73
We report the preparation of poly(3,4-ethylene dioxythiophene) (PEDOT)-modified polyvinylidene fluoride electrospun fibers and their use as a novel adsorbent material for the removal of the anionic dye Methyl Orange (MO) from aqueous media. This novel adsorbent material can be used to selectively remove MO on a wide pH range (3.0–10.0), with a maximum capacity of 143.8 mg/g at pH 3.0. When used in a recirculating filtration system, the maximum absorption capacity was reached in a shorter time (20 min) than that observed for batch mode experiments (360 min). Based on the analyses of the kinetics and adsorption isotherm data, one can conclude that the predominant mechanism of interaction between the membrane and the dissolved dye molecules is electrostatic. Besides, considering the estimated values for the Gibbs energy, and entropy and enthalpy changes, it was established that the adsorption process is spontaneous and occurs in an endothermic manner. The good mechanical and environmental stability of these membranes allowed their use in at least 20 consecutive adsorption/desorption cycles, without significant loss of their characteristics. We suggest that the physical-chemical characteristics of PEDOT make these hybrid mats a promising adsorbent material for use in water remediation protocols and effluent treatment systems. 相似文献
965.
Bryan Butter Paola Santander Guadalupe del C. Pizarro Diego P. Oyarzún Federico Tasc Julio Sánchez 《环境科学学报(英文版)》2021,33(3):304-312
Chromium (Cr) is used in many manufacturing processes, and its release into natural waters is a major environmental problem today. Low concentrations of Cr(VI) are toxic to human health and living organisms due to the carcinogenic and mutagenic nature of this mineral. This work examined the conversion of Cr(VI) to Cr(III) via electrochemical reduction using gold electrode in an acidic sodium alginate (SA) solution and subsequent removal of the produced Cr(III)-SA by the polymer-enhanced ultrafiltration (PEUF) technique. A solution of SA in nitric acid was used both as an electrolytic medium during the voltammetric measurements and bulk electrolysis and as an extracting agent during the PEUF technique. The electroanalysis of Cr(VI) was performed by linear sweep voltammetry in the presence of acidic SA solution to study its voltammetric behavior as a function of the Cr(VI) concentration, pH, presence of Cr(III), SA concentration and scan rate. In addition, the quantitative reduction of Cr(VI) to Cr(III) was studied through the bulk electrolysis technique.The results showed efficient reduction with well-defined peaks at approximately 0.3 V vs. Ag/AgCl, using a gold working electrode. As the pH increased, the reduction signal strongly decreased until its disappearance. The optimum SA concentration was 10 mmol/L, and it was observed that the presence of Cr(III) did not interfere in the Cr(VI) electroanalysis. Through the quantitative reduction by bulk electrolysis in the presence of acidic SA solution, it was possible to reduce all Cr(VI) to Cr(III) followed by its removal via PEUF. 相似文献
966.
S. Veerasingam R. Venkatachalapathy S. Sudhakar P. Raj V. Rajeswari 《环境科学学报(英文版)》2011,23(7):1129-1134
Eight mollusc species and sediment samples collected from three different stations along Tamilnadu coast, Bay of Bengal, India
were analysed for the levels of petroleum hydrocarbons to elucidate the status of the petroleum residues in mollusc meant for human
consumption. The concentrations of petroleum hydrocarbons in sediments along Tamilnadu coast varied from 5.04–25.5 g/g dw (dry
weight). High concentration of petroleum hydrocarbons in the sediment of Uppanar estuary (25.5 1.45 g/g dw) was perhaps land
and marine based anthropogenic sources of this region. The petroleum hydrocarbon residues in eight mollusc species collected from
Uppanar, Vellar and Coleroon estuaries varied between 2.44–6.04 g/g ww (wet weight). Although the concentration of petroleum
hydrocarbons in sediment of the Uppanar region was markedly higher than the background, the petroleum hydrocarbon residues in
mollusc collected from Uppanar estuary did not suggest bioaccumulation. The results signified that industrial growth has affected the
aquatic environments and regular monitoring will help to adopt stringent pollution control measures for better management of the
aquatic region. 相似文献
967.
Meeta Lavani Priyangshu M. Sarm Ajoy K. Man Simrita Cheem Banwari La 《环境科学学报(英文版)》2011,23(8):1394-1402
We compared the efficacy of a natural biocide with four chemical tetrakishydroxymethyl phosphonium sulfonate, benzyl trimethyl
ammonium chloride, and formaldehyde, glutaraldehyde, to control microbial induced corrosion in oil pipelines. The efficacy of biocides
were monitored against Desulfovibrio vulgaris and Desulfovibrio gigas in experimental pipes by measuring cell counts, H2S production,
Fe(II) production, production of extracellular polymeric substances and structure of biofilm. The treatment with cow urine had minimum
planktonic cell counts of 3 102 CFU/mL as well as biofilm cell counts of 9 101 CFU/mL as compared with tetrakishydroxyl methyl
phosphonium sulfonate, benzyl trimethyl ammonium chloride, formaldehyde and glutaraldehyde. Sulfide production was the lowest
with cow urine (0.08 mmol/L), followed by tetrakishydroxymethyl phosphonium sulfonate 0.72 mmol/L. On day 90 of treatment,
Fe(II) production was also found to be the lowest with cow urine. The scanning electron microscopic studies indicated that the biofilm
bacteria were killed by cow urine. These results demonstrate the cow urine mediated control of microbially induced corrosion, and this
is indicative of its potential as a viable substitute of toxic biocides. To the best of our knowledge, this seems to be the first report which
screens possible biocidal activity by cow urine as compared to the most common biocides which oil industry is currently using. 相似文献
968.
Company J 《Die Naturwissenschaften》2011,98(1):67-78
The titanosaur Lirainosaurus astibiae is the only sauropod species known from the Late Cretaceous of the Iberian Peninsula. Lirainosaurus did not reach a gigantic body size and is one of the smallest sauropods discovered to date. Histological analysis of Lirainosaurus bones, focused on diaphyseal transverse sections of appendicular elements, reveals that Lirainosaurus did not exhibit the osseous microstructure typical for large sauropods, but is comparable with that of the coeval titanosaurs
Alamosaurus sanjuanensis, Ampelosaurus atacis, and Magyarosaurus dacus, and also shares histological traits with other small to medium-sized sauropodomorph dinosaurs. Lirainosaurus limb bones exhibit a laminar fibrolamellar bone microstructure interrupted by growth marks, fully obliterated in adulthood
by intense secondary remodeling processes which tend to replace completely the primary cortex. Lirainosaurus attained smaller sizes than typical sauropods reducing the rate of primary periosteal osteogenesis and developing an extensive
secondary remodeling well before the adult size was reached. Histological organization of Lirainosaurus long bones is more mature than observed in basal neosauropods at similar ontogenetic stage, documenting a case of peramorphosis
by pre-displacement. This heterochronic growth would be a reversal of the accelerated pattern of bone deposition typical for
the sauropod lineage. 相似文献
969.
A postanal tail is a major synapomorphy of the phylum Chordata, which is composed of three subphyla: Vertebrata, Cephalochordata,
and Tunicata (Urochordata). Among tunicates, appendicularians are the only group that retains the tail in the adult, and the
adult tail functions in locomotion and feeding in combination with a cellulose-based house structure. Given the phylogenetic
position of tunicates, the appendicularian adult tail may possess ancestral features of the chordate tail. We assess the ultrastructural
development of the tail epidermis of the appendicularian Oikopleura dioica. The epidermis of the larval tail is enclosed by the larval envelope, which is a thin sheet similar to the outer tunic layer
of ascidian larvae. The epidermis of the adult tail seems to bear no tunic-like cellulosic integuments, and the tail fin is
a simple folding of the epidermis. Every epidermal cell, except for the triangular cells at the edge of the tail fin, has
a conspicuous matrix layer of fibrous content in the apical cytoplasm without enclosing membranes. The epidermis of the larval
tail does not have a fibrous matrix layer, suggesting the production of the layer during larval development and metamorphosis.
Zonulae adhaerentes firmly bind the epidermal cells of the adult tail to one another, and the dense microfilaments lining
the cell borders constitute a mechanical support for the cell membranes. The intracellular matrix, cell junctions, and cytoskeletons
probably make the tail epidermis a tough, flexible shell supporting the active beating of the oikopleuran adult tail. 相似文献
970.
This study explored the effects of H2O2 on Cyanobacteria and non-target microbes using fluorometry, microscopy, flow cytometry, and high throughput DNA sequencing of the 16S rRNA gene during a series of mesocosm and whole-ecosystem experiments in a eutrophic pond in NY, USA. The addition of H2O2 (8 mg/L) significantly reduced Cyanobacteria concentrations during a majority of experiments (66%; 6 of 9) and significantly increased eukaryotic green and unicellular brown algae in 78% and 45% of experiments, respectively. While heterotrophic bacteria declined significantly following H2O2 addition in all experiments, bacteria indicative of potential fecal contamination (Escherichia coli, Enterococcus, fecal coliform bacteria) consistently and significantly increased in response to H2O2, evidencing a form of ‘pollution swapping’. H2O2 more effectively reduced Cyanobacteria in enclosed mesocosms compared to whole-ecosystem applications. Ten whole-pond H2O2 applications over a two-year period temporarily reduced cyanobacterial levels but never reduced concentrations below bloom thresholds and populations always rebounded in two weeks or less. The bacterial phyla of Cyanobacteria, Actinobacteria, and Planctomycetes were the most negatively impacted by H2O2. Microcystis was always reduced by H2O2, as was the toxin microcystin, but Microcystis remained dominant even after repeated H2O2 treatments. Although H2O2 favored the growth of eukaryotic algae over potentially harmful Cyanobacteria, the inability of H2O2 to end cyanobacterial blooms in this eutrophic waterbody suggests it is a non-ideal mitigation approach in high biomass ecosystems and should be used judiciously due to potential negative impacts on non-target organisms and promotion of bacteria indicative of fecal contamination. 相似文献