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381.
Stephanie B. Harris Ulrike W. Tschirner Adam Gillespie Madeleine J. Seeger 《Journal of Polymers and the Environment》2018,26(8):3262-3271
Compostable terpolymers of l-lactide (LLA), delta-valerolactone (DVL), and switchgrass organosolv lignin (OSL) were synthesized via ring-opening polymerization to improve on polylactide homopolymer properties for commercial applications. OSL has properties that improve some of the deficiencies of polylactide, including polylactide’s limitations for use in food, beverage and medical applications due to its high water permeability and low ultraviolet light (UV) blocking capabilities. DVL was incorporated into these polymers to add flexibility. The addition of DVL to the polymer had a positive effect on the tensile strain properties of the resultant terpolymer, resulting in a more flexible polymer with a reduced Young’s modulus. Water vapor transmission rate calculations confirmed that water vapor was transported more slowly through terpolymer films than through the PLLA homopolymer under varying hygrostatic conditions. While the addition of DVL increased UV permeability, the addition of even a small amount of lignin can effectively counteract this effect. 相似文献
382.
Ji-Eun Jung Simona Liguori Adam D. Jew Gordon E. Brown Jr. 《Journal of the Air & Waste Management Association (1995)》2018,68(1):39-53
One of the biggest environmental concerns caused by coal-fired power plants is the emission of mercury (Hg), which is toxic metal. To control the emission of Hg from coal-derived flue gas, it is important to understand the behavior and speciation of Hg as well as the interaction between Hg and solid materials in the flue gas stream. In this study, atomic-scale theoretical investigations using density functional theory (DFT) were carried out in conjunction with laboratory-scale experimental studies to investigate the adsorption behavior of Hg on hematite (α-Fe2O3). According to the DFT simulation, the adsorption energy calculation proposes that Hg physisorbs to the α-Fe2O3(0001) surface with an adsorption energy of ?0.278 eV, and the subsequent Bader charge analysis confirms that Hg is slightly oxidized. In addition, Cl introduced to the Hg-adsorbed surface strengthens the Hg stability on the α-Fe2O3(0001) surface, as evidenced by a shortened Hg-surface equilibrium distance. The projected density of states (PDOS) analysis also suggests that Cl enhances the chemical bonding between the surface and the adsorbate, thereby increasing the adsorption strength. In summary, α-Fe2O3 has the ability to adsorb and oxidize Hg, and this reactivity is enhanced in the presence of Cl. For the laboratory-scale experiments, three types of α-Fe2O3 nanoparticles were prepared using the precursors Fe(NO3)3, Fe(ClO4)3, and FeCl3, respectively. The particle shapes varied from diamond to irregular stepped and subrounded, and particle size ranged from 20 to 500 nm depending on the precursor used. The nanoparticles had the highest surface area (84.5 m2/g) due to their highly stepped surface morphology. Packed-bed reactor Hg exposure experiments resulted in this nanoparticles adsorbing more than 300 μg Hg/g. The Hg LIII-edge extended X-ray absorption fine structure spectroscopy also indicated that HgCl2 physisorbed onto the α-Fe2O3 nanoparticles.Implications: Atomic-scale theoretical simulations proposes that Hg physisorbs to the α-Fe2O3(0001) surface with an adsorption energy of ?0.278 eV, and the subsequent Bader charge analysis confirms that Hg is slightly oxidized. In addition, Cl introduced to the Hg-adsorbed surface strengthens the Hg stability on the α-Fe2O3(0001) surface, as evidenced by a shortened Hg-surface equilibrium distance. The PDOS analysis also suggests that Cl enhances the chemical bonding between the surface and the adsorbate, thereby increasing the adsorption strength. Following laboratory-scale experiment of Hg sorption also shows that HgCl2 physisorbs onto α-Fe2O3 nanoparticles which have highly stepped structure. 相似文献
383.
384.
A. Armstrong J. Holden P. Kay M. Foulger S. Gledhill A.T. McDonald A. Walker 《Journal of environmental management》2009,90(11):3512-3519
In recent years there has been a dramatic increase in artificial drain-blocking in world peatlands. The UK blanket peatlands have been severely drained over the past few decades but now drains are being blocked in an attempt to improve peatland environments. The drain-blocking has been a disparate process with limited knowledge transfer between organisations and within organisations operating in different geographic areas. Consequently, there has been no compilation of techniques used and their effectiveness. During this study thirty-two drain-blocked sites were surveyed and all the key stakeholders interviewed. Drain-blocking using peat turf was preferred by practitioners and was also the most cost-effective method. Peat turves were successful except on steep slopes, in areas of severe erosion, in very wet or very dry locations, or if the mineral substrate was exposed. A drain-blocking best practice guide is offered by this paper, providing information on the most suitable methods for blocking peatland drains under different circumstances. Additional considerations are provided for practitioners to ensure peatland drain-blocking is as successful as possible. 相似文献
385.
Management of public lands occurs today with high levels of scrutiny and controversy. To succeed, managers seek the support,
involvement, and endorsement of the public. This study examines trust as an indicator of managerial success and attempts to
identify and measure the components that most influence it. A review of trust literature yielded 14 attributes that were hypothesized
to contribute to trust, grouped into the three dimensions of Shared Norms and Values, Willingness to Endorse, and Perceived
Efficacy. Operationalizing these attributes and dimensions, a telephone survey was administered to a sample of Montana, USA,
residents living adjacent to the Bitterroot National Forest (n = 1,152). Each of the attributes was measured in the context of federal lands fire and fuel management. Structural equation
modeling showed that all 14 attributes were found to be influential contributors to levels of trust. Results suggest that
if managers are to maintain or increase levels of public trust, they need to consider each of trust’s attributes as they make
social, ecological, and economic resource decisions. 相似文献
386.
With record-breaking tourist visits in Kenya in 2005–2006, communities near the country’s renowned protected areas must undertake
or revisit planning efforts to conserve and enhance the region’s natural, social, and economic resources. This article examines
the differences between two stakeholder groups in the Samburu region of central Kenya: (1) protected area leadership and staff;
and (2) members of the communities adjacent to the protected areas. Based on the results and analysis of 30 in-depth interviews,
the authors identify differences between protected area staff and their community members regarding perceptions about communication
between the two groups, and the economic benefits of tourism. The different stakeholders agreed, however, about challenges
related to equitable distribution of tourism-based employment and revenue. The results indicate a need to reach consensus
about what constitutes sufficient communication between national reserves and their community, and to what extent tourism-related
revenue and employment should be distributed within the region. A discussion of the potential role of indicators and standards
to make such decisions is presented. 相似文献
387.
388.
Jose M. Adam Author Vitae Francisco J. Pallarés Author Vitae Author Vitae 《Journal of Safety Research》2009,40(4):293-299
Problem
One of the phases with the highest risk of falls from a height in the construction of a building is during the floor slab formwork stage. This paper analyzes this particular risk, as well as the most frequently used fall-protection systems.Method
A survey was carried out to define the current situation in Spain with regard to falls from a height during floor slab formwork and the fall-protection systems used to prevent such a risk.Results
The results of the survey clarified the current situation in Spain with regard to this risk, and made it clear that there is considerable risk of falling from a height during the floor slab formwork stage.Discussion
All the safety systems analyzed presented a series of weak points that should be studied in detail before they can be used on building sites.Impact on industry
The risk of falling associated with floor slab formwork and the most frequently used protection systems are analyzed. As no research had been carried out to date on this type of risk, we consider the research presented in this article to be a pioneer in the field. 相似文献389.
Adam S. Markowski M. Sam Mannan 《Journal of Loss Prevention in the Process Industries》2009,22(6):921-927
This paper explores the application of the fuzzy logic for risk assessment of major hazards connected with transportation of flammable substances in long pipelines. As a basis for risk assessment, the framework of the fuzzy Layer of Protection Analysis (fLOPA) was used. fLOPA presents a new approach to risk assessment based on two assumptions: 1. different effects of the layer of protection functions on particular elements of the risks (frequency and severity of consequence), and 2. the application of fuzzy logic system (FLS) composed of three elements: fuzzification, inference process and defuzzification. A further calculation follows LOPA methodology with the use of fuzzy logic system where fuzzy risk matrix is used for risk assessment. A typical case study comprising section of a long pipeline failure is performed and a comparison between the classical LOPA approach and fuzzy approach is made. 相似文献
390.
A suite of tests was conducted to evaluate and identify the cause or causes of toxicity in Passaic River sediments. Sediment toxicity was measured with three types of bioassays: a whole sediment bioassay with the marine amphipod, Ampelisca abdita, and interstitial water bioassays with A. abdita and the bioluminescent bacterium Vibrio fisheri (Microtox((R))). In addition, a Phase I Toxicity Identification Evaluation (TIE) was conducted to elucidate the cause of observed toxicity. Analytical concentrations of selected residues in whole sediment and interstitial water from the five sampling stations were considered in conjunction with the conclusions drawn from the toxicity tests and Phase I TIE results. Finally, a toxic units approach was used to evaluate the predicted toxicity of measured interstitial water residue concentrations. There was a lack of toxic response in the short-term interstitial water bioassays, indicating that oxidants, soluble forms of metals, and dissolved phase neutral organics were not likely toxicants. However, there was significant toxicity indicated by the whole sediment A. abidita bioassays. After 10 days, there was complete or near complete mortality in amphipods exposed to all of the sediment samples tested. Removal of interstitial water toxicity by filtration was common to all four stations that exhibited measurable initial toxicity. The observed toxicity characteristics are consistent with particle associated neutral organics. This conclusion is supported by toxicity removal via filtration, lack of toxicity in the Microtox((R)) assays, and the fact that whole sediments were more toxic than was interstitial water. 相似文献