Radiological Program of the Los Angeles County Air Pollution Control District

Abstract

One technology Geld tested under the SITE demonstration program was stabilization-solidification. The HAZCON process was one of those tested. It treats hazardous wastes, consisting of both inorganic and organic contaminants, by mixing it with portland cement, water and a proprietary additive called Chloranan in a modified cement mixer to produce a concrete mass. In evaluating the technology during the demonstration, two major criteria were investigated by using existing laboratory tests. These criteria were mobility of the contaminants before and after treatment and the long-term effect on mobility, and durability of the solidified masses. The former criteria was evaluated using various leaching tests, primarily the Toxicity Characteristic Leaching Procedure (TCLP) and permeability. The durability criteria was determined from weathering tests, wet-dry and freezethaw, unconfined compressive strength, microstructural analyses and sampling the prepared blocks from the demonstration twice at 9-month intervals. This paper describes the results of the field sampling performed 9 and 18 months after the initial field demonstration and relates it to the results obtained during the demonstration.

According to the data, little or no change in the chemical and physical properties of the blocks occurred. The technology is capable of immobilizing heavy metals. The organics were not immobilized and the treated material appears quite durable.     

An Upper Limit Analysis of Carbon Monoxide Monitoring in the United States

In performing carbon monoxide (CO) studies, the question is invariably raised as to whether available monitoring data are truly representative of the highest ambient 8-hr average CO levels experienced in major cities. The most practical means for such a determinate is to inventory the critical characteristics of monitor siting. The authors catalogued such data for the worst station in eight of the 12 counties measuring the highest number of CO violations in the nation.     

Limitations of reverse polyethylene samplers (RePES) for evaluating toxicity of field contaminated sediments

Passive samplers are used to measure dissolved nonionic organic contaminants (NOCs) in environmental media. More recently, reverse polyethylene samplers (RePES) have been used with spiked sediments to recreate interstitial water exposure concentrations and observed toxicity. In the present study, RePES were used with field contaminated sediments. The RePES was not capable of recreating the pattern of toxicity with the amphipod and mysid observed with intact field sediments. Decreased survival in the RePES exposures as compared to the whole sediment exposures was most likely caused by an overexposure to NOCs due to a lack of surrogate black carbon in the RePES system. As an alternative, aqueous phase studies were performed in which polyethylene was allowed to equilibrate with slurries of intact sediments for 3 weeks. Three weeks was found to be an insufficient amount of time for the polyethylene to equilibrate with the sediment. An additional study demonstrated 3 months was sufficient for lower contaminant concentrations, but might not be an adequate amount of time for more highly contaminated sediments. The aqueous phase transfer approach may be useful if equilibration is sufficiently long, although this length of time may be impractical for use in certain applications, such as toxicity identification evaluations (TIEs).     

Integration of Wireless Sensor Networks into Cyberinfrastructure for Monitoring Hawaiian “Mountain-to-Sea” Environments

Monitoring the complex environmental relationships and feedbacks of ecosystems on catchment (or mountain)-to-sea scales is essential for social systems to effectively deal with the escalating impacts of expanding human populations globally on watersheds. However, synthesis of emerging technologies into a robust observing platform for the monitoring of coupled human-natural environments on extended spatial scales has been slow to develop. For this purpose, the authors produced a new cyberinfrastructure for environmental monitoring which successfully merged the use of wireless sensor technologies, grid computing with three-dimensional (3D) geospatial data visualization/exploration, and a secured internet portal user interface, into a working prototype for monitoring mountain-to-sea environments in the high Hawaiian Islands. A use-case example is described in which native Hawaiian residents of Waipa Valley (Kauai) utilized the technology to monitor the effects of regional weather variation on surface water quality/quantity response, to better understand their local hydrologic cycle, monitor agricultural water use, and mitigate the effects of lowland flooding.     

The dissipation and transport of veterinary antibiotics in a sandy loam soil

The environmental fate of the antibiotics sulfachloropyridazine and oxytetracycline was investigated in a sandy loam soil. Liquid pig manure was fortified with the compounds and then applied to soil plots to investigate leaching, dissipation and surface run-off under field conditions. Additionally, as the macrolide antibiotic tylosin had been administered to the pigs from which the slurry had been sourced, this was also analysed for in the samples collected. Sulfachloropyridazine dissipated rapidly with DT(50) and DT(90) values of 3.5 and 18.9 days but oxytetracycline was more persistent with DT(50) and DT(90) values of 21.7 and 98.3 days. Both sulfachloropyridazine and oxytetracyline were detected in surface run-off samples at maximum concentrations of 25.9 and 0.9microg/l respectively but only sulfachloropyridazine was detected in soil water samples at a maximum concentration of 0.78microg/l at 40cm depth 20 days after treatment. Tylosin was not detected in any soil or water samples. The results indicated that tylosin, when applied in slurry, posed very little risk of accumulating in soil or contaminating ground or surface water. However, tylosin may pose a risk if used to treat animals on pasture and risks arising from transformation products of tylosin, formed during slurry storage, cannot be ruled out. Oxytetracycline posed a very low risk of ground or surface water contamination but had the potential to persist in soils and sulfachloropyridazine posed a moderate risk of contaminating ground or surface water but had low potential to accumulate in soils. These findings were consistent with the sorption and persistence characteristics of the compounds and support a number of broad-scale monitoring studies that have measured these antibiotic classes in the environment.     

Catalytic destruction of 1,2-dichlorobenzene on V2O5-WO3/Al2O3-TiO2 catalyst

Studies on the catalytic destruction of 1,2-dichlorobenzene were carried out on a specially constructed semi-technical equipment whose most important element was a catalytic reactor with a monolithic catalyst in the form of 150 x 150 x 100 mm cubes. A catalyst made from cordierite with an active layer composed of Al2O3 - 64 wt%, TiO2 - 26 wt%, V2O5 - 6.6 wt% and WO3 - 3.4 wt% was used. The reactor made it possible to carry out the process in the temperature range 150-350 degrees C, at variable catalyst loading and different velocities of gas flow through the reactor. The content of 1,2-dichlorobenzene in the air was analysed by a chromatographic method. A significant effect of catalyst loading and temperature on 1,2-dichlorobenzene destruction efficiency was observed and no effect of the linear flow velocity through the catalyst on o-dichlorobenzene destruction efficiency was reported. The applied vanadium-tungsten catalyst on a monolithic carrier made from TiO2/gamma-Al2O3 revealed very good activity that resulted in an over 80% efficiency of 1,2-dichlorobenzene destruction at the temperature around 250 degrees C at a very high catalyst loading reaching ca. 8200 h(-1). Additionally, in this study the kinetics of 1,2-dichlorobenzene decomposition was determined, specifying the order of reaction and dependence of the decomposition rate constant on temperature, using a simple power-rate law model.     

Receptor modeling of ambient particulate matter data using positive matrix factorization: review of existing methods

Methods for apportioning sources of ambient particulate matter (PM) using the positive matrix factorization (PMF) algorithm are reviewed. Numerous procedural decisions must be made and algorithmic parameters selected when analyzing PM data with PMF. However, few publications document enough of these details for readers to evaluate, reproduce, or compare results between different studies. For example, few studies document why some species were used and others not used in the modeling, how the number of factors was selected, or how much uncertainty exists in the solutions. More thorough documentation will aid the development of standard protocols for analyzing PM data with PMF and will reveal more clearly where research is needed to help future analysts select from the various possible procedures and parameters available in PMF. For example, research likely is needed to determine optimal approaches for handling data below detection limits, ways to apportion PM mass among sources identified by PMF, and ways to estimate uncertainties in the solution. The review closes with recommendations for documenting the methodological details of future PMF analyses.     

Use of Stable Nitrogen Isotopes and Permeable Membrane Devices to Study what Factors Influence Freshwater Mollusk Survival in the Conasauaga River

Recent biological inventory data shows severe declines in freshwater mussel abundance and biodiversity in the Conasauga River Basin in Northwest Georgia, USA. Based on assessments of habitat conditions, mussel populations should be sustainable. We conducted a study of sediment and water quality to evaluate the impact of anthropogenic contamination on mussel populations. Permeable membrane devices (PMD), polar organic chemical integrative samplers (POCIS™), conventional water and sediment quality analyses, and stable nitrogen isotope ratio analyses (δ¹⁵N) of snails and sediments were used to assess sediment and water quality at target sites throughout the basin. Ambient concentrations of organic contaminants in water were well below any aquatic life criteria; concentrations of some nutrients were detected above aquatic life criteria levels. Most mussel species in the river are endangered or threatened; therefore, snails were collected for δ¹⁵N analyses. Mean δ¹⁵N values for snails collected at forested upper watershed sites (national forest areas) were significantly lower than δ¹⁵N values from snails in agricultural areas. δ¹⁵N values for raw cow manure and manure-treated soil were similar to δ¹⁵N values for snails collected in agricultural areas. Dissolved nitrate from water samples had elevated δ¹⁵N values similar to the upper range of δ¹⁵N values for snails in agricultural areas. Data, particularly stable nitrogen isotope data, indicates that a land use change from national forest land to agriculture alters nitrogen sources to the basin and snails. Implications of nutrient release on freshwater molluscan reproduction, growth, and survival are discussed.     

Guiding principles for rewilding

There has been much recent interest in the concept of rewilding as a tool for nature conservation, but also confusion over the idea, which has limited its utility. We developed a unifying definition and 10 guiding principles for rewilding through a survey of 59 rewilding experts, a summary of key organizations’ rewilding visions, and workshops involving over 100 participants from around the world. The guiding principles convey that rewilding exits on a continuum of scale, connectivity, and level of human influence and aims to restore ecosystem structure and functions to achieve a self-sustaining autonomous nature. These principles clarify the concept of rewilding and improve its effectiveness as a tool to achieve global conservation targets, including those of the UN Decade on Ecosystem Restoration and post-2020 Global Biodiversity Framework. Finally, we suggest differences in rewilding perspectives lie largely in the extent to which it is seen as achievable and in specific interventions. An understanding of the context of rewilding projects is the key to success, and careful site-specific interpretations will help achieve the aims of rewilding.