Occupational exposure in the fluorescent lamp recycling sector in France

The fluorescent lamp recycling sector is growing considerably in Europe due to increasingly strict regulations aimed at inciting the consumption of low energy light bulbs and their end-of-life management. Chemical risks were assessed in fluorescent lamp recycling facilities by field measurement surveys in France, highlighting that occupational exposure and pollutant levels in the working environment were correlated with the main recycling steps and processes.The mean levels of worker exposure are 4.4 mg/m³, 15.4 μg/m³, 14.0 μg/m³, 247.6 μg/m³, respectively, for total inhalable dust, mercury, lead and yttrium. The mean levels of airborne pollutants are 3.1 mg/m³, 9.0 μg/m³, 9.0 μg/m³, 219.2 μg/m³, respectively, for total inhalable dust, mercury, lead and yttrium. The ranges are very wide. Surface samples from employees’ skin and granulometric analysis were also carried out. The overview shows that all the stages and processes involved in lamp recycling are concerned by the risk of hazardous substances penetrating into the bodies of employees, although exposure of the latter varies depending on the processes and tasks they perform. The conclusion of this study strongly recommends the development of a new generation of processes in parallel with more information sharing and regulatory measures.     

Preliminary toxicological assessment of phthalate esters from drinking water consumed in Portugal

This paper reports, for the first time, the concentrations of selected phthalates in drinking water consumed in Portugal. The use of bottled water in Portugal has increased in recent years. The main material for bottles is polyethylene terephthalate (PET). Its plasticizer components can contaminate water by leaching, and several scientific studies have evidenced potential health risks of phthalates to humans of all ages. With water being one of the most essential elements to human health and because it is consumed by ingestion, the evaluation of drinking water quality, with respect to phthalate contents, is important. This study tested seven commercial brands of bottled water consumed in Portugal, six PET and one glass (the most consumed) bottled water. Furthermore, tap water from Lisbon and three small neighbor cities was analyzed. Phthalates (di-n-butyl phthalate ester (DnBP), bis(2-ethylhexyl) phthalate ester (DEHP), and di-i-butyl phthalate ester (DIBP)) in water samples were quantified (PET and glass) by means of direct immersion solid-phase microextraction and ionic liquid gas chromatography associated with flame ionization detection or mass spectrometry due to their high boiling points and water solubility. The method utilized in this study showed a linear range for target phthalates between 0.02 and 6.5 μg L^?1, good precision and low limits of detection that were between 0.01 and 0.06 μg L^?1, and quantitation between 0.04 and 0.19 μg L^?1. Only three phthalates were detected in Portuguese drinking waters: dibutyl (DnBP), diisobutyl (DIBP), and di(ethylhexyl) phthalate (DEHP). Concentrations ranged between 0.06 and 6.5 μg L^?1 for DnBP, between 0.02 and 0.16 μg L^?1 for DEHP, and between 0.1 and 1.89 μg L^?1 for DIBP. The concentration of DEHP was found to be up to five times higher in PET than in glass bottled water. Surprisingly, all the three phthalates were detected in glass bottled water with the amount of DnBP being higher (6.5 μg L^?1) than in PET bottled water. These concentrations do not represent direct risk to human health. Regarding potable tap water, only DIBP and DEHP were detected. Two of the cities showed concentration of all three phthalates in their water below the limits of detection of the method. All the samples showed phthalate concentrations below 6 μg L^?1, the maximum admissible concentration in water established by the US Environmental Protection Agency. The concentrations measured in Portuguese bottled waters do not represent any risk for adult's health.     

‘Ecomálaga’: an ecosystem analysis of the Mediterranean coast around Málaga, Spain

In October 1992, the Oceanographic Centre of Málaga of the Spanish Oceanographical Institute (IEO) started a monitoring project,Ecomálaga, which collects physical, chemical, biological and sedimentological data from the Alborán Sea shelf. The project is coordinated with similar projects in the Atlantic and Mediterranean Centres of IEO. The ultimate objective is to, understand the long-term changes of the essential marine-environmental parameters. So far, nine quarterly surveys have been carried out—from October 1992 to December 1994. The following variables were registered:abiotic: location weather, water temperature, salinity, pH, dissolved oxygen, chlorophyll a, nitrate, nitrite, phosphate, silicate,biotic: zooplankton biomass and species composition, and ichthyoplankton. The granulometric composition and organic matter content of sediments are also included. Data are stored in a computerized data base named Ecomálaga Data Base, with contributions from geology, physics, plankton biology and marine chemistry. The data base not only contains separate files for each research topic, but also allows for interchange between these files, resulting in a synoptic data output. It offers the users an output in the form of synthetic records of each station sampled. The analysis of the data indicates seasonal influences and ainshore-offshore gradient, as well as an Atlantic influence on the stations located in the transect closest to the Strait of Gibraltar.     

Implementing environmental with other standardized management systems: Scope,sequence, time and integration

The aim of this article is to analyze how the implementation of the environmental management system (EMS) in accordance with the ISO 14001: 2004 standard has been carried out in organizations having more than one standardized Management System (MSs). In particular, four implementation aspects will be discussed, namely the different management system standards (MSSs) used for registration, for example ISO 14001, ISO 9001, OHSAS 18001, ISO 27001 and SA 8000, the order in which they were implemented, the time required for each implementation, as well as the scope of integration of these MSSs into a single Integrated Management System (IMS).In order to do so, some of the results of a survey carried out in 176 organizations registered to, at a minimum, both ISO 14001: 2004 and ISO 9001: 2000 standards for environmental and quality management, respectively, are presented. As one of the few existing empirical studies regarding the integration of multiple MSs, this research reveals the importance of the different possibilities which organizations can opt for when considering EMS implementation. For example, while most respondents implemented ISO 9001 before ISO 14001, others did so simultaneously or even applied ISO 14001 first. Furthermore, although a large majority of organizations integrated their EMS with additional standardized MSs, a small percentage did not. Apart from illustrating the survey outcomes, the article contains a detailed case analysis of four specific organizations with high environmental awareness that have implemented quality and other standardized MSs.     

Organochlorine levels in viperine snake Natrix maura carcasses from the ebro delta (NE Spain): Sexual and size-related differences

Organochlorine compounds (PCBs, DDTs and HCB) in carcasses from a population of the Viperine Snake (Natrix maura) living in the Ebro Delta were analyzed. This is a wetland area on the Mediterranean coast where the natural ecosystem has been partially substituted by rice fields. High levels of pollutants (mainly DDTs and PCBs) have been detected in several species living in this area, due to the production of these compounds by a former industrial activity upstream as well as agricultural activity in the Delta. Organochlorines were analyzed in adult males and females, and in immature snakes. DDTs (mainly p,p′-DDE) were the most abundant pollutant present. The DDT/PCB ratio was higher than expected, which is consistent with the position of the Viperine Snake in the trophic web as well as the type of prey consumed. Immature snakes had more organochlorines than adults. However, the broad range of concentrations shown by immature snakes, suggested that part of the organochlorine load is transferred from gravid females to their eggs. In adults, organochlorine concentrations increased with carcass weight in both males and females. This increase was higher in males since females lost contaminants through fat investment during vitellogenesis. Seasonally, PCBs and DDTs levels increased in spring when snakes showed higher feeding activity, whereas higher levels of HCB were present at the end of summer, when the river input increased. Furthermore, HCB does not seem to biomagnify well across the trophic chain. Organochlorine concentrations in Viperine Snake carcasses were high since: 1) the dry tissue had less than 5% of fat, and 2) snakes were caught many years after the DDT ban, supporting the fact that cleaning of the ecosystem does not occur easily. These results indicate that snakes are adequate as indicators of the contamination in natural ecosystems but sex and body size of the samples should be taken into account for interpretation of results.     

Allocation of GHG emissions in combined heat and power systems: a new proposal for considering inefficiencies of the system

The paper industry is responsible for a considerable amount of greenhouse gas (GHG) emissions mainly due to its intensive energy requirements. The production of heat and power streams in a cogeneration system, i.e., a combined heat and power (CHP) plant, releases considerable amounts of GHG emissions into the atmosphere. Such emissions are already subjected to legislation globally. The amount of GHG emissions is usually calculated from the product of the total amount of energy activity multiplied by an emission factor. However, each energy output stream should get a share of emissions responsibility. This fact could assist in assigning weights to the emissions generated for power and thermal purposes in a combined heat and power plant. However, developing a suitable method of allocating emissions in a cogeneration system is still a concern and a subject research for scientists, companies and policy makers. This paper exposes and evaluates different published allocation methods and applies them to a real case of a combined heat and power plant integrated in a paper mill and proposes a new allocation method.