Investigation on the effect of sintering temperature on kaolin hollow fibre membrane for dye filtration

Despite its extraordinary price, ceramic membrane can still be able to surpass polymeric membrane in the applications that require high temperature and pressure conditions, as well as harsh chemical environment. In order to alleviate the high cost of ceramic material that still becomes one of the major factors that contributes to the high production cost of ceramic membrane, various attempts have been made to use low cost ceramic materials as alternatives to well-known expensive ceramic materials such as alumina, silica, and zirconia in the fabrication of ceramic membrane. Thus, local Malaysian kaolin has been chosen as the ceramic material in this study for the preparation of kaolin hollow fibre membrane since it is inexpensive and naturally abundant in Malaysia. Due to the fact that the sintering process plays a prominent role in obtaining the desired morphology, properties, and performances of prepared ceramic membrane, the aim of this work was to study the effect of different sintering temperatures applied (ranging from 1200 to 1500 °C) in the preparation of kaolin hollow fibre membrane via dry/wet phase inversion-based spinning technique and sintering process. The morphology and properties of membrane were then characterised by SEM, AFM, FTIR, XRD, and three-point bending test, while the performances of membrane were investigated by conducting water permeation and Reactive Black 5 (RB5) dye rejection tests. From the experimental results obtained, the sintering temperature of 1400 °C could be selected as the optimum sintering temperature in preparing the kaolin hollow fibre membrane with the dense sponge-like structure of separation layer that resulted in the good mechanical strength of 70 MPa with the appreciable water permeation of 75 L/h m² bar and RB5 rejection of 68%.     

Effects of fly ash addition on physical properties of porous clay-fly ash composites via polymeric replica technique

The porous composites of clay and fly ash have the potential to be used in many fields, such as catalyst support and gas adsorbents. In this study, various ratios of fly ash (1–2) with different percentage of suspension (50–70 wt%) were applied to produce porous clay-fly ash composites via polymeric replica technique. Fabrication process starts by mixing clay and fly ash in distilled water to form slurry. The process is followed by fully immersing polymer sponge in slurry. The excess slurry is then removed through squeezing. Finally, the sponge coated with slurry is sintered at 500 and 1250 °C for 1 h. It is found that the compressive strength of porous composites improves significantly (0.178–1.28 MPa) when the amount of clay-fly ash suspension mixture (50–70 wt%) increases. The compressive strength of porous composites is mainly attributed to the mullite, quartz and amorphous phase formations. These results are supported by X-ray diffraction analysis. On the other hand, increase in the amount of suspension reduces the apparent density (from 2.44 to 2.32 g/cm³) and porosity (from 97 to 85 %). The reduction in apparent density is believed to be caused by the presence of high fly ash content in porous composites. The melted fly ash cenospheres have closed the internal pores and increased density of samples. Higher suspension level not only reduces porosity, but also increases close pores of the porous composites. The results are justified through the observation from the structures of porous clay-fly ash composites.     

Asymmetric investigation to track the effect of urbanization,energy utilization,fossil fuel energy and CO2 emission on economic efficiency in China: another outlook

Environmental Science and Pollution Research - The accelerated urbanization in China was already coupled with a steadily increasing demand for energy usage. The present study major aim was to...     

Physical infrastructure,energy consumption,economic growth,and environmental pollution in Pakistan: an asymmetry analysis

Environmental Science and Pollution Research - This study explores the symmetric and asymmetric effects of physical infrastructure on energy consumption, economic growth, and air pollution of...     

Monitoring of copper accumulation in water,soil, forage,and cows impacted by heavy automobiles in Sargodha,Pakistan

Environmental Science and Pollution Research - The instant endeavor was undertaken to monitor copper (Cu) contents in water, soil, forage, and cow’s blood impacted by heavy automobiles in...     

The trade-off between economic growth and environmental quality: does economic freedom asymmetric matter for Pakistan?

Environmental Science and Pollution Research - This empirical study investigates the dynamic effects of economic freedom on economic growth and air quality for Pakistan over the period...     

Effect of land use changes on non-carcinogenic health risks due to nitrate exposure to drinking groundwater

Environmental Science and Pollution Research - This study aimed to determine the effect of land-use changes on the non-carcinogenic health risk of nitrate ion exposure of underground drinking water...     

The strain gradient approach to predict necking in tube hydroforming

A stress-based forming limit diagram for necking prediction which is based on the strain gradient theory of plasticity in conjunction with the M–K model has been represented and used in tube hydroforming. In this study, the finite element model for bulge forming of straight tube has been constructed and verified with published experimental data. The adaptive simulation technique is based on the ability to detect the onset and growth of defects (e.g., wrinkling, and bursting) and to promptly readjust the loading paths. Thus, a suitable load path has been obtained by applying Adaptive Simulation Method in ANSYS Parametric Design Language (APDL).     

Impact of green trust and green perceived quality on green purchase intentions: a moderation study

Environment, Development and Sustainability - The current study explores the role of green trust, green perceived risk and green perceived quality in changing green purchase intention....     

Assessment of the impacts of climate change and variability on water resources and use,food security,and economic welfare in Iran

Climate change influences the agricultural sector by reducing available water resources, thereby influencing income, consumer and producer surplus, and crop prices. So, it is necessary to have a comprehensive integrated method to measure the effects of these changes on natural resources and social conditions. The present study aims to use the positive mathematical programming method to discover the trend and conditions of groundwater resources, agricultural water use, food security, and economic welfare of the agricultural sector in Iran. To this end, data for the period 2000–2015 was used under four different scenarios of normal climate change, climate change, climate variability, and concurrent climate change The results showed that the mean agricultural water use will amount to 35,103.6, 26,533.8, 35,216, and 26,510.7 million m³ and the mean decline in the reserves of aquifers will amount to 4422.22, 11,165.6, 4438.25, and 11,267.4 million m³ under the scenarios, respectively. With respect to food security, the net farm revenue will be 314,560, 248,753, 315,427, and 248,574 billion IRR, respectively. The mean crop price per ton will reach 905.3, 1141.8, 904, and 1142.8 million IRR, respectively. The mean consumer surplus will be 172,107.7, 166,450, 172,024, and 166,403 billion IRR and the mean producer surplus will be 419,959.2, 395,380, 419,751, and 395,204 billion IRR, respectively. Based on the results, to reduce the adverse impacts of climate change on different studied aspects, it is necessary to change policymaking in the water and agricultural sectors, especially regarding the shift from traditional agricultural water allocation to its market-based allocation and to change planting pattern.