Determination of heavy metal contents in water,sediments, and fish tissues of Shizothorax plagiostomus in river Panjkora at Lower Dir,Khyber Pakhtunkhwa,Pakistan

The present study was conducted to investigate the contamination of water, sediments, and fish tissues with heavy metals in river Panjkora at Lower Dir, Khyber Pakhtunkhwa, Pakistan. Water, sediments, and fish (Shizothorax plagiostomus) samples were collected from September 2012 to January 2013 at three different sites (upstream site at Sharigut, sewage site at Timergara, and downstream site at Sadoo) of river Panjkora. The concentrations of heavy metals in water were in the order Zn?>?Cu?≈?Pb?>?Ni?≈?Cd with mean values of 0.30, 0.01, 0.01, 0.0 and 0.0 mg/l, respectively, which were below the maximum permissible limits of WHO for drinking water. In sediments, heavy metals were found in the order Cu?>?Zn?>?Ni?>?Pb?>?Cd with mean concentrations of 50.6, 38.7, 9.3, 8, and 0.4 mg/kg, respectively. Ni and Cd were not found in any fish tissues, but Zn, Cu, and Pb were detected with the mean concentration ranges of 0.04–1.19, 0.03–0.12, and 0.01–0.09 μg/g, respectively. The present study demonstrates that disposal of waste effluents causes a slight increase in the concentration of heavy metals in river Panjkora as revealed by variation in metal concentrations from upstream to downstream site. Sewage disposal was also found to change physicochemical characteristics of Panjkora water. At present, water and fish of river Panjkora are safe for human consumption, but the continuous sewage disposal may create problems in the future.     

Morphometry and land cover based multi-criteria analysis for assessing the soil erosion susceptibility of the western Himalayan watershed

Complex mountainous environments such as Himalayas are highly susceptibility to natural hazards particular those that are triggered by the action of water such as floods, soil erosion, mass movements and siltation of the hydro-electric power dams. Among all the natural hazards, soil erosion is the most implicit and the devastating hazard affecting the life and property of the millions of people living in these regions. Hence to review and devise strategies to reduce the adverse impacts of soil erosion is of utmost importance to the planners of watershed management programs in these regions. This paper demonstrates the use of satellite based remote sensing data coupled with the observational field data in a multi-criteria analytical (MCA) framework to estimate the soil erosion susceptibility of the sub-watersheds of the Rembiara basin falling in the western Himalaya, using geographical information system (GIS). In this paper, watershed morphometry and land cover are used as an inputs to the MCA framework to prioritize the sub-watersheds of this basin on the basis of their different susceptibilities to soil erosion. Methodology included the derivation of a set of drainage and land cover parameters that act as the indicators of erosion susceptibility. Further the output from the MCA resulted in the categorization of the sub-watersheds into low, medium, high and very high erosion susceptibility classes. A detailed prioritization map for the susceptible sub-watersheds based on the combined role of land cover and morphometry is finally presented. Besides, maps identifying the susceptible sub-watersheds based on morphometry and land cover only are also presented. The results of this study are part of the watershed management program in the study area and are directed to instigate appropriate measures to alleviate the soil erosion in the study area.     

Determination of organochlorine and organophosphate pesticide residues in fruits,vegetables and sediments

Abstract

A method is described for the determination of organochlorine and organophosphate pesticide residues in fruits, vegetables and sediments. The concentrated solvent extract was sealed in a polymeric membrane tube, dialysed in cyclohexane and the solvent replaced with hexane. The organophosphates were analysed on a specific thermionic detector without further clean‐up. For the organochlorine pesticides the extract was eluted through 3 g of alumina and analysed on GC/ECD. The clean‐up for sediment extract was carried out on a10 g alumina column with 100 mL hexane containing 5% acetone and the eluate was concentrated to 5 mL.

The detection limit for organophosphates on a 40 g sample and a final volume of 10 mL was on the average 0.01 mg/kg. The detection limit for organochlorine pesticides, with the final volume of 25 mL, was 0.005 mg/kg for all pesticides except for p,p'‐DDT and endosulfan sulphate, which was 0.01 mg/kg.

The detection limit for oganochlorine pesticides in sediment, with the final volume of 2 mL, was less than 1 μg/kg and for organophosphate pesticides less than 10 μg/kg when the final volume was made to 0.5 mL. At the detection limits the method produced a very high coefficient of variation for both organochlorine and organophosphate pesticides.     

Erosion Modeling in Hard Rock Terrain Using Morphometry: A Case Study from Tamilnadu,India

Remote sensing and geographical information system (GIS) can help identify erosion‐prone areas in need of soil conservation efforts     

Natural gas engine driven heat pump system – a case study of an office building

ABSTRACT

An eQUEST model was developed to conduct a simulation study of a natural gas engine-driven heat pump (GEHP) for an office building in Woodstock, Ontario, Canada. Prior to the installation of the GEHP, the heating and cooling demands of the office building were provided by rooftop units (RTUs), comprising of natural gas heater and electric air conditioner. Energy consumption for both GEHP and RTUs were monitored for operation in alternating months. These recorded energy consumptions along with weather data were used in the regression analysis. The developed eQUEST models were validated and calibrated with the regression analysis results with respect to the ASHRAE Guideline 14–2014. The eventual models were then applied to investigate the potential annual energy consumption, greenhouse gas (GHG) emission and energy cost savings achieved by using the GEHP in Woodstock, and other cities in Canada, particularly in Ontario.     

The fly ash influenced the heavy metal status of the soil and the seeds of sunflower. A case study

In this study, four cultivars of sunflower (Helianthus annuus) were grown in the sandy loam soil, supplemented with graded (v/v) quantity (0, 20, 40, 60, 80, 100%) of the fly ash, released by the combustion of the coal from the thermal power plant. The presence of fly ash in the soil increased its porosity, water holding capacity, pH, E.C., C.E.C., the content of sulphate, carbonate, bicarbonate, chloride, phosphorus, potassium, calcium and various trace elements. However, in the seeds, except Fe, Pb, Mn and Zn, and other heavy metals remained untraced up to 40% of the fly ash, above that their quantity slightly increased but the values are very much under the permissible limits.     

Reproductive health in Afghanistan: results of a knowledge, attitudes and practices survey among Afghan women in Kabul

A reproductive-health knowledge, attitudes and practices (KAP) survey was carried out among 468 Afghan women of reproductive age. A convenience sample of women was selected from attendees in the outpatient departments of four health facilities in Kabul. Seventy-nine per cent of respondents had attended at least one antenatal consultation during their last pregnancy. Two-thirds (67 per cent) delivered their first child between 13 and 19 years. The Caesarean-section rate was low (1.6 per cent). Two-thirds (67 per cent) of deliveries occurred in the home. The contraceptive prevalence rate was 23 per cent (16 per cent modern and 7 per cent natural methods). Twenty-four per cent had knowledge of any STIs, although most of these women did not know correctly how to prevent them. Most of the women (93 per cent) needed authorization from their husband or a male relative before seeking professional health-care. In multivariate analysis, women's schooling was significantly associated with antenatal-care attendance (AOR 4.78), institutional delivery (AOR 2.29), skilled attendance at birth (AOR 2.07) and use of family planning (AOR 4.59). Reproductive-health indicators were noted to be poor even among these women living in Kabul, a group often considered to be the most privileged. To meet the reproductive-health needs of Afghan women, the socio-cultural aspects of their situation--especially their decision-making abilities -- will need to be addressed. A long-standing commitment from agencies and donors is required, in which the education of women should be placed as a cornerstone of the reconstruction process of Afghanistan.     

Intercomparison of INAA and ICP-MS results for thorium determination in Pakistani diet

A pilot study on ingestion and organ content of trace elements of importance in radiological protection was to be carried out in Pakistan. Baseline analytical data on daily dietary intake of thorium was to be measured using Instrumental Neutron Activation Analysis (INAA) technique. To determine the accuracy and reliability of our technique, some samples were measured in Pakistan using INAA and in Japan using Inductively Coupled Plasma-Mass Spectrometry. For intercomparison of results overall mean Z-scores were calculated. The results showed validity of our technique. Mean value of 232Th concentration in Pakistani diet samples using INAA technique is 0.0062 +/- 0.0028 microg/g and with ICP-MS technique is 0.0069 +/- 0.0032 microg/g.     

Bioremediation of residual fertilizer nitrate: II. Soil redox potential and soluble iron as indicators of soil health during treatment

The prospect of using wastewater containing high loads of soluble organic matter (OM) for removing residual agricultural chemicals (fertilizer, pesticide, or herbicide) in farm soil, although promising, could have adverse effects on soil agricultural quality as a result of development of redoximorphic features in the soil profile. In this study, the effect of organic carbon supplement for bioremediation of residual fertilizer nitrate on soil properties, redox potential (Eh), pH, and metal ion mobilization was studied using sandy soils packed in columns. The study was included in a general project, described elsewhere (Ugwuegbu et al., 2000), undertaken to evaluate use of controlled water table management (WTM) systems to supply organic carbon for creating a reduced environment conducive to denitrification of residual fertilizer nitrate leaching from the farm to subsurface water. The columns were subjected to subirrigation with water containing soluble organic carbon in the form of glucose. The work was carried out in two experimental setups and the long-term effect of a range of glucose concentrations on the Eh, pH, and soluble levels of Fe and Mn was investigated. From the results obtained, it could be concluded that excessive organic carbon supplement to soil can have adverse effects on soil quality and that Eh and soluble Fe are the two most practical parameters for monitoring soil health during treatment of farm chemicals.     

Considerations for the design of organic mulch permeable reactive barriers

Organic mulch consists of insoluble carbon biopolymers that are enzymatically hydrolyzed during decomposition to release aqueous total organic carbon (TOC). The released TOC is utilized by microorganisms as an electron donor to transform electrophilic contaminants via reductive pathways. Over the last decade, organic mulch permeable reactive barriers (PRBs), or biowalls, have received increased interest as a relatively inexpensive slow‐release electron donor technology for addressing contaminated groundwater. To date, biowalls have been installed to enhance the passive bioremediation of groundwater contaminated with a variety of electrophilic compounds, including chlorinated solvents, explosives, and perchlorate. In addition, several mulch biowall projects are currently under way at several U.S. Department of Defense facilities. However, at the present time, the guidelines available for the design of mulch PRBs are limited to a few case studies published in the technical literature. A biowall design, construction, and operation protocol document is expected to be issued by the Air Force Center for Environmental Excellence in 2007. In this publication, three technical considerations that can have a significant impact on the design and performance of mulch PRBs are presented and discussed. These technical considerations are: (1) hydraulic characteristics of the mulch bed; (2) biochemical characteristics of different types of organic amendments used as mulch PRB fill materials; and (3) a transport model that can be used to estimate the required PRB thickness to attain cleanup standards. © 2007 Wiley Periodicals, Inc.