TiO2 nanotubes as solid-phase extraction adsorbent for the determination of polycyclic aromatic hydrocarbons in environmental water samples

An analytical method based on TiO2 nanotubes solid-phase extraction (SPE) combined with gas chromatography (GC) was established for the analysis of seven polycyclic aromatic hydrocarbons (PAHs): acenaphtylene, acenaphthene, anthracene, fluorene, phenanthrene, fluoranthene and pyrene. Factors a ecting the extraction e ciency including the eluent type and its volume, adsorbent amount, sample volume, sample pH and sample flow rate were optimized. The characteristic data of analytical performance were determined to investigate the sensitivity and precision of the method. Under the optimized extraction conditions, the method showed good linearity in the range of 0.01–0.8 g/mL, repeatability of the extraction (RSD were between 6.7% and 13.5%, n = 5) and satisfactory detection limits (0.017–0.059 ng/mL). The developed method was successfully applied to the analysis of surface water (tap, river and dam) samples. The recoveries of PAHs spiked in environmental water samples ranged from 90% to 100%. All the results indicated the potential application of titanate nanotubes as solid-phase extraction adsorbents to pre-treat water samples.     

Restoring the plant productivity of heavy metal-contaminated soil using phosphate sludge, marble waste, and beneficial microorganisms

Assisted natural remediation (ANR) has been highlighted as a promising, less expensive, and environmentally friendly solution to remediate soil contaminated with heavy metals. We tested the effects of three amendments (10% compost, C; 5 or 15% phosphate sludge, PS5 and PS15; and 5 or 15% marble waste, MW5 and MW15) in combination with microorganism inoculation (rhizobacteria consortium alone, mycorrhizae alone, and the two in-combination) on alfalfa in contaminated soil. Plant concentrations of Zn, Cu, and Pb were measured, along with proline and malondialdehyde production. The microbiological and physicochemical properties of the mining soil were evaluated. Application of the amendments allowed germination and promoted growth. Inoculation with the rhizobacteria consortium and/or mycorrhizae stimulated plant growth. PS and MW stimulated the production of proline. Inoculation of alfalfa with the rhizobacteria-mycorrhizae mixture and the application of MW allowed the safe cultivation of the legume, as shown by the low concentrations of metals in plant shoots. Zn and Pb concentrations were below the limits recommended for animal grazing and accumulated essentially in roots. Soil analyses showed the positive effect of the amendments on the soil physicochemical properties. All treatments increased soil pH (around 7), total organic carbon, and assimilable phosphorus content. Notably, an important decrease in soluble heavy metals concentrations was observed. Overall, our findings revealed that the applied treatments reduced the risk of metal-polluted soils limiting plant growth. The ANR has great potential for success in the restoration of polymetallic and acidic mining soils using the interaction between alfalfa, microorganisms, and organo-mineral amendments.     

Neutron activation analysis of ceramic tiles and its component and radon exhalation rate

IntroductionCeramic,consistofearthymaterialslikeclaykaolin ,limestoneandsandglass .Ceramicmaterialsarenonmetalic ,inorganiccompoundsprimaryoxides ,alsocarbides ,nitridesandsilicides .Twotypesofbondingmechanismsoccurinceramicmaterial ,ionicandcovalent.Theo…     

Egyptian blue — Cuprorivaite a window to ancient Egyptian technology

Egyptian Blue, a multicomponent synthetic blue pigment has been recorded in ancient Egypt since the Fourth Dynasty of the Old Kingdom (2600–2480 B.C.). The pigment consisting of cuprorivaite (CaCuSi₄O₁₀) with variable amounts of wollastonite (CaSiO₃), Cu-rich glass and cuprite (Cu₃O) or tenorite (CuO) was prepared by melting the copper-rich ingredient with lime and desert sand. Low melting temperatures (below 742 °C) were achieved by addition of flux-like plant ashes. The high quality of the pigments collected from monuments of the Fifth Dynasty (2480–2320 B.C.) may indicate that the first manufacture was in early dynastic or perhaps predynastic eras. During the reign of Thutmosis III (18th Dynasty, 1490–1436 B.C.) probably bronze filings were first applied as starting material, thus indicating a technological innovation. This new method was employed till the Roman times.     

Integration of biodiversity in urban planning instruments in developing countries: the case of Kumasi Metropolitan Assembly,Ghana

There is a growing concern about integrating biodiversity into urban planning, yet, discussions are concentrated on science-informed planning in general. Few have explored the integration of biodiversity in specific planning instruments, especially in African cities. This paper examines how and what components of biodiversity are integrated into master plans, medium-term plans, building codes, zoning codes and permits in Kumasi City, Ghana. There is limited integration of biodiversity in most planning instruments as they were mostly designed on the basis of health, safety and economy. Allied to lack of funding and public participation, biodiversity in Kumasi is under significant threat from rapid urban development. Creating an opportunity for popular participation and decentralizing the planning system could set the preconditions for local integration and revision of instruments. Simplifying the definition of biodiversity could increase local planners’ appreciation, understanding and their ability to make use of biodiversity data.     

Seasonal food insecurity in Bangladesh: evidences from northern areas

Seasonal food insecurity in Bangladesh is a multidimensional socioeconomic issue emanated from more than just access and availability of food. In general, it has been considered that the northern areas of Bangladesh, treated as monga-prone, is more vulnerable to seasonal food insecurity as compared to any other region of the country. The manifestation of monga is essentially food insecurity and consequent vulnerabilities. The paper investigates the seasonal food insecurity status, coping strategies along with its possible determinants linked to socioeconomic conditions of the affected households in Kurigram, one of the monga-prone districts of northern Bangladesh. A primary survey was conducted to explore the food insecurity status and diverse factors leading to food insecurity in terms of food consumption, livelihood and consequent family experiences in mitigating the severity of food insecurity during the monga (lean) period. The nature of household food insecurity seems to be an outcome of a variety of risk factors, as well as inability to manage those risks due to income and resource constraints. Moreover, a reduction in food intake during the monga period is one of the common scenarios in the study area. Marginal effects and elasticities after probit regression reveal that household’s income, share of per capita medical expenditure, safety net(s) involvement and the area of residence appear to be the leading factors affecting seasonal food insecurity during the monga period to a significant extent. Households with more medical expenditure (68 %), cultivable landholding (9 %) and households residing by the riverside (4 %) have a higher probability of food insecurity than their counterparts. On the contrary, relatively large size family (-16 %), higher income (-4 %) and safety net coverage (-19 %) have reduced the probability of food insecurity during the monga period. Finally, the paper concludes with some policy issues based on on-site observation and econometric analysis to overcome this transitory food insecurity in the monga-prone areas.     

Efficiency and degradation products elucidation of the photodegradation of mefenpyrdiethyl in water interface using TiO2 P-25 and Hombikat UV100

The photodegradation of mefenpyrdiethyl (MFD), an herbicide safener, was investigated in aqueous suspensions by using Degussa P-25 and Hombikat UV100 titanium oxide under simulated sunlight irradiation. The effects of initial concentration of the herbicide, pH, catalysts and hydrogen peroxide doses as well as their combinations were studied and optimized. Accordingly, the kinetic parameters were determined and the effectiveness of the processes was assessed by calculating the rate constants. A pseudo first-order kinetics was observed. Under experimental conditions, the degradation rate constants were strongly influenced using P-25 and no noticeable effect was observed for Hombikat UV100. DFT calculations with B3LYP/6-311+G(2d,p)//B3LYP/6-31+G(d,p) level of theory were performed to check whether significant conformational changes occur when the charge state of the MFD substrate changes and whether these changes could play a role in the dependency of photodegradation rate constant on the studied pH. High resolution mass spectrometry (FT-ICR/MS) was implemented to identify the main degradation products.