Emissions of VOCs at Urban Petrol Retail Distribution Centres in India (Delhi and Mumbai)

Air pollution has assumed gigantic proportion killing almost half a million Asians every year. Urban pollution mainly comprises of emissions from buses, trucks, motorcycle other forms of motorized transport and its supporting activities. As Asia's cities continue to expand the number of vehicles have risen resulting in greater pollution. Fugitive emissions from retail distribution center in urban area constitute a major source. Petrol vapours escape during refueling adding pollutants like benzene, toluene, ethylbenzene and xylene to ambient air. This paper discusses a study on fugitive emissions of Volatile Organic Compounds (VOC) at some refueling station in two metropolitan cities of India, i.e., Mumbai and Delhi. Concentration of VOCs in ambient air at petrol retail distribution center is estimated by using TO-17 method. Concentration of benzene in ambient air in Delhi clearly shows the effect of intervention in use of petroleum and diesel fuel and shift to CNG. Chemical Mass Balance (CMB) model is used to estimate source contributions. At Delhi besides diesel combustion engines, refueling emissions are also major sources. At Mumbai evaporative emissions are found to contribute maximum to Total VOC (TVOC) concentration in ambient air.     

Retention of estrogenic steroid hormones by selected New Zealand soils

We performed batch sorption experiments for 17beta-estradiol (E2) and 17alpha-ethynylestradiol (EE2) on selected soils collected from dairy farming regions of New Zealand. Isotherms were constructed by measuring the liquid phase concentration and extracting the solid phase with dichloromethane, followed by an exchange step, and analysis by HPLC and UV detection. The corresponding metabolite estrone, (E1) formed during equilibration of E2 with soil was taken into account to estimate the total percentage recoveries for the compounds, which ranged from 47-105% (E2 and E1) and 83-102% (EE2). Measured isotherms were linear, although some deviation from linearity was observed in a few soils, which was attributed to the finer textured particles and/or the allophanic nature of the soils having high surface area. There was a marked difference in K(d)(eff) (effective distribution coefficient) values for E2 and EE2 among the soils, consistent with the soils organic carbon content and ranged from 14-170 L kg(-1) (E2), and 12-40 L kg(-1) (EE2) in the soils common for both compounds. The sorption affinity of hormones in the soils followed an order: EE2相似文献   

Spatially distributed modeling of the long-term carbon balance of a boreal landscape

Spatially and temporally distributed information on the sizes of biomass carbon (C) pools (BCPs) and soil C pools (SCPs) is vital for improving our understanding of biosphere-atmosphere C fluxes. Because the sizes of C pools result from the integrated effects of primary production, age-effects, changes in climate, atmospheric CO₂ concentration, N deposition, and disturbances, a modeling scheme that interactively considers these processes is important. We used the InTEC model, driven by various spatio-temporal datasets to simulate the long-term C-balance in a boreal landscape in eastern Canada. Our results suggested that in this boreal landscape, mature coniferous stands had stabilized their productivity and fluctuated as a weak C-sink or C-source depending on the interannual variations in hydrometeorological factors. Disturbed deciduous stands were larger C-sinks (NEP₂₀₀₄ = 150 gC m⁻² yr⁻¹) than undisturbed coniferous stands (e.g. NEP₂₀₀₄ = 8 gC m⁻² yr⁻¹). Wetlands had lower NPP but showed temporally consistent C accumulation patterns. The simulated spatio-temporal patterns of BCPs and SCPs were unique and reflected the integrated effects of climate, plant growth and atmospheric chemistry besides the inherent properties of the C pool themselves. The simulated BCPs and SCPs generally compared well with the biometric estimates (BCPs: r = 0.86, SCPs: r = 0.84). The largest BCP biases were found in recently disturbed stands and the largest SCP biases were seen in locations where moss necro-masses were abundant. Reconstructing C pools and C fluxes in the ecosystem in such a spatio-temporal manner could help reduce the uncertainties in our understanding of terrestrial C-cycle.     

A comprehensive multidisciplinary investigation on CO2 capture from diesel engine

Environmental Science and Pollution Research - Climate change and global warming are the visible consequences of the increased amount of carbon dioxide (CO2) in the atmosphere. Among the various...     

Using biochar for remediation of soils contaminated with heavy metals and organic pollutants

Soil contamination with heavy metals and organic pollutants has increasingly become a serious global environmental issue in recent years. Considerable efforts have been made to remediate contaminated soils. Biochar has a large surface area, and high capacity to adsorb heavy metals and organic pollutants. Biochar can potentially be used to reduce the bioavailability and leachability of heavy metals and organic pollutants in soils through adsorption and other physicochemical reactions. Biochar is typically an alkaline material which can increase soil pH and contribute to stabilization of heavy metals. Application of biochar for remediation of contaminated soils may provide a new solution to the soil pollution problem. This paper provides an overview on the impact of biochar on the environmental fate and mobility of heavy metals and organic pollutants in contaminated soils and its implication for remediation of contaminated soils. Further research directions are identified to ensure a safe and sustainable use of biochar as a soil amendment for remediation of contaminated soils.     

Underwater treatment of lead-contaminated sediment

The sediment associated with the reconstruction of a bridge pier was classifiable as hazardous by the Toxicity Characteristic Leaching Procedure (TCLP), due to elevated concentrations of lead. However, RCRA regulations do not classify the sediment as hazardous unless it is moved. RMT designed an in-situ, underwater treatment process to render the sediment nonhazardous, using phosphate-based chemistry before dredging. Subsequent sediment management was conducted without the additional regulatory requirements and costs associated with managing hazardous waste.     

Organochlorine and organophosphorous pesticide residues in ground water and surface waters of Kanpur, Uttar Pradesh, India

A survey undertaken in Kanpur, northern India, has shown the presence of high concentrations of both organochlorine and organophosphorous pesticides in the surface and ground water samples. Liquid-liquid extraction followed by GC-ECD was used for the determination of these compounds. Among the various pesticides analyzed, high concentrations of gamma-HCH (0.259 microg/l) and malathion (2.618 microg/l) were detected in the surface water samples collected from the River Ganges in Kanpur. In the ground water samples collected from the various hand pumps located in agricultural and industrial areas, apart from gamma-HCH and malathion, dieldrin was also detected. The maximum concentration values of gamma-HCH, malathion and dieldrin were 0.900, 29.835 and 16.227 microg/l, respectively. Especially, the concentration of malathion was found to be much higher than the EC water quality standards in the ground water samples from industrial area posing a high risk to the common people. Pesticides like DDE, DDT, aldrin, ethion, methyl parathion and endosulfan were not detected in both the surface and ground water samples.     

High performance of catalytic sheet filters of V2O5-WO3/TiO2 for NOx reduction

Environmental Science and Pollution Research - Nitrogen oxide (NOx) emissions in fuel from the stationary as well as from mobile sources primarily from power stations, industrial heaters,...