Evaluation of Canisters for Measuring Emissions of Volatile Organic Air Pollutants from Hazardous Waste Incineration

Regulation to control air emissions of toxic organic compounds require the collection and analysis of effluent gas from low level sources such as hazardous waste incinerators. The standard SW- 846 Method specifies the use of Tenax and Tenax/charcoal adsorbent traps for collection of volatile organics from incinerators. This study evaluates passivated stainless steel canisters as an alternative to adsorbent traps to eliminate some of the problems associated with adsorbent sampling. Initially the stability of 18 nonpolar, volatile organic compounds was determined in Summa-treated stainless steel canisters with greater than 100 ppmv HCI and saturated with water vapor. All 18 components were stable for a twoweek period; however, an Interference caused a 10-fold increase In the FID response of trlchloroethylene, toluene, and chlorobenzene. No Interference of the ECD response was found for any of the 11 compounds detected with the ECD including trlchloroethylene. A pilot scale incinerator was sampled using canisters, and the destruction efficiency of 1,1,1-trichloroethane was determined at a concentration of less than 0.5 ppbv while determining 1,1-dichloroethylene, the major product of Incomplete combustion, at a concentration of 8000 ppbv from the same sample.     

Graphs of grief and other green feelings: the uses of affect in the study of environmental communication

ABSTRACT

How can theories of affect and felt emotions be useful in studying the communication of environmental crises? Beginning from tears spilt over a graph of transgressed planetary boundaries published in an academic paper, this article explores the presentation in graphic visual forms of affective imagery and a growing sophistication amongst scientists, policymakers and activist communicators in the visualization of information, data and stories employed to carry the often difficult and complex messages of current earth systems crises. Critically, this article attends to the “emotion work” of such images. Taking a lead from cultural sociology and attempting to elucidate the relationship between societies under pressure and its choice of texts, this article considers the environmental documentary Cowspiracy [Anderson, K., & Kuhn, K. (2014). Cowspiracy. San Francisco, CA: AUM Films & First Spark Media.] to ask questions of affect’s relation to expressions of the earth systems crisis, which is also a crisis of culture.     

Sentiment analysis of the Twitter response to Netflix's Our Planet documentary

The role of nature documentaries in shaping public attitudes and behavior toward conservation and wildlife issues is unclear. We analyzed the emotional content of over 2 million tweets related to Our Planet, a major nature documentary released on Netflix, with dictionary and rule-based automatic sentiment analysis. We also compared the sentiment associated with species mentioned in Our Planet and a set of control species with similar features but not mentioned in the documentary. Tweets were largely negative in sentiment at the time of release of the series. This effect was primarily linked to the highly skewed distributions of retweets and, in particular, to a single negatively valenced and massively retweeted tweet (>150,000 retweets). Species mentioned in Our Planet were associated with more negative sentiment than the control species, and this effect coincided with a short period following the airing of the series. Our results are consistent with a general negativity bias in cultural transmission and document the difficulty of evoking positive sentiment, on social media and elsewhere, in response to environmental problems.     

Spatial Analysis of Soil Salinity and Soil Structural Stability in a Semiarid Region of New South Wales,Australia

Salt-affected soils are a major threat to agriculture especially in the semiarid regions of the world. The effective management of these soils requires adequate understanding of not only how water and, hence, solutes are transported within the soil, but also how soil salinity and sodicity spatially interact to determine soil structural breakdown. For sustainable agricultural production, information on quantitative soil quality, such as salinity, is required for effective land management and environmental planning. In this study, quantitative methods for mapping indicators of soil structural stability, namely salinity and sodicity, were developed to assess the effect of these primary indicators on soil structural breakdown. The current levels of soil salinity, as measured by electrical conductivity (EC) of the soil/water suspension, soil sodicity, represented by exchangeable sodium percentage (ESP), and aggregate stability, were assessed. Remote sensing, geographical information system (GIS), and geostatistical techniques-primarily regression-kriging and indicator-kriging-were used to spatially predict the soil sodicity and salinity. The patterns of salinity (EC) and sodicity (ESP > 5%) were identified. The effect of land use on these soil quality indicators was found to be minimal. Co-spatial patterns were elucidated between sodic soils (defined by ESP > 5%) and highly probable mechanically dispersive soils predicted from indicator-kriging of ASWAT scores. It was established that the incorporation of EC with ESP into an objective index, called electrolyte stability index (ESI = ESP/EC), gave a good indication of soil dispersion, although the threshold ESI value below which effective structural breakdown might occur is 0.025, which is twice as small as the expected 0.05. The discrepancies between ESI and ASWAT scores suggest that other soil factors than salinity and sodicity are affecting soil structural breakdown. This calls for further investigation. The study provides valuable information in the form of risk zones of soil structural breakdown for land management. These zones, with a probability of mechanical soil dispersion of >0.70, require immediate management attention with greater monitoring and amelioration techniques, particularly gypsum or lime application and/or altered cultivation techniques.     

The role of climate variability in convergence of residential water consumption across Chilean localities

Environmental Economics and Policy Studies - This paper analyses the existence of convergence in residential water consumption across geographical regions using econometric methods taken from the...     

CAERvest® – a novel endothermic hypothermic device for core temperature cooling: safety and efficacy testing

Introduction. Cooling of the body is used to treat hyperthermic individuals with heatstroke or to depress core temperature below normal for neuroprotection. A novel, chemically activated, unpowered cooling device, CAERvest®, was investigated for safety and efficacy. Methods. Eight healthy male participants (body mass 79.9?±?1.9?kg and body fat percentage 16.1?±?3.8%) visited the laboratory (20 °C, 40% relative humidity) on four occasions. Following 30-min rest, physiological and perceptual measures were recorded. Participants were then fitted with the CAERvest® proof of concept (PoC) or prototype 1 (P1), 2 (P2) or 3 (P3) for 60 min. Temperature, cardiovascular and perceptual measures were recorded every 5 min. After cooling, the CAERvest® was removed and the torso checked for cold-related injuries. Results. Temperature measures significantly (p?Conclusion. This study demonstrates that the CAERvest® is an effective device for reducing body temperature in healthy normothermic individuals without presence of cold injury. Further research in healthy and clinical populations is warranted.     

Arabica-coffee and teobroma-cocoa agro-industrial waste biosorbents,for Pb(II) removal in aqueous solutions

Environmental Science and Pollution Research - Agro-industrial waste biosorbents of arabica–coffee (WCA) and theobroma–cocoa (WCT) have been characterized and tested to remove Pb(II)...     

ASsessment Of Alcohol Ethoxylate Surfactants And Fatty Alcohols Mixtures In River Sediments And Prospective Risk Assessment

A feasible and relatively readily available analytical method was adapted for the assessment of alcohol ethoxylates (AE) and fatty alcohols (FA) in sediments. This study illustrates the simultaneous measurement of 38 of 114 possible alcohol ethoxylate ethoxymers (AE) and fatty alcohols (FA) found in commercially important AE products. We predicted toxicity for all identified fractions, as well as the total mixture toxicity, relative to three exposure scenarios via sewage treatment plants (STP) for these widely used chemicals in consumer products and hence generate a preliminary environmental risk screening for AE and FA in sediments. The method is based on derivatization of solvent or solid-phase extracts with 2-fluoro-N-methylpyridinium p-toluenesulfonate (Pyr+). The derivatized extracts were analyzed with liquid chromatography/mass spectrometry (LC/MS) operating in the positive ion electrospray mode. The extraction efficiency of AE and FA in three different sediments of varying composition was evaluated with spike-recovery studies, ranging from 64% to 80%. The detection limits for individual ethoxymers typically ranged from 1 to 5ngg⁻¹on a dry weight basis. The mean limit of detection (LOD) was 6ngg⁻¹and the median LOD was 3ngg⁻¹. AE and FA in sediments were found to be stable for two weeks if preserved with 3% (v/v) formalin and stored at 4–6^∘C. Based on equilibrium partitioning, background concentrations of AE and FA were predicted to be below concentrations known to elicit chronically toxic effects. Total worst case mixture toxicities for all AE ethoxymers combined with FA were predicted to result in a risk quotient less than 0.6. Activated sludge treatment (STP) significantly reduced the release of total AE and FA by four-fold, suggesting that the total mixture risk quotient would be < 0.15 for sediment dependent organisms.     

Carbon and hydrogen isotope fractionation by microbial methane oxidation: improved determination

Isotope fractionation is a promising tool for quantifying methane oxidation in landfill cover soils. For good quantification an accurate determination of the isotope fractionation factor (alpha) of methane oxidation based on independent batch experiments with soil samples from the landfill cover is required. Most studies so far used data analysis methods based on approximations of the Rayleigh model to determine alpha. In this study, the two most common approximations were tested, the simplified Rayleigh approach and the Coleman method. To do this, the original model of Rayleigh was described in measurable variables, methane concentration and isotopic abundances, and fitted to batch oxidation data by means of a weighted non-linear errors-in-variables regression technique. The results of this technique were used as a benchmark to which the results of the two conventional approximations were compared. Three types of batch data were used: simulated data, data obtained from the literature, and data obtained from new batch experiments conducted in our laboratory. The Coleman approximation was shown to be acceptable but not recommended for carbon fractionation (error on alpha-1 up to 5%) and unacceptable for hydrogen fractionation (error up to 20%). The difference between the simplified Rayleigh approach and the exact Rayleigh model is much smaller for both carbon and hydrogen fractionation (error on alpha-1<0.05%). There is also a small difference when errors in both variables (methane concentration and isotope abundance) are accounted for instead of assuming an error-free independent variable. By means of theoretical calculations general criteria, not limited to methane, (13)C, or D, were developed for the validity of the simplified Rayleigh approach when using labelled compounds.