Evaluation of the respicon as a personal inhalable sampler in industrial environments

The Respicon has been introduced as a sampler for health related measurements of airborne contaminants at workplaces. The instrument is aimed at simultaneous collection of three health related aerosol fractions: (a) the coarser inhalable fraction, defining the aerosol fraction that may enter the nose and mouth during breathing; (b) the intermediate thoracic fraction, defining the fraction that may penetrate beyond the larynx and so reach the lung; and (c) the finer respirable fraction, defining the fraction that may penetrate to gas exchange region of the lung. The instrument has a number of features attractive to occupational hygienists: in addition to providing the three aerosol fractions simultaneously, it is light and compact enough to be used as a personal sampler. yet can be a tripod mounted for area sampling, it can provide samples not only for gravimetric analysis but also microscopic and chemical analyses; and it is also available in a photometric direct-reading version. The instrument has previously been evaluated as an area sampler and, in this mode of operation, has shown reasonable accuracy in collecting respirable, thoracic and inhalable particles, the latter up to particle diameters of ca. 80 microm. Except for some scattered unpublished data there exist no systematic investigations in the Respicon's performance when used as a personal sampler in the industrial environment. In this paper, we will report on a study of side by side comparison of the Respicon with the IOM inhalable sampler, regarded as a reference instrument for the inhalable fraction. The main study was performed at six different workplaces in a nickel refinery. Statistical analysis of the gravimetrically-determined concentration data reveals consistently lower aerosol exposure values for the Respicon as compared to the IOM sampler. The data for the nickel workplaces are compared with findings from other studies. The results are interpreted in the light of the overall results and the possibility of introducing a correction factor is discussed.     

Diclofenac sodium aqueous systems at low concentrations: Interconnection between physicochemical properties and action on hydrobionts

Diclofenac sodium(DS) is a widely used nonsteroidal anti-inflammatory drug(NSAIDs).NSAIDs are poorly removed during standard wastewater treatment.The consequences of the presence of NSAIDs in rivers and lakes at 10~(-11)–10~(-8) mol/L are not yet established;therefore, ecotoxicologists have focused their efforts on studying the effect of lowconcentration NSAIDs on fish and hydrobionts, and also on predicting the potential risks to humans.Literature provides some information about the bioeffects of some NSAID solutions in low concentrations but there is no physicochemical explanation for these phenomena.Studying the physicochemical patterns of DS solutions in the low range of concentrations and establishing an interconnection between the solutions' physicochemical properties and bioeffects can provide a conceptually new and important source of information regarding the unknown effects of DS.The physicochemical properties and action of DS solutions on Ceriodaphnia affinis cladocerans,Paramecium caudatum infusoria, Chlorella vulgaris unicellular green algae, as well as on the growth of the roots of Triticum vulgare wheat seeds, were studied in the calculated concentration range of 1 × 10~(-3)–1 × 10~(-18) mol/L.The relationship between these phenomena was established using the certified procedures for monitoring the toxicity of natural water and wastewater.It was shown for the first time that water solutions of DS are dispersed systems in which the dispersed phase undergoes a rearrangement with dilution, accompanied by changes in its size and properties, which affects the nonmonotonic dependences of the system's physicochemical properties and could cause nonmonotonic changes in action on hydrobionts in the low concentration range.     

A FAST RECURSIVE GIS ALGORITHM FOR COMPUTING STRAHLER STREAM ORDER IN BRAIDED AND NONBRAIDED NETWORKS1

ABSTRACT: Stream ordering is a useful property of every river network, having a wide range of applications. A method for determining stream orders that quickly and easily addresses various network topologies and magnitudes is therefore needed. This paper introduces a general recursive stream ordering framework for vector hydrography. It also presents a linear, O(n), stream ordering procedure for braided river networks, which is a major improvement to the existing quadratic, O(n²), procedure. The discussion includes results and interpretations, and the appendices present procedure pseudocodes and thorough line by line explanations.     

The Analysis of Sustainability Indicators as Socially Constructed Policy Instruments: benefits and challenges of 'interactive research'

Sustainability indicator sets are increasingly being discussed on the policy level as fruitful contributions to the improvement of political decision- making and to the implementation of programs oriented towards the achievement of strategic goals of sustainable development. The vast number of different indicator type tools, their varying contexts of use and their differing objectives indicate that there is no simple answer to what sustainable indicator type tools should look like or could be used for. Instead, more than the final products (e.g. a specific indicators set), the analyses of the discourse on this topic reveal a lot of information. Thus, an innovative research approach is recommended focusing on understanding the production of social meaning and processes of social interaction within political-administrative systems. Firstly, there is a need to identify the development, purpose and use of sustainability indicator sets, which depend on the different interests of policy actors, their relationships and existing governance structures. Secondly, one should identify any reasons for the ineffective use of indicator sets where the goals of sustainability are concerned. The approach of 'interactive research' understood as a research process, in which 'researchers' and 'practitioners' develop knowledge for solving problems in a communicative, reflexive and collaborative way, facilitates this challenging research task. This paper critically examines the approach of interactive research and sheds some light on benefits as well as challenges of it via extracting the lessons learnt in an EU-funded project called 'Promoting Action for Sustainability through Indicators at the Local Level in Europe' (PASTILLE), which applied an interactive research approach.     

EFFECT OF PRICE ON THE RESIDENTIAL DEMAND FOR WATER WITHIN AN AGENCY1

ABSTRACT: This paper develops a model that can be used to forecast the residential elasticity of demand for water within a district. Long-term water conservation programs and revenue and cost decisions hinge crucially on a determination of this elasticity. This study then pools cross-sectional (census) and time series data to generate elasticity forecasts for the Oakland urban area.     

TRENDS IN LEAD CONCENTRATIONS IN MAJOR U.S. RIVERS AND THEIR RELATION TO HISTORICAL CHANGES IN GASOLINE-LEAD CONSUMPTION1

ABSTRACT: Declines in concentrations of dissolved lead occurred at nearly two-thirds of 306 locations on major U.S. rivers from 1974 to 1985. Declines in dissolved lead concentrations are statistically significant (p < 0.10) at approximately one-third of the sampling locations. Statistically significant increases in dissolved lead concentrations occurred at only 6 percent of the sites, but are clustered in the Texas-Gulf and Lower Mississippi regions. Possible explanations for the observed trends in lead concentrations are tested through comparisons with (1) records of lead discharges from major sources including leaded-gasoline consumption and municipal- and industrial-point source discharges, (2) trends in various water-quality constituents such as pH and total alkalinity, and (3) basin characteristics such as drainage area. Statistically significant declines in lead concentrations in streams and gasoline lead (i.e., the largest source of lead at these sites) are highly coincident for the 1979 to 1980 period at most sampling locations. The greatest amount of decline in gasoline lead occurred at sites showing statistically significant downtrends in stream concentrations of lead from 1974 to 1985. No more than 5 percent of the trends in stream lead are influenced by municipal- and industrial-point sources of lead. Factors that affect the transport of dissolved lead, including lead solubility, suspended sediment, and basin characteristics such as drainage basin size, are not significantly related to trends in dissolved lead. Trends in streamflow explain no more than 7 percent of the downtrends in concentrations of lead and may partly explain the frequent increases in lead concentrations in the Texas-Gulf and Lower Mississippi regions.     

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