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81.
Amber Krause 《Environmental Communication: A Journal of Nature and Culture》2018,12(3):322-343
The news media’s increased reliance on visual communication to illustrate complex processes and promote learning stresses the importance of investigating how visual content impacts the understanding of scientific issues. In this paper, we investigate how members of the public interpret and make sense of differentially framed images of hydraulic fracturing (fracking) depicting environmental risk, economic benefit, or issue protest. For the analysis, a repeated measures online experiment was conducted with 250 participants to evaluate 40 photographs of fracking operations and consequences. Quantitative coding and thematic analysis of open-ended responses to the images reveal that standing attitudes, operationalized as support, opposition, or indecision about fracking, segments viewers into distinct groups and shapes interpretations of environmental risk and economic benefit. Issue opponents are more likely to indicate concern for the environment regardless of frame shown, whereas undecideds and supporters cite the impact on human health more frequently, largely in relation to job site safety. Supporters also see the least ambiguity, and most economic gains, in images about the controversial production practice. 相似文献
82.
Jean Rouchaud Pascal Roucourt Alfons Vanachter Frans Benoit Norbert Ceustermans 《毒物与环境化学》2013,95(1):59-68
Broccoli and Chinese cabbage crops were treated at planting by pouring an emulsion of the fungicide chlorothalonil around the stem of the plant. During culture, chlorothalonil was biodegraded in soil into l,3‐dicarbamoyl‐2,4,5,6‐tetrachlorobenzene (compound 1), l,3‐dicyano‐4‐hydroxy‐2,5,6‐trichlorobenzene (compound 2), and l‐carbamoyl‐3‐cyano‐4‐hydroxy‐2,5,6‐trichlorobenzene (compound 3). Compounds 1 and 2 were the major metabolites in soil. In the harvested broccoli (in the flower) and Chinese cabbages (the leaves), the concentrations of chlorothalonil and of compounds 1 and 2 were lower respectively than 0.1, 0.1 and 0.5mg/kg fresh weight. 相似文献
83.
84.
Grünhage L Krause GH Köllner B Bender J Weigel HJ Jäger HJ Guderian R 《Environmental pollution (Barking, Essex : 1987)》2001,111(3):355-362
The current European critical levels for ozone (O3) to protect crops, natural and semi-natural vegetation and forest trees are based on a relative small number of open-top chamber experiments with a very limited number of plant species. Therefore, the working group "Effects of Ozone on Plants" of the Commission on Air Pollution Prevention of the Association of German Engineers and the German Institute of Standardization reanalysed the literature on O3 effects on European plant species published between 1989 and 1999. An exposure-response relationship for wild plant species and agricultural crops could be derived from 30 experiments with more than 30 species and 90 data points; the relationship for conifer and deciduous trees is based on 20 experiments with nine species and 50 data points. From these relationships maximum O3 concentrations for different risk stages are deduced, below which the vegetation type is protected on the basis of the respective criteria. Because it is assumed that the fumigation concentrations reflect the O3 concentrations at the top of the canopy, i.e. the upper surface boundary of the quasi-laminar layer if the micrometeorological big-leaf approach is applied, the application of these maximum O3 concentrations requires the transformation of O3 concentrations measured at a reference height above the canopy to the effective phytotoxic concentrations at the top of the canopy. Thus, the approach described in this paper is a synthesis of the classical concept of toxicology of air pollutants (critical concentrations) and the more toxicological relevant dose concept. 相似文献
85.
The oxycoal process with cryogenic oxygen supply 总被引:1,自引:0,他引:1
Due to its large reserves, coal is expected to continue to play an important role in the future. However, specific and absolute
CO2 emissions are among the highest when burning coal for power generation. Therefore, the capture of CO2 from power plants may contribute significantly in reducing global CO2 emissions. This review deals with the oxyfuel process, where pure oxygen is used for burning coal, resulting in a flue gas
with high CO2 concentrations. After further conditioning, the highly concentrated CO2 is compressed and transported in the liquid state to, for example, geological storages. The enormous oxygen demand is generated
in an air-separation unit by a cryogenic process, which is the only available state-of-the-art technology. The generation
of oxygen and the purification and liquefaction of the CO2-enriched flue gas consumes significant auxiliary power. Therefore, the overall net efficiency is expected to be lowered by
8 to 12 percentage points, corresponding to a 21 to 36% increase in fuel consumption. Oxygen combustion is associated with
higher temperatures compared with conventional air combustion. Both the fuel properties as well as limitations of steam and
metal temperatures of the various heat exchanger sections of the steam generator require a moderation of the temperatures
during combustion and in the subsequent heat-transfer sections. This is done by means of flue gas recirculation. The interdependencies
among fuel properties, the amount and the temperature of the recycled flue gas, and the resulting oxygen concentration in
the combustion atmosphere are investigated. Expected effects of the modified flue gas composition in comparison with the air-fired
case are studied theoretically and experimentally. The different atmosphere resulting from oxygen-fired combustion gives rise
to various questions related to firing, in particular, with regard to the combustion mechanism, pollutant reduction, the risk
of corrosion, and the properties of the fly ash or the deposits that form. In particular, detailed nitrogen and sulphur chemistry
was investigated by combustion tests in a laboratory-scale facility. Oxidant staging, in order to reduce NO formation, turned
out to work with similar effectiveness as for conventional air combustion. With regard to sulphur, a considerable increase
in the SO2 concentration was found, as expected. However, the H2S concentration in the combustion atmosphere increased as well. Further results were achieved with a pilot-scale test facility,
where acid dew points were measured and deposition probes were exposed to the combustion environment. Besides CO2 and water vapour, the flue gas contains impurities like sulphur species, nitrogen oxides, argon, nitrogen, and oxygen. The
CO2 liquefaction is strongly affected by these impurities in terms of the auxiliary power requirement and the CO2 capture rate. Furthermore, the impurity of the liquefied CO2 is affected as well. Since the requirements on the liquid CO2 with regard to geological storage or enhanced oil recovery are currently undefined, the effects of possible flue gas treatment
and the design of the liquefaction plant are studied over a wide range. 相似文献
86.
Frank M. Hauser Tim Metzner Thorsten Rößler Michael Pütz Steffen Krause 《Environmental Forensics》2019,20(1):13-25
The entry of illegally discharged waste into the sewage system can cause serious damage to sewage pipes and harm the public domain. Besides industrial and communal sources, discharges from clandestine laboratories are of special forensic interest. Aim of this study is to investigate the possibility to detect clandestine discharges of possibly hazardous waste directly at the point of discharge. Tests were performed at a facility where real wastewater was pumped in a controlled way through an open sewage pipe above ground. Chloride, ammonia, pH and conductivity electrodes were investigated for their ability to detect discharges of different types of waste. Waste samples were diluted up to 50 times in a static wastewater environment and pH, conductivity and chloride electrodes were able to distinguish all waste dilutions from blank wastewater. These three electrodes were then used for dynamic tests by placing them inside flowing sewage water and discharging different types of liquid waste ten meters upstream of them. Parameters of the waste discharges like volume, time interval and speed of discharge were varied and the responses of the electrodes were collected. The dynamic tests showed that these three electrodes were able to pick up different waste discharges in a real wastewater environment. It was found that a high sampling rate of the sensors would be required to connect a certain discharge to a specific household connection. These findings highlight the possibility to locate illegal discharges, coming from a variety of sources, using the waste discharge itself. 相似文献
87.
Mengmei Zhang Alfons Buekens Xiaodong Li 《Journal of Material Cycles and Waste Management》2018,20(3):1516-1529
Typical thermal fingerprints are rather evenly composed of all available polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) congeners, a feature also linked with CuCl2-catalysis. Conversely, chlorophenol condensation patterns are supported strongly by CrCl3-, ZnCl2- and CdCl2-catalysis; they feature selective formation of, e.g., 1,3,6,8- and 1,3,7,9-TCDD arising from mainly 2,4,6-trichlorophenol, a chlorophenol well-represented in incinerator flue gas. Just few, well-defined PCDD-congeners steadily emerge from chlorophenols. Surprisingly, it is experimentally established that these are not generally formed by parallel processes. Additionally, the formation of four important 2,3,7,8-substituted TCDD/F- and PeCDD/F-congeners is statistically quasi-unrelated. Apparently, external (α) or lateral (β)-chlorination occurs as a chance event, contrary to observations and hypotheses in earlier studies. These statements are corroborated by selected congener-to-congener representations. For performing this statistical analysis, simple techniques are followed. Cross-correlation matrices show a relationship for each pair of PCDD/F-congeners in a particular data set: PCDD/F-congener pairs statistically correlate, anti-correlate, or appear rather neutral. In this paper, these novel concepts were applied on data, established during tests on Model Fly Ash (MFA); principal component analysis was used to demonstrate the relevance of MFA-data in relation to municipal solid waste incineration signatures. 相似文献
88.
Photocatalysis is applied increasingly in addressing and solving environmental and energy-related problems. Especially the TiO2-derived catalysts attract attention because of their catalytic efficiency, wide range of applications, ease in use, and low cost (it costs about 150 Yuan a kilogram in China). This review first describes the principles of photocatalytic destruction by semiconductors and then focuses on degradation rates and reaction mechanisms in a variety of photocatalytic uses of modified TiO2. Finally, these concepts are illustrated by selected examples relating to the photocatalytic degradation of organic persistent pollutants, such as polychlorinated benzenes (PCBz), biphenyls (PCB) and dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). And some approaches towards industrial application are analyzed. 相似文献
89.
Rosalinda Gioia Abidemi James Akindele Sunday Adekunle Adebusoye Kwadwo Ansong Asante Shinsuke Tanabe Alfons Buekens Annie J. Sasco 《Environmental science and pollution research international》2014,21(10):6278-6289
Several studies have shown an increase in PCB sources in Africa due to leakage and wrongly disposed transformers, continuing import of e-waste from countries of the North, shipwreck, and biomass burning. Techniques used in the recycling of waste such as melting and open burning to recover precious metals make PCBs contained in waste and other semivolatile organic substances prone to volatilization, which has resulted in an increase of PCB levels in air, blood, breast milk, and fish in several regions of Africa. Consequences for workers performing these activities without adequate measures of protection could result in adverse human health effects. Recent biodegradation studies in Africa have revealed the existence of exotic bacterial strains exhibiting unique and unusual PCB metabolic capability in terms of array of congeners that can serve as carbon source and diversity of congeners attacked, marking considerable progress in the development of effective bioremediation strategies for PCB-contaminated matrices such as sediments and soils in tropical regions. Action must be taken to find and deal with the major African sources of these pollutants. The precise sources of the PCB plume should be pinned down and used to complete the pollutant inventories of African countries. These nations must then be helped to safely dispose of the potentially dangerous chemicals. 相似文献
90.
Max J. Krause Giles W. Chickering 《Journal of the Air & Waste Management Association (1995)》2016,66(11):1084-1097
Landfill gas (LFG) generation is predicted by a first-order decay (FOD) equation that incorporates two parameters: a methane generation potential (L0) and a methane generation rate (k). Because non-hazardous waste landfills may accept many types of waste streams, multiphase models have been developed in an attempt to more accurately predict methane generation from heterogeneous waste streams. The ability of a single-phase FOD model to predict methane generation using weighted-average methane generation parameters and tonnages translated from multiphase models was assessed in two exercises. In the first exercise, waste composition from four Danish landfills represented by low-biodegradable waste streams was modeled in the Afvalzorg Multiphase Model and methane generation was compared to the single-phase Intergovernmental Panel on Climate Change (IPCC) Waste Model and LandGEM. In the second exercise, waste composition represented by IPCC waste components was modeled in the multiphase IPCC and compared to single-phase LandGEM and Australia’s Solid Waste Calculator (SWC). In both cases, weight-averaging of methane generation parameters from waste composition data in single-phase models was effective in predicting cumulative methane generation from -7% to +6% of the multiphase models. The results underscore the understanding that multiphase models will not necessarily improve LFG generation prediction because the uncertainty of the method rests largely within the input parameters. A unique method of calculating the methane generation rate constant by mass of anaerobically degradable carbon was presented (kc) and compared to existing methods, providing a better fit in 3 of 8 scenarios. Generally, single phase models with weighted-average inputs can accurately predict methane generation from multiple waste streams with varied characteristics; weighted averages should therefore be used instead of regional default values when comparing models.
Implications: Translating multiphase first-order decay model input parameters by weighted average shows that single-phase models can predict cumulative methane generation within the level of uncertainty of many of the input parameters as defined by the Intergovernmental Panel on Climate Change (IPCC), which indicates that decreasing the uncertainty of the input parameters will make the model more accurate rather than adding multiple phases or input parameters. 相似文献