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531.
Recently, although dynamic approaches have been used increasingly to describe metal bioaccumulation in aquatic organisms, the validation of such laboratory-derived modelling is rarely assessed under environmental conditions. The present study aims to evaluate and verify statistical and mathematical models for the bioaccumulation of cadmium (Cd) and to evaluate the suitability of Gammarus pulex as a biomonitor for Cd. To optimise Cd2+ ion bioaccumulation conditions a Box–Behnken design was used and whether G. pulex can be used as an estimated tool to assess aquatic quality was investigated. A Box–Behnken experimental design combined with response surface modelling (RSM) was employed for Cd2+ bioaccumulation in G. pulex. Independent variables including temperature, contact time and Cd2+ ion concentration significance and their interactions were tested using analysis of variance. The selected variables’ optimum values were obtained by solving the quadratic regression model along with by analysing the response surface contour plots. Based on Box–Behnken design, the applied model is significant because model F-value and R2 were obtained as 5121.49, 0.9998, respectively. Bioaccumulation of Cd amount was analysed using electrothermal atomic absorption spectrophotometer. The obtained data suggest that G. pulex can be evaluated as Cd biomonitor. 相似文献
532.
Eshrat Gharaei-Fathabad Mojtaba Tabatabaei Yazdi Seyed-Nasser Ostad Mohammad Ali Faramarzi 《毒物与环境化学》2013,95(4):795-799
The extracellular extract obtained from 3 weeks incubation of the soil isolate cyanobacterium strain Nostoc piscinale GT-319 in BG-11 broth medium showed cytotoxic activity against Chinese Hamster Ovary (CHO) cells. Based on comet assay, a concentration of 333 µg mL?1 (IC50) produced DNA breakages in CHO cells. The concentration of 481 mg kg?1 (LD50) produced acute toxicity in mice at 48 h. 相似文献
533.
Abbas Akbarzadeh Hasan-Ali Laghai Masuod Monavari Shaban Ali Nezami Seyed Soheil Saeedi Saravi 《毒物与环境化学》2013,95(6):1055-1062
The trophic state of the Anzali wetland was determined by nutrient analysis, indicating an alarming hypertrophic state. The Anzali wetland is environmentally and economically one of the most important ecosystems that is located in north-west Iran. This wetland was registered as a Ramsar site in September 1975, but due to many problems, particularly eutrophication created by excessive amounts of nutrients, it was registered in the Montreux record. This study was conducted for a year on 21 stations in three zones including receiving rivers, surface water and exiting rivers. Geographic information systems were used to better understand the prevailing situation. Analysis was conducted according to international standards and classification of OECD for freshwaters. The indicators used were levels of total nitrogen (TN) and total phosphorous (TP), and the trophic state index (TSI). Data showed an increase of excess nutrients from domestic and agricultural sources, leading to human, cultural eutrophication processes rather than natural eutrophication. 相似文献
534.
Mukhtar Ahmed Ravindranath H. Aladakatti Suliman Y. Al Omar Daoud Ali Shaban Rushdy Sayed Mukhtar Ahmed Ghodesawar 《毒物与环境化学》2013,95(8):1207-1220
Boswellia papyrifera and Boswellia carterii released from smoke contaminate indoor environment and consequently adversely affect humans as evidenced by respiratory disturbances. The aim of this study was to determine the effects of these plants on pathological and biochemical changes in vas deferens of albino rats. Animals were administered 4 g/kg body weight B. papyrifera and B. carterii daily for 120 days along with controls. Significant changes were observed in epithelial cell types and some cells showed signs of degeneration. The ultrastructural studies revealed marked changes in cytoplasmic organelles. Microvilli were missing and lysosomes were found in the cytoplasm. In addition, all treated groups plasma fructose and other biochemical parameters were decreased indicating reduced energy necessary for motility and contractility of spermatozoa. Many spermatozoa were disorganized and agglomerated. Data suggest that smoke from these plants adversely affects vas deferens. 相似文献
535.
Mushtaq Ahmed Zafer Ullah Wazir Rahmat Ali Khan Mohammed Imran Khan Syed Waqas Asif Iqbal 《毒物与环境化学》2013,95(9):1539-1545
Medicinal plants play a crucial role in maintaining human health. Kalanchoe pinnata has been used for treatment of different ailments like infections, rheumatism, and inflammation. Data showed that Kalancho pinnata methanolic extract (100 or 1000 μg/ml) significantly inhibited growth of shoots (hypocotyls) and roots (radicals) of rice compared to control after 3 or 7 days treatment. Further, the Kalancho pinnata methanolic extract (50–1000 μg/ml) exhibited antioxidant properties and scavenged free radicals in dose-dependent manner compared with a standard antioxidant (ascorbic acid). Kalancho pinnata methanolic extract also possesses antifungal property that inhibited approximately 76% and 51% growth of Aspergillus flavous and Aspergillus niger, respectively, using the extract at 200 μg/ml. 相似文献
536.
Ali?NasrolahiEmail author Christian?Pansch Mark?Lenz Martin?Wahl 《Marine Biology》2012,159(2):331-340
The fate of key species, such as the barnacle Amphibalanus improvisus, in the course of global change is of particular interest since any change in their abundance and/or performance may entail
community-wide effects. In the fluctuating Western Baltic, species typically experience a broad range of environmental conditions,
which may preselect them to better cope with climate change. In this study, we examined the sensitivity of two crucial ontogenetic
phases (naupliar, cypris) of the barnacle toward a range of temperature (12, 20, and 28°C) and salinity (5, 15, and 30 psu)
combinations. Under all salinity treatments, nauplii developed faster at intermediate and high temperatures. Cyprid metamorphosis
success, in contrast, was interactively impacted by temperature and salinity. Survival of nauplii decreased with increasing
salinity under all temperature treatments. Highest settlement rates occurred at the intermediate temperature and salinity
combination, i.e., 20°C and 15 psu. Settlement success of “naive” cyprids, i.e., when nauplii were raised in the absence of
stress (20°C/15 psu), was less impacted by stressful temperature/salinity combinations than that of cyprids with a stress
history. Here, settlement success was highest at 30 psu particularly at low and high temperatures. Surprisingly, larval survival
was not highest under the conditions typical for the Kiel Fjord at the season of peak settlement (20°C/15 psu). The proportion
of nauplii that ultimately transformed to attached juveniles was, however, highest under these “home” conditions. Overall,
only particularly stressful combinations of temperature and salinity substantially reduced larval performance and development.
Given more time for adaptation, the relatively smooth climate shifts predicted will probably not dramatically affect this
species. 相似文献
537.
Prediction of non-methane hydrocarbons in Kuwait using regression and Bayesian kriged Kalman model 总被引:1,自引:0,他引:1
This article describes the hierarchical Bayesian approach for predicting average hourly concentrations of ambient non-methane hydrocarbons (NMHC) in Kuwait where records of six monitor stations located in different sites are observed at successive time points. Our objective is to predict the concentration level of NMHC in unmonitored areas. Here an attempt is made for the prediction of unmeasured concentration of NMHC at two additional locations in Kuwait. We will implement a kriged Kalman filter (KKF) hierarchical Bayesian approach assuming a Gaussian random field, a technique that allows the pooling of data from different sites in order to predict the exposure of the NMHC in different regions of Kuwait. In order to increase the accuracy of the KKF we will use other statistical models such as imputation, regression, principal components, and time series analysis in our approach. We considered four different types of imputation techniques to address the missing data. At the primary level, the logarithmic field is modeled as a trend plus Gaussian stochastic residual model. The trend model depends on hourly meteorological predictors which are common to all sites. The residuals are then modeled using KKF, and the prediction equation is derived conditioned on adjoining hours. On this basis we developed a spatial predictive distribution for these residuals at unmonitored sites. By transforming the predicted residuals back to the original data scales, we can impute Kuwait’s hourly non-methane hydrocarbons field. 相似文献
538.
Mehdi Bagheri Mehrdad BagheriFarzane Heidari Ali Fazeli 《Journal of Loss Prevention in the Process Industries》2012,25(1):40-51
New chemical process design strategies utilizing computer-aided molecular design (CAMD) can provide significant improvements in process safety by designing chemicals with required target properties and the substitution of safer chemicals. An important aspect of this methodology concerns the prediction of properties given the molecular structure. This study utilizes one such emerging method for prediction of a hazardous property, flash point (FP), which is in the center of attention in safety studies. Using such a reliable data set comprising 1651 organic and inorganic chemicals, from 79 diverse material classes, and robust dynamic binary particle swarm optimization for the feature selection step resulted in the most efficient molecular features of the FP investigations. Apart from the simple yet precise five-parameter multivariate model, the FP nonlinear behavior was thoroughly investigated by a novel hybrid of particle swarm optimization and support vector regression. Besides, 195 missing experimental FPs of the DIPPR data set are predicted via the presented procedure. 相似文献
539.
Environmental and Ecological Statistics - In this paper we explore a covariance-spectral modelling strategy for spatial-temporal processes which involves a spectral approach for time but a... 相似文献
540.
Ahmad?Dirany Patrick?DroguiEmail author My?Ali?El Khakani 《Environmental Chemistry Letters》2016,14(4):507-514
Calcium carbonate (CaCO3) deposited in water systems leads to scale formation, decreases flow rate, reduces heat transfer and favors microbial proliferation of toxic bacteria such as Legionella. This issue may be solved by electrochemical deposition, without adding toxic chemicals. Therefore, we studied here the deposition of CaCO3 by electrochemical reduction of oxygen into hydroxide ions with stainless steel and titanium (Ti) working electrodes. Analysis was done using cyclic voltammetry, chronoamperometry, dynamic impedance spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy (EDX) coupled with X-ray diffraction (XRD). Results show that optimal formation of CaCO3 is done at ?1.2 V with the stainless steel electrode and at ?1.4 V for the Ti electrode. More negative potentials induce the formation of calcite. Using the Ti electrode, we found that aragonite is the major form (82 %), with only one capacitive loop. Using the stainless steel electrode at 1.2 V, we found 47 % of aragonite and 38 % of calcite. Overall, our findings demonstrate the feasibility of the electrochemical deposition of CaCO3 in cooling water systems, without the addition of any chemical. 相似文献