Effects of oyster shell on soil chemical and biological properties and cabbage productivity as a liming materials

Oyster shell, a byproduct of shellfish-farming in Korea and containing a high amount of CaCO(3), has a high potential to be used as a liming material in agriculture. However, the agricultural utilization of oyster shell is limited due to its high concentration NaCl. The oyster-shell meal collected had a low concentration of water soluble NaCl (mean 2.7 g kg(-1)), which might be a result of stacking the material for 6 months in the open field. It has a very similar liming potential with calcium carbonate, with 3.4 and 3.8 Mg ha(-1) for silt loam (SiL, pH 6.2) and sandy loam (SL, pH 5.8) to bring the soil pH to 6.5, respectively. To determine the effect of crushed oyster-shell meal on improving soil chemical and biological properties and crop plant productivity, oyster-shell meal was applied at rates of 0, 4, 8, 12, and 16 Mg ha(-1) before transplanting Chinese cabbage (Brassica campestris L.) in the two soils mentioned above. Soil pH was significantly increased to 6.9 and 7.4 by 16 Mg ha(-1) shell meal application (4 times higher level than the recommendation) in SiL and SL, respectively, at harvesting stage. The effect of liming was found higher in SL compared to SiL soil, probably due to the different buffering capacity of the two soils. The concentration of NaCl and EC value of soils were found slightly increased with shell meal applications, but no salt damage was observed. Oyster-shell meal application increased soil organic matter, available P, and exchangeable cations concentrations. The improved soil pH and nutrient status significantly increased the microbial biomass C and N concentrations and stimulated soil enzyme activities. With the exception of acid phosphomonoesterase (PMEase) activity, which decreased with increasing soil pH in SL but slightly increased in SiL, the activities of urease and alkali PMEase increased markedly with increasing soil pH by shell meal application. The improved soil chemical and biological properties resulted in increased crop productivity. The highest yield in Chinese cabbage was achieved following the application of 8 Mg ha(-1) oyster-shell meal. Conclusively, crushed oyster shell could be used as an alternative liming material to restore the soil chemical and microbial properties in upland soil and to increase crop productivity.     

Contamination levels of selected organochlorine and organophosphate pesticides in the Selangor River, Malaysia between 2002 and 2003

In Malaysia, rivers are the main source of public water supplies. This study was conducted from 2002 to 2003 to determine the levels of selected organochlorine and organophosphate pesticides in the Selangor River in Malaysia. Surface water samples have been collected seasonally from nine sites along the river. A liquid-liquid extraction followed by gas chromatography-mass spectrometry technique was used to determine the trace levels of these pesticide residues. The organochlorine pesticides detected were lindane, heptachlor, endosulfan, dieldrin, endosulfan sulfate, o,p'-DDT, p,p'-DDT, o,p'-DDE and p,p'-DDE whereas for organophosphate pesticides, they were chlorpyrifos and diazinon. At the river upstream where a dam is located for public water supply, incidents of pesticide levels exceeding the European Economic Community Directive of water quality standards have occurred. Furthermore, the wetland ecosystems located at the downstream of the river which houses the fireflies community is being threatened by occasional pesticide levels above EPA limits for freshwater aquatic organisms. The occurrence of these residual pesticides in the Selangor River can be attributed to the intense agriculture and urban activity.     

Enhanced photocatalytic activities of silicon nanowires/graphene oxide nanocomposite: Effect of etching parameters

Homogeneous and vertically aligned silicon nanowires (SiNWs) were successfully fabricated using silver assisted chemical etching technique. The prepared samples were characterized using scanning electron microscopy, transmission electron microscopy and atomic force microscopy. Photocatalytic degradation properties of graphene oxide (GO) modified SiNWs have been investigated. We found that the SiNWs morphology depends on etching time and etchant composition. The SiNWs length could be tuned from 1 to 42 µm, respectively when varying the etching time from 5 to 30 min. The etchant concentration was found to accelerate the etching process; doubling the concentrations increases the length of the SiNWs by a factor of two for fixed etching time. Changes in bundle morphology were also studied as function of etching parameters. The SiNWs diameter was found to be independent of etching time or etchant composition while the size of the SiNWs bundle increases with increasing etching time and etchant concentration. The addition of GO was found to improve significantly the photocatalytic activity of SiNWs. A strong correlation between etching parameters and photocatalysis efficiency has been observed, mainly for SiNWs prepared at optimum etching time and etchant concentrations of 10 min and 4:1:8. A degradation of 92% was obtained which further improved to 96% by addition of hydrogen peroxide. Only degradation efficiency of 16% and 31% has been observed for bare Si and GO/bare Si samples respectively. The obtained results demonstrate that the developed SiNWs/GO composite exhibits excellent photocatalytic performance and could be used as potential platform for the degradation of organic pollutants.     

Energy flow modeling and sensitivity analysis of inputs for canola production in Iran

This study examines energy use patterns and the relationship between energy inputs and yield for canola production in Golestan province of Iran. Data used in this study were obtained from 130 randomly selected canola farms using a face to face survey. The results revealed that total energy of 17,786.36 MJ ha⁻¹ was required for canola production and fertilizer, diesel fuel and electricity were the main energy consuming inputs. Energy use efficiency and energy productivity were 3.02 and 0.12 kg MJ⁻¹, respectively. Moreover, in specifying a functional relationship the Cobb-Douglas production function was applied and the results showed that machinery, fertilizer, diesel fuel and water for irrigation energies significantly contributed to yield. Also, the marginal physical productivity (MPP) technique was applied to analyze the sensitivity of energy inputs. It was found that, canola production had more sensitivity on machinery, fertilizer and water for irrigation energies; so that an additional use of 1 MJ from each of the machinery, total fertilizer and water for irrigation would lead to an increase in production by 0.93, 0.61 and 0.24 kg, respectively. However, electricity and seed energies were contributed negatively to yield, which may result in inverse effect on yield and impose risks to the environment.     

Contesting governance of indigenous forests in New Zealand: The case of the West Coast Forest Accord

This paper uses the concept of ‘governance’ and the related notion of ‘multi-layered’ forest management decision making as an overarching framework for analysis of conflict between different stakeholder groups with contrasting perceptions about ‘appropriate’ use of indigenous forests in a New Zealand case study. In New Zealand, recent institutional reforms inspired by neo-liberal policy agendas have led to substantial conflicts between segments of society over the ‘appropriate’ governance of remnant indigenous forests. This study focuses on the West Coast Forest Accord (WCFA) as an illustration of the attempt to change governance structures of indigenous forest management by re-regulating the indigenous forest industry. It is argued that by seeking to accommodate multiple stakeholder interests, in particular industry, community and environmental groups, the WCFA was doomed to fail, as multiple, and often conflicting, stakeholder agendas focused on the goal of ‘sustainable management’ of indigenous forests could no longer be reconciled. Notwithstanding the shift in emphasis from government towards governance in the recent literature, the study findings confirm a continuing strong role by the state as an actor in the forestry sector in New Zealand.     

Determining the heavy metal pollution in Denizli (Turkey) by using Robinio pseudo-acacia L

The leaves of Robinia pseudo-acacia L. (Fabaceae) were evaluated as a biomonitors of heavy metal contamination in Denizli city, Turkey. Concentrations of Fe, Zn, Pb, Cu, Mn and Cd were determined in washed and unwashed leaves and soils collected from a wide range of sites with different degrees of metal pollution (industry, urban roadside, suburban) and from a rural (control) site by atomic absorption spectrometry. All the elements that measured were found to be at high levels in samples collected at industrial sites, except for lead and copper which were found at high levels in samples collected from urban roadsides that associated with the road traffic. The strong correlation between the degree of contamination and concentrations in all plant leaves assessed display that the leaves of R. pseudo-acacia reflect the environmental changes accurately, and that they seem as an effective biomonitor of environmental quality in areas subjected to industrial and traffic pollutions.     

Computer professionals and Carpal Tunnel Syndrome (CTS).

Carpal Tunnel Syndrome (CTS) is an important problem among computer professionals. Hence the prevalence of CTS among computer professionals and risk factors were studied. 648 subjects were selected from 4,276 computer professionals from 21 companies by with simple random sampling method. CTS was diagnosed based on clinical features. The prevalence of CTS was found to be 13.1% (95% CI 10.5-15.7%). Subjects with over 8 years of computer work, over 12 hrs of work per day and system administrators were at a higher risk for CTS (OR 3.3, 4.9 and 2.5 respectively). Flexed or extended hand position had higher risk for CTS. Higher risk for CTS was found with higher exposure to computer work. Ergonomic considerations are important in facilitating proper positioning of hand while working with a computer. Further studies on CTS risk factors among computer professionals are essential for planning prevention.     

REAL-TIME SOIL WATER MONITORING FOR OPTIMUM WATER MANAGEMENT1

Abstract: Efficient water resource management is one of the most important policy issues facing agriculture in Hawaii in the years ahead. Soil water sensors, multisensor capacitance probes (MCP), have been successfully used for different water management projects. These MCPs monitor water content at multiple depths and at various locations in real-time. The objectives of this study were to determine the effect of water content on field soil bulk density of Wahiawa silty clay tropical soil; measure field saturated hydraulic conductivity of this tropical soil: calibrate MCP system for this soil: and monitor and evaluate real-time soil water content variations under a tomato crop using the calibrated MCP system. Sensor calibration was conducted under laboratory conditions. Soil bulk density at different water contents and saturated hydraulic conductivity were measured on the field. Bulk density increased with increasing water content: there was a 30 percent bulk density increase as a result of 0.25 cm³ cm^-3 water content variation. Compared with the manufacturer's calibration, site specific laboratory calibration of MCP gave a more accurate determination of soil water. Field determined saturated hydraulic conductivity was higher than laboratory determined values reported in the literature for the same soil type. Real-time soil water content monitoring within the root zone showed substantial variations due to water input (irrigation and rainfall) and water output (evapotranspiration and deep percolations). However, water content variations were much further reduced in the soil layer below the root zone.     

Relation of fish larvae and zooplankton biomass in the Gulf of Aden

This study is based on zooplankton samples collected in the upper 50 m by the F.R.V. Manihine in the Gulf of Aden during October–November, 1966 and February–March, 1967. Generally, the displacement volume of zooplankton varied between 20 and 67 ml/m². Some higher values, up to 100 ml/m², were also observed. The number of larval fish in positive hauls ranged from 2 to 282 larvae/m². An inverse relationship between the number of larval fish and the accompanying volume of zooplankton was noted. This relationship is discussed. It is hypothesized that larval mortality due to predation in the Gulf of Aden during the northeast monsoon (November, February and March) was very high.