Nitrogen footprints: Regional realities and options to reduce nitrogen loss to the environment

Ambio - Nitrogen (N) management presents a sustainability dilemma: N is strongly linked to energy and food production, but excess reactive N causes environmental pollution. The N footprint is an...     

The Use of Zero‐Valent Iron (ZVI) Technology to Promote DDT and Dieldrin Degradation at Point Pelee National Park

Point Pelee National Park (PPNP) is highly contaminated with dichlorodiphenyltrichloroethane (DDT) and dieldrin due to the historical use of these two persistent organochlorine pesticides. Zero‐valent iron (ZVI) technology with and without amendments has been successfully used in the past to promote organochlorine pesticides degradation in several locations in North America and Europe. In this study, the use of two commercially available ZVI products, DARAMEND^® and EHC^®, to promote DDT and dieldrin degradation in PPNP's soil and groundwater were investigated. DARAMEND^® was applied to PPNP's soil in a laboratory experiment and in an in situ pilot‐scale plot. In both cases, DARAMEND^® did not significantly increase DDT or dieldrin degradation in treated soils. The effectiveness of EHC^® was tested in a laboratory experiment that simulated the park's groundwater environment using PPNP's pesticide contaminated soil. The result was consistent with the one reported for DARAMEND^®, in that there was no significant increase in DDT or dieldrin degradation in any of the samples treated with EHC^®. These results demonstrate that both of these ZVI commercially available products are not suitable for in situ remediation at PPNP.  ©2017 Wiley Periodicals, Inc.     

Trends in on-road vehicle emissions and ambient air quality in Atlanta,Georgia, USA,from the late 1990s through 2009

On-road vehicle emissions of carbon monoxide (CO), nitrogen oxides (NO_x), and volatile organic compounds (VOCs) during 1995–2009 in the Atlanta Metropolitan Statistical Area were estimated using the Motor Vehicle Emission Simulator (MOVES) model and data from the National Emissions Inventories and the State of Georgia. Statistically significant downward trends (computed using the nonparametric Theil-Sen method) in annual on-road CO, NO_x, and VOC emissions of 6.1%, 3.3%, and 6.0% per year, respectively, are noted during the 1995–2009 period despite an increase in total vehicle distance traveled. The CO and NO_x emission trends are correlated with statistically significant downward trends in ambient air concentrations of CO and NO_x in Atlanta ranging from 8.0% to 11.8% per year and from 5.8% to 8.7% per year, respectively, during similar time periods. Weather-adjusted summertime ozone concentrations in Atlanta exhibited a statistically significant declining trend of 2.3% per year during 2001–2009. Although this trend coexists with the declining trends in on-road NO_x, VOC, and CO emissions, identifying the cause of the downward trend in ozone is complicated by reductions in multiple precursors from different source sectors.

Implications:Large reductions in on-road vehicle emissions of CO and NO_x in Atlanta from the late 1990s to 2009, despite an increase in total vehicle distance traveled, contributed to a significant improvement in air quality through decreases in ambient air concentrations of CO and NO_x during this time period. Emissions reductions in motor vehicles and other source sectors resulted in these improvements and the observed declining trend in ozone concentrations over the past decade. Although these historical trends cannot be extrapolated to the future because pollutant concentration contributions due to on-road vehicle emissions will likely become an increasingly smaller fraction of the atmospheric total, they provide an indication of the benefits of past control measures.     

Protected area planning to conserve biodiversity in an uncertain future

Protected areas are a key instrument for conservation. Despite this, they are vulnerable to risks associated with weak governance, land-use intensification, and climate change. We used a novel hierarchical optimization approach to identify priority areas for expanding the global protected area system that explicitly accounted for such risks while maximizing protection of all known terrestrial vertebrate species. To incorporate risk categories, we built on the minimum set problem, where the objective is to reach species distribution protection targets while accounting for 1 constraint, such as land cost or area. We expanded this approach to include multiple objectives accounting for risk in the problem formulation by treating each risk layer as a separate objective in the problem formulation. Reducing exposure to these risks required expanding the area of the global protected area system by 1.6% while still meeting conservation targets. Incorporating risks from weak governance drove the greatest changes in spatial priorities for protection, and incorporating risks from climate change required the largest increase (2.52%) in global protected area. Conserving wide-ranging species required countries with relatively strong governance to protect more land when they bordered nations with comparatively weak governance. Our results underscore the need for cross-jurisdictional coordination and demonstrate how risk can be efficiently incorporated into conservation planning. Planeación de las áreas protegidas para conservar la biodiversidad en un futuro incierto     

Impediments and Solutions to Sustainable,Watershed-Scale Urban Stormwater Management: Lessons from Australia and the United States

In urban and suburban areas, stormwater runoff is a primary stressor on surface waters. Conventional urban stormwater drainage systems often route runoff directly to streams and rivers, thus exacerbating pollutant inputs and hydrologic disturbance, and resulting in the degradation of ecosystem structure and function. Decentralized stormwater management tools, such as low impact development (LID) or water sensitive urban design (WSUD), may offer a more sustainable solution to stormwater management if implemented at a watershed scale. These tools are designed to pond, infiltrate, and harvest water at the source, encouraging evaporation, evapotranspiration, groundwater recharge, and re-use of stormwater. While there are numerous demonstrations of WSUD practices, there are few examples of widespread implementation at a watershed scale with the explicit objective of protecting or restoring a receiving stream. This article identifies seven major impediments to sustainable urban stormwater management: (1) uncertainties in performance and cost, (2) insufficient engineering standards and guidelines, (3) fragmented responsibilities, (4) lack of institutional capacity, (5) lack of legislative mandate, (6) lack of funding and effective market incentives, and (7) resistance to change. By comparing experiences from Australia and the United States, two developed countries with existing conventional stormwater infrastructure and escalating stream ecosystem degradation, we highlight challenges facing sustainable urban stormwater management and offer several examples of successful, regional WSUD implementation. We conclude by identifying solutions to each of the seven impediments that, when employed separately or in combination, should encourage widespread implementation of WSUD with watershed-based goals to protect human health and safety, and stream ecosystems.     

Racial differences in promotion candidate performance and reactions to selection procedures: a field study in a diverse top‐management context

The present study examined African‐American and White promotion candidates' reactions to and performance on selection procedures that were completed within a police department where African Americans occupied the majority of top‐management positions. Reactions (perceived job relatedness and test‐taking motivation) of 187 candidates competing for promotion to the rank of sergeant were assessed after completing a written job knowledge test and a situational interview. Analyses showed that both the African‐American and White candidates judged the situational interview to be more job‐related than the pencil‐and‐paper job knowledge test. In addition, African Americans perceived both selection measures to be more job‐related and reported higher levels of test‐taking motivation than White candidates even though African Americans performed more poorly than White candidates on the paper‐and‐pencil test. These results challenge the contention that lower test‐taking motivation for African‐American candidates is related to racial differences in performance on pencil‐ and‐paper tests. Implications and directions for future research on reactions to selection procedures for promotion in racially diverse employment settings are discussed. Copyright © 2007 John Wiley & Sons, Ltd.     

Toxicity of carbaryl, diquat dibromide, and fluoranthene, individually and in mixture, to larval grass shrimp, Palaemonetes pugio

This study examined the toxicity of two pesticides (carbaryl and diquat dibromide) and one polycyclic aromatic hydrocarbon (fluoranthene), both singly and in mixture, to grass shrimp larvae (Palaemonetes pugio). These three chemicals are all present in coastal environments and can easily enter estuarine ecosystems. Fluoranthene was the most toxic chemical with a 96-h LC50 value of 32.45 microg/L, followed by carbaryl (43.02 microg/L) and diquat dibromide (1624 microg/L). In the chemical mixture tests, the binary carbaryl/diquat dibromide mixture and the ternary carbaryl/diquat dibromide/fluoranthene mixture had additive results.     

Understanding long-term baseflow water quality trends using a synoptic survey of the ground water-surface water interface, central Wisconsin

The relationship between stream water quality and landscape activities is difficult to evaluate where the principal source of stream flow is ground water seepage because the average travel time from ground water recharge areas to stream discharge positions can be on the order of decades. We tested the idea that past and future baseflow water quality can be predicted based on a synoptic survey of ground water recharge age-dates (based on chlorofluorocarbon [CFC] measurements) and water quality measurements obtained at the ground water-surface water interface. In this study we (i) characterize the discharge-weighted age distribution and water quality of ground water seepage into the Little Plover River (LPR); (ii) use this information to backcast and forecast baseflow NO(3)(-) concentrations; and (iii) evaluate NO(3)(-) backcasts against historical baseflow data (1960 to 2000). The discharge-weighted apparent CFC age of ground water seepage into the LPR was 23.7 (+/-7) yr. Baseflow backcasts matched the four decade rise of baseflow NO(3)(-) from 2 to 8 mg L(-1). Baseflow forecasts included three scenarios. Scenario A projects the historical rise of NO(3)(-) in the LPR basin's ground water recharge through 2050. Scenario B projects a leveling off of NO(3)(-) in ground water recharge in the year 2000. Scenario C projects a leveling off in the year 1985. Under Scenario A, LPR baseflow NO(3)(-) will increase steadily from 8 to 19 mg L(-1) between 2000 and 2050. Under scenarios B and C baseflow NO(3)(-) will plateau at 13 mg L(-1) in 2030 and at 10 mg L(-1) in 2010, respectively. The approach developed in this study can be used to (i) reconstruct historical baseflow water quality patterns in the absence of long-term monitoring data and (ii) project the effects of potential management decision on future water quality.     

氮与自然

在某种程度上,人类对全球氮循环的改变是很重要的,因为增加的氮极大地改变了许多天然生态系统的组成、生产率和其它性质.增加的氮为什么有这么大的影响力?为什么如此多的天然生态系统都处于缺氮状态?减缓氯相对于其它元素的循环过程,和控制生态系统水平的氮输入输出过程,都使氮供应成为生态系统动态的限制因子.我们讨论了可以减慢氮循环的因子:陆地植物和其它有机体之间的化学计量学差异,蛋白质沉淀防御植物的多度,土壤有机质中C-N键状态.对输入来讲,氮固定的能量消耗及其后果,氮以外的养分供应,对固氮者的优先取食,所有这些都能限制生物固氮者的多度和/或活动.这些过程加在一起,推动和维持着许多天然陆地生态系统的氮限制.