The benefits of the Kyoto Protocol to developing countries

The Kyoto Protocol relies on incentive-based regulations layered underneath a global cap on net emissions of greenhouse gases. Within the Kyoto Protocol are opportunities and constraints for signatory nations. Of concern to developing nations are the constraints the Kyoto Protocol could place on future growth. We examine the constraints and the opportunities offered to developing countries within the Kyoto Protocol. By identifying the potential costs and benefits the Kyoto Protocol has to offer to developing countries and by examining the incentives each create, we hope to spark serious investigations into ways to minimize the potential costs of entering the Kyoto Protocol and take full advantage of the potential benefits.

Strain-related physiological and behavioral effects of <Emphasis Type="Italic">Skeletonema marinoi</Emphasis> on three common planktonic copepods

Three strains of the chain-forming diatom Skeletonema marinoi, differing in their production of polyunsaturated aldehydes (PUA) and nutritional food components, were used in experiments on feeding, egg production, hatching success, pellet production, and behavior of three common planktonic copepods: Acartia tonsa, Pseudocalanus elongatus, and Temora longicornis. The three different diatom strains (9B, 1G, and 7J) induced widely different effects on Acartia tonsa physiology, and the 9B strain induced different effects for the three copepods. In contrast, different strains induced no or small alterations in the distribution, swimming behavior, and turning frequency of the copepods. 22:6(n-3) fatty acid (DHA) and sterol content of the diet typically showed a positive effect on either egg production (A. tonsa) or hatching success (P. elongatus), while other measured compounds (PUA, other long-chain polyunsaturated fatty acids) of the algae had no obvious effects. Our results demonstrate that differences between strains of a given diatom species can generate effects on copepod physiology, which are as large as those induced by different algae species or groups. This emphasizes the need to identify the specific characteristics of local diatoms together with the interacting effects of different mineral, biochemical, and toxic compounds and their potential implications on different copepod species.     

The concentration and probabilistic risk assessment of potentially toxic elements in fillets of silver pomfret (Pampus argenteus): A global systematic review and meta-analysis

The contamination of fish type products such as silver pomfret fish fillets by potentially toxic elements (PTEs) has raised global health concerns. Related studies regarding the concentration of PTEs in fillets of silver pomfret fish were retrieved among some international databases such as Scopus, PubMed and Embase between 1 January 1983 and 10 March 2020. The pooled (mean) concentration of PTEs in fillets of silver pomfret fish was meta-analyzed with the aid of a random-effect model (REM). Also, the non-carcinogenic risk was estimated via calculating the 95th percentile of the total target hazard quotient (TTHQ). The meta-analysis of 21 articles (containing 25 studies or data reports) indicated that the ranking of PTEs in fillets of silver pomfret fish was Fe (11,414.81 µg/kg wet weight, ww) > Zn (6055.72 µg/kg ww) > Cr (1825.79 µg/kg ww) > Pb (1486.44 µg/kg ww) > Se (1053.47 µg/kg ww) > Cd (992.50 µg/kg ww) > Ni (745.23 µg/kg ww) > Cu (669.71 µg/kg ww) > total As (408.24 µg/kg ww) > Co (87.03 µg/kg ww) > methyl Hg (46.58 µg/kg ww). The rank order of health risk assessment by country based on the TTHQ for adult consumers was Malaysia (2.500) > Bangladesh (0.886) > Iran (0.144) > China (0.045) > Pakistan (0.020) > India (0.015), while the corresponding values for child consumers was Malaysia (11.790) > Bangladesh (4.146) > Iran (0.675) > China (0.206) > Pakistan (0.096) > India (0.077). The adult consumers in Malaysia and children in Malaysia and Bangladesh were at considerable non-carcinogenic risk. Therefore, following the recommended control plans in order to reduce the health risk associated with the ingestion of PTEs via consumption of silver pomfret fish fillets is crucial.     

Construction,renovation, and demolition waste in landfill: a review of waste characteristics,environmental impacts,and mitigation measures

Environmental Science and Pollution Research - With the increase in global population, industrialization, and urbanization, waste from construction, renovation, and demolition (CRD) activities has...     

Removal of thiobencarb in aqueous solution by zero valent iron

A cost-effective method with zero valent iron (ZVI) powder was developed for the purification of thiobencarb (TB)-contaminated water. The removal treatment was performed in the batch system. A sample solution of 10 ml containing 10 microg ml(-1) of TB could be almost completely treated by 100mg of ZVI at 25 degrees C for 12h of treatment time. Since the formation of chloride ion in the aqueous solution during the treatment of TB was observed, the removal of TB with ZVI may contain two processes: reduction (degradation) and adsorption. Because the present treatment for TB is simple, easy handling and cheap, the developed technology with ZVI can contribute to the treatment of agricultural wastewaters.     

Land surface temperature estimating in urbanized landscapes using artificial neural networks

Scenario-based land surface temperature (LST) modeling is a powerful tool for adopting proper urban land use planning policies. In this study, using greater Isfahan as a case study, the artificial neural network (ANN) algorithm was utilized to explore the non-linear relationships between urban LST and green cover spatial patterns derived from Landsat 8 OLI imagery. The model was calibrated using two sets of variables: Normalized Difference Built Index (NDBI) and Normalized Difference Vegetation Index (NDVI). Furthermore, Compact Development Scenario (CDS) and Green Development Scenario (GDS) were defined. The results showed that GDS is more successful in mitigating urban LST (mean LST?=?40.93) compared to CDS (mean LST?=?44.88). In addition, urban LST retrieved from the CDS was more accurate in terms of ANOVA significance (sig?=?0.043) than the GDS (sig?=?0.010). The findings of this study suggest that developing green spaces is a key strategy to combat against the risk of LST concerns in urban areas.     

The influence of processing and clarifier agents on the concentrations of potentially toxic elements (PTEs) in pekmez (a grape molasses-like syrup)

The changes in some potentially toxic elements (PTEs) including lead (Pb), cadmium (Cd), arsenic (As), iron (Fe), zinc (Zn), and copper (Cu) during pekmez (grape molasses-like syrup) processing and the utilization of various types of clarifiers (white soil, bentonite, and gelatin) in two levels (1.5 and 3% w/w) were analyzed. The average concentrations of Pb, Cd, As, Fe, Zn, and Cu in grape samples were measured as 0.055?±?0.005, 0.030?±?0.002, 0.044?±?0.002, 2.882?±?0.013, 2.372?±?0.088, and 1.194?±?0.01 μg g^?1. During pekmez production, the range of changes in Pb, Cd, As, Fe, Zn, and Cu was ?43.38% to 40.25%, ?55.49% to 0.23%, ?76.15% to 1.80%, ?74.15% to 58.47%, ?40.55% to ?18.12%, and ?83.16% to ?21.39%, respectively. The effect of the clarification process on the PTEs depended on the type and concentration of both PTE and clarifier agent used while the incorporation of gelatin resulted in a significant reduction in all of PT.

Graphical abstract

     

A sustainable sulfate process to produce TiO2 pigments

Titanium dioxide (TiO₂) is a widely used white pigment. TiO₂ production in 2006 was about 1,400,000 metric tons in the USA. The two major processes to manufacture TiO₂ are the chloride process and the sulfate process. Currently, the TiO₂ industry finds the waste generated in the chloride process less than the waste generated in the sulfate process in its present design, despite generating large quantities of process-related carbon dioxide and carbon monoxide. As a consequence, the sulfate process appears less economical, notably due to the production of green vitriol, FeSO₄·7H₂O, as a major waste. Here, we describe a more sustainable sulfate process based on an earlier study on thermal decomposition of iron(II) sulfates. In the sustainable sulfate process, FeSO₄·7H₂O waste is used for greener production of sulfuric acid, H₂SO₄, used in turn for the digestion of ilmenite. Theoretical and actual yields of waste byproducts per metric ton of TiO₂ produced are used to show the environmental and economic advantages of the sustainable sulfate process.     

Cytotoxicity,in vivo toxicity,and chemical composition of the hexane extract of Plectranthus amboinicus (Lour.) Spreng

Environmental Science and Pollution Research - Cancer is a universal health issue, and many anticancer therapeutic drugs have been isolated from natural products. This study analyzed the cytotoxic...