PM10浓度时间序列多时间尺度分析的小波方法

文章利用Morlet小波函数进行小波变换,以乌鲁木齐市的大气污染物时间序列为例,分析了当地PM10的多时间尺度的演变特性。研究结果显示,其年际变化和季节性变化的时间尺度在尺度空间中分布不均匀,受气象和污染源因素影响,具有较明显的局部化特征。     

苏丹红I对小鼠卵巢的损伤作用及对Caspase-3和Ki-67表达的影响

苏丹红是一种人工合成偶氮染料,可引起肝脏及泌尿系统等多个脏器的肿瘤,但苏丹红对生殖系统的毒性研究较少。本研究以昆明小鼠为受试对象,探讨苏丹红I对小鼠卵巢组织Caspase-3和Ki-67表达的影响。将24只昆明小鼠随机分为:对照组、低剂量(60 mg·kg~(-1))、中剂量(120 mg·kg~(-1))、高剂量(240 mg·kg~(-1))4组,6只/组。胃灌4周,4周末处死。HE染色观察各组卵巢组织病理变化,免疫组化法检测卵巢组织Caspase-3和Ki-67表达,Real time PCR检测卵巢组织Caspase-3和Ki-67 m RNA表达,Western blotting检测卵巢组织中Ki-67及Caspase-3蛋白表达。与对照组比较,实验组卵巢中Caspase-3阳性细胞率显著升高(P0.05),而Ki-67阳性细胞率显著降低(P0.05),Real time PCR及Western blotting结果与免疫组化法结果一致。本实验发现苏丹红染毒后颗粒细胞的Caspase-3表达增加,且Caspase-3表达呈剂量依赖性,但Ki-67表达受到抑制。     

Variations between rice cultivars in root secretion of organic acids and the relationship with plant cadmium uptake

To attempt to understand certain mechanisms causing the variations between rice cultivars with regard to Cd uptake and accumulation, pot soil experiments were conducted with two rice cultivars at different levels of Cd, i.e., 0 (the control), 10, 50 mg Cd kg⁻¹ soil. The two rice cultivars differ significantly with regard to Cd uptake and accumulation. Root secretions of low-molecular-weight organic acids (LMWOA) for each treatment were measured with ion chromatography. The results showed that LMWOA concentrations in the soil planted with Shan you 63 (a high soil Cd accumulator) were all higher than those in the soil planted with Wu yun jing 7 (low soil Cd accumulator) at different soil Cd levels, although the magnitudes of the differences varied for individual LMWOA and depend on soil Cd concentrations. For all six LMWOA, there were significant differences at P < 0.05 or < 0.01 levels for soils treated with 10 and 50 mg kg⁻¹ Cd. The magnitude of the differences was greater under soil Cd treatments, especially at relatively low levels (for example, 10 mg Cd kg⁻¹ soil), than in the control. Acetic acid and formic acid constituted more than 96% of the total concentration of the six LMWOA, while citric acid constituted only about 0.1%. The rice cultivar with higher concentrations of LMWOA in soil accumulated more Cd in the plants. The results indicate that LMWOA secretion by rice root, especially in Cd-contaminated soils, is likely to be one of the mechanisms determining the plant Cd uptake properties of rice cultivars.     

不同施肥措施对棉田土壤磷细菌及磷转化强度的影响

研究了不同施肥措施对棉田土壤磷细菌的数量、分布、动态变化及磷转化强度的影响.结果表明,有机肥合理配施N、P、K肥能有效的促进磷细菌的生长发育,磷细菌数量及活性增加,从而增强磷的有效性,改善土壤的供磷性能,有利于棉花生长.     

高分子重金属絮凝剂对 Hg2+的捕集及性能

以含Hg^2 废水作为处理对象,研究了几个影响高分子重金属絮凝剂去除水中Hg^2 的因素,实验表明：(1)pH值对Hg^2 的去除率影响不大;(2)水中某些二价离子的存在不仅不会消耗高分子重金属絮凝剂的用量,而且会促进螯合体MHM-Hg^2 絮凝沉淀,Hg^2 的去除率在99％以上,而一价金属离子对处理效果影响不大;(3)Hg^2 和致浊物质会互相促进彼此的去除,浊度的去除率在98％以上,Hg^2 的去除率在99％以上;(4)高分子重金属絮凝剂对重金属离子具有选择性,可将部分重金属离子从其它离子中分离开、回收再利用．     

Zinc tolerance and accumulation in Pteris vittata L. and its potential for phytoremediation of Zn- and As-contaminated soil

A field investigation and pot experiments were conducted to determine the potential of arsenic (As) hyperaccumulator, Pteris vittata L., to remediate sites co-contaminated with zinc (Zn) and As. We found that P. vittata L. had a very high tolerance to Zn and grew normally at sites with high Zn concentrations. In addition, P. vittata L. could effectively take up Zn into its fronds, with a maximum of 737 mg kg(-1) under field conditions. In pot experiments, the accumulated Zn concentration increased significantly as the Zn treatment was raised from 0 to 2000 mg kg(-1), with a maximum Zn accumulation of 0.22 mg pot(-1). Although the concentration of As in P. vittata L. was reduced by the addition of Zn, total frond accumulation of As was elevated when the Zn treatment was increased from 0 to 1000 mg kg(-1), with a maximum As accumulation of 8.3 mg pot(-1) in the presence of 1000 mg kg(-1) Zn. The high Zn tolerance, relatively high ability to accumulate Zn, and great capacity to accumulate As under conditions of suppression by high Zn suggest that P. vittata L. could be useful for the remediation of sites co-contaminated with Zn and As.     

水位波动带氮素迁移转化规律

为考察水位波动对非饱和-饱和土层中氮素迁移转化的影响,设计土柱实验装置Ⅰ和Ⅱ分别模拟水位稳定与波动两种情景,测定一个水位波动周期内地下水中NO₃^--N、NO₂^--N和NH₄⁺-N浓度变化情况。结果表明,柱Ⅱ水位第1次下降柱内1^#,2^#,3^#,4^#采样点NO₃^--N浓度均增大,增幅分别为6.5%、14.9%、15.33%和19.8%。水位上升时结果相反,分别降低17.3%、26.15%、50.29%和44.61%。第2次水位下降至初始位置4个采样点NO₃^--N浓度再次增大,幅度分别为7.1%、10.6%、13.89%和7.76%。铵态氮呈相反趋势不同程度的变化。水位波动柱Ⅱ连通水槽内总氮量增加显著高于柱I水槽,即水位波动有利于波动带地下水中氮素垂向迁移,加重波动带以下地下水硝酸盐污染。因此,水位波动对氮素迁移转化的影响不容忽视。     

氯化铁和硫酸铁对酸性土壤中有效态镉和铅污染的修复作用

采用浸泡实验法研究了氯化铁和硫酸铁对酸性土壤中有效态镉和铅污染的修复效果,结果表明,氯化铁和硫酸铁均能有效去除土壤有效态镉和铅污染,Fe(Ⅲ)用量为50~100 mmol/kg时,有效态Cd和Pb的去除效果可达70%~96%。氯化铁和硫酸铁能去除土壤中的水溶态、碳酸盐结合态、腐殖酸结合态、铁锰氧化物结合态和强有机结合态Cd和Pb及交换态Cd。氯化铁和硫酸铁对Cd均既有洗脱修复作用又有固定修复作用,且洗脱修复作用的贡献稍大;氯化铁用量较小时(50 mmol/kg)对Pb既有固定修复又有洗脱修复作用,固定修复作用稍大;用量较大时(100 mmol /kg),对Pb只有洗脱修复作用。硫酸铁对Pb的修复作用则以固定修复作用为主,洗脱修复作用很小。     

Fe(Ⅱ)EDTA络合吸收-铁粉还原再生脱除NO性能

利用Fe(Ⅱ)EDTA络合吸收-铁粉间歇还原再生脱除NO并回收氨资源的方法,实验研究了铁粉还原再生Fe(Ⅱ)(NO)EDTA的过程及其影响因素。结果表明,以0.015 mol/L的Fe(Ⅱ)EDTA做吸收剂,在起始pH 5.5、温度323K条件下吸收400×10-6~500×10-6的NO,脱除率95%以上;铁粉还原再生Fe(Ⅱ)(NO)EDTA过程可用缩芯模型阐释;铁粉添加量与搅拌强度直接决定了铁粉质点数量,是影响反应的重要因素;实验中Fe(Ⅱ)(NO)EDTA络合液150 mL,氧气含量为5%时,搅拌速度900 r/min、粒径为0.12 mm的铁粉浓度5.3 g/L、温度353 K、pH=6为最适宜再生条件。     

外浮顶原油储罐VOCs排放核算参数对排放量的影响研究

依据美国环保署颁布的储罐VOCs排放量核算公式,从环境参数、原油参数和储罐结构参数3个方面对外浮顶储罐VOCs排放的影响进行了研究,其中包括了边缘密封排放挂壁排放、浮盘附件排放和浮盘着陆期间排放等几个相关排放核算数学公式。结果表明:环境风速增大,环境温度升高或太阳辐射强度提高均导致排放量增大;原油温度升高或原油周转量增加也导致排放量增加;储罐直径增加,罐漆颜色浅,或者罐壁锈蚀情况好会降低VOCs排放量。