Use of micellar liquid chromatography for rapid monitoring of fungicides post harvest applied to citrus wastewater

A method based on micellar liquid chromatography has been developed to simultaneously monitor four pesticides largely post-harvest applied to citrus:thiabendazole,pyrimethanil,o-phenylphenol and imazalil.Water samples were filtered and directly injected without other treatment,thus avoiding extraction steps.The composition of the mobile phase was optimized using a chemometrical approach to achieve and excellent resolution to 0.07 mol/L SDS/5%,V/V 1-pentanol buffered at p H 3.Mobile phase run through a C18 column at 1 m L/min at room temperature.The detection was performing by UV–Visible absorbance using a wavelength program:0–10 min,305 nm(for thiabendazole);10–12;265 nm(for pyrimethanil)and 12–18,220 nm(o-phenylphenol and imazalil).The developed method was validated following the guidelines of the US Environmental Protection Agency in terms of:quantitation range,(0.5–4 to 15μg/m L),linearity(r20.9995),sensitivity(LOD,0.18–1.4μg/m L),precision(9.2%),trueness(93.9%–103.7%),and ruggedness(9.9%).It was found that the fungicides remain up to eight days in surface water at outdoor conditions.The method was used to screen the presence of the analytes in several waste water samples,and was proved to be useful in routine analysis.     

Workspace design for crane cabins applying a combined traditional approach and the Taguchi method for design of experiments

Procedures in the development process of crane cabins are arbitrary and subjective. Since approximately 42% of incidents in the construction industry are linked to them, there is a need to collect fresh anthropometric data and provide additional recommendations for design. In this paper, dimensioning of the crane cabin interior space was carried out using a sample of 64 crane operators’ anthropometric measurements, in the Republic of Serbia, by measuring workspace with 10 parameters using nine measured anthropometric data from each crane operator. This paper applies experiments run via full factorial designs using a combined traditional and Taguchi approach. The experiments indicated which design parameters are influenced by which anthropometric measurements and to what degree. The results are expected to be of use for crane cabin designers and should assist them to design a cabin that may lead to less strenuous sitting postures and fatigue for operators, thus improving safety and accident prevention.     

Drivers of farm-level adaptation to climate change in Africa: an evaluation by a composite index of potential adoption

Over recent decades, there has been increasing levels of research dedicated to assess drivers of farm-level uptake of adaptation strategies to climate change. The main purpose of this research being to determine how policy intervention can most effectively increase adoption. This paper aims to synthesise this past research in order to scale up uptake of farm-level adaptation strategies through a composite index of potential adoption in Africa. In doing so, we review the estimated coefficients of econometric regressions in 42 case studies published in peer-review journals to identify the factors that regularly explain adoption. We find that these common factors can be grouped into seven components, that is human capital, financial resources, infrastructure and technology, social interaction and governance, food security, dependence on agriculture and attitudes towards the environment. Using national-level indicators of these seven categories, we develop a composite index to inform potential adoption and test the robustness of the index in an in-depth sensitivity analysis. The results show that the highest likelihood of adoption of farm-level adaptation strategies is in Northern African countries namely Tunisia, Egypt, Algeria and Morocco and in Southern African countries such as South Africa and Botswana. Conversely, they indicate that the lowest likelihood of adoption is situated in nations of the Sahel and Horn of Africa and in nations that have recently experienced conflict. We conclude that adoption is associated predominantly with governance, civil rights, financial resources and education. However, it is not necessarily driven by the magnitude of climate change impacts on agricultural production.     

Ensuring the service quality at a university construction technology laboratory in Brazil

Service quality in a construction technology laboratory can result in an improvement in construction companies’ competitiveness. This research aims to evaluate the service quality provided by a construction technology laboratory, specifically in the segment of performing testing through the rupturing of concrete samples. For this research, a survey was conducted using a structured questionnaire that was created based on a literature review regarding the surveying of laboratory customers at a university in the south of Brazil. Our research was both exploratory and quantitative, and the data were analyzed by applying multivariate data analysis. The conclusions of this study show that the dimensions of quality services are: communication, reliability, responsiveness, credibility, and tangibility. These five dimensions together provide a high explained variance standard of 79.75%. Having a suitable number of attendants available to serve customers and presenting agility in the construction laboratory is one of the managerial research contributions. Moreover, through information availability, this research generates greater traceability that can be used both by customers and by institutional management. Constantly and thoroughly monitoring the customer service cycle is another relevant factor that can improve the quality of the services provided.     

The clustering conditions for managing creative tourism destinations: the Alqueva region case,Portugal

The paper discusses conditions and format of a cluster model to support the management of a potential creative tourism destination in a setting where regional cross-sectoral collaboration is lacking. Creative tourism development requires a flexible framework and a healthy collaboration environment, more so when associated with resources shared by several stakeholders. This article focuses on the tourism potential of archaeological knowledge discovered during the environmental impact assessment of the Alqueva dam (Alentejo, Portugal). Interviews were conducted with 38 regional actors in the tourism and heritage sectors, as well as the dam developers and the companies responsible for archaeological interventions. Findings indicate that the lack of specific local policy addressing archaeological heritage hampers its potential use for tourism development, which is further aggravated by the absence of stakeholder communication and cooperation. A conceptual cluster model for the management of creative tourism destinations based on heritage resources and other local resources is proposed.     

Effects of soil composition on solid phase microextraction determination of triazine and organophosphorus pesticides

The influence of organic matter and clay contents on headspace solid phase microextraction (HS-SPME) determination of triazine and organophosphorus pesticides in different soils was studied. The results of the study showed that content of soil organic matter dominantly participated in sorption of triazines (simazine, atrazine and prometryn) to soil, while sorption of organophosphorus pesticides (phorate and tebupirimfos) could not be explained only by contents of dominant soil sorption components (soil organic matter and clay). Sorption of all pesticides studied to different soil types was similar at their lower concentrations while the influence of soil composition was expressed at higher concentration levels. Except for phorate, the obtained sorption trends were different from those obtained by direct SPME mode (DM-SPME) and exhaustive liquid-solid extraction (LSE) method. These results indicated that most likely co-extractants from the analyzed medium complicated evaporation and diffusion of the pesticides to the PDMS fiber during HS-SPME sampling.     

Assessing supercritical fluid extraction for the analysis of fipronil,kresoxim-methyl,acrinathrin, and pyridaben residues in melon

An analytical method, using supercritical fluid extraction (SFE), was assessed for residue analysis of the insecticides fipronil, acrinathrin and pyridaben and the fungicide kresoxim-methyl in melons. Extraction conditions were optimized on glass beads, as inert material, evaluating different pressures, temperatures, and CO₂ volumes. Also, the extractability of pesticides from hydromatrix and anhydrous magnesium sulfate was evaluated. Both adsorbents were evaluated for the preparation of SFE-spiked melon samples. Extractions of fortified samples were done using 20 mL of CO₂, 300 atm, and 50°C. Different extraction conditions, including the addition of water and methanol as a static modifier, were used to assess the extractability of these pesticides, and the addition of methanol was demonstrated to improve the extraction of all the studied pesticides.     

The Scientific Basis of Marine Pollution Prevention Strategies

Abstract

Prevention of marine pollution, particularly in semi-enclosed seas, embayments and areas with limited exchange of water, requires a well conceived and harmonized legal system, specified standards, a monitoring programme, and effective control and enforcement capabilities. This comprehensive approach is often called a strategy. Three generations of strategies have been devised and applied historically in Europe and North America, each a step further in integrating environmental protection, technical advancement and economic capabilities. the overpowering socio-economic problems of transition from a centrally planned to a market economy, a task facing a dozen central and eastern European coastal states, compound the problem of application of an integrated approach.

No management strategy can achieve its set goals unless based on scientific evidence. the data base has to offer information on two basic questions, one specific and one of a general nature.

The specific question is: Has the area under consideration some features, an activity, or one or more living species, which must be protected at any cost? the answer to this question will invoke the precautionary principle into strategic considerations, and leads to the general question: What is the carrying (= assimilative or environmental) capacity for each activity and for the discharge of each contaminant into the impacted area? Answers to these questions lead to the choice of the strategy for environmental management.     

Wave hydrodynamics around a multi-functional artificial reef at Leirosa

This paper describes an application of the Boussinesq-type COULWAVE model to study the wave hydrodynamics in the vicinity of a multi-functional artificial reef (MFAR). This reef is under investigation and consists of a supplementary protection solution for the Leirosa sand dune system located at South of Figueira da Foz, on the Portuguese West coast. Such installation near the coastline is expected to contribute to enhance the surfing conditions in the area, protect the sand dune system in the surroundings of Leirosa beach, and increase its environmental value. Numerical calculations with the COULWAVE model were performed for four test cases, considering two reef geometries (differing in the reef angle) and two incident wave conditions (storm condition and a common wave condition). Comparisons between the results obtained, in terms of wave heights and breaking line positions allow us to assess the influence of the reef on the hydrodynamics near the beach and around the reef. Moreover, the reef performance was analysed in terms of surfability and coastal protection. The surfability parameters (breaker height, Iribarren number and peel angle) were calculated for each test case using the numerical wave heights, wave directions and wave breaking positions. Comparisons of parameters allow characterizing the most appropriate configuration of the reef to improve the surfing conditions in the study area. A methodology based on numerical free surface elevations and horizontal velocity components was developed to calculate wave directions, since this is not a direct output of the COULWAVE model. Concerning coastal protection, analyses of the mean currents around the reef were used together with observations of the velocity cells near the shoreline as an indication of the sediment transport.