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231.
Fatai Adigun Aborode Andrea Raa Matthias Voigt Leticia Malta Cost Eva M. Krupp Joerg Feldmann 《环境科学学报(英文版)》2016,28(11):150-161
We investigated the role of glutathione(GSH) and phytochelatins(PCs) on the detoxification of selenite using Arabidopsis thaliana. The wild-type(WT) of Arabidopsis thaliana and its mutants(glutathione deficient Cad 2–1 and phytochelatins deficient Cad 1–3) were separately exposed to varying concentrations of selenite and arsenate and jointly to both toxicants to determine their sensitivities. The results of the study revealed that, the mutants were about 20-fold more sensitive to arsenate than the WT, an indication that the GSH and PCs affect arsenate detoxification. On the contrary, the WT and both mutants showed a similar level of sensitivity to selenite, an indication that the GSH and PCs do not significantly affect selenite detoxification. However, the WT is about 8 times more sensitive to selenite than to arsenate, and the mutants were more resistant to selenite than arsenate by a factor of 2. This could not be explained by the accumulation of both elements in roots and shoots in exposure experiments. The co-exposure of the WT indicates a synergistic effect with regards to toxicity since selenite did not induce PCs but arsenic and selenium compete in their PC binding as revealed by speciation analysis of the root extracts using HPLC–ICP–MS/ESI–MS. In the absence of PCs an antagonistic effect has been detected which might suggest indirectly that the formation of Se glutathione complex prevent the formation of detrimental selenopeptides. This study, therefore, revealed that PC and GSH have only a subordinate role in the detoxification of selenite. 相似文献
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235.
David M. Hetrick Andrea L. Sjoreen 《Journal of the American Water Resources Association》2004,40(5):1129-1140
ABSTRACT: Hydrologic Transport Assessment System (HYTRAS) is a software package that models contaminant transport in rivers and streams, including volatilization, adsorption/desorption, sedimentation, settling, and resuspension. Biodegradation, photolysis, and any other process that can be modeled using a first‐order decay constant can be included as well. HYTRAS originally modeled the transport of radionuclides and has recently been expanded to include transport of chemicals. The transport of chemicals has been validated using data from an accidental release of the chemicals disulfoton and thiometon into the Rhine River in 1986. For these chemicals, sorption is not an important process. For the range of measured flow velocities, HYTRAS was found to bound the peak arrival times. For the range of measured degradation rates, HYTRAS was found to bound the peak concentrations within 400 km of the source and bound the peak concentrations within a factor of two out to 700 km. 相似文献
236.
A New Respirometric Test Simulating Soil Burial Conditions for the Evaluation of Polymer Biodegradation 总被引:2,自引:0,他引:2
Roberto Solaro Andrea Corti Emo Chiellini 《Journal of Polymers and the Environment》1998,6(4):203-208
A new convenient and reliable method is described for assessing the biodegradation properties of polymeric materials under simulated soil burial conditions, which makes it possible to test with nutrient-rich soils. This method consists of the utilization of a minimum amount of a soil layer, in which the samples to be tested are set in close contact, sandwiched between two layers of perlite, a natural porous aluminosilicate. The biodegradation level is monitored by determining the carbon dioxide evolution derived from the test samples. The limited amount of soil used limits carbon dioxide evolution from the blanks, due to the corresponding limited overall amount of soil carbon. This experimental setup allows for an extremely satisfactory level of confidence in the analytical results, permitting a wider variety of soil types to be tested. 相似文献
237.
垃圾中转站是城市生活垃圾收运处置系统中一个必不可少的环节,合肥市居民生活垃圾中转站目前有31个,其中27个正常运行.由于合肥市垃圾采取卫生填埋处置,现有垃圾中转站的最大特点,就是将垃圾采用高强度的压缩技术进行"打包".我们对合肥市各区垃圾中转站分布及其具体情况也作了详细的调查,并对中转站的位置进行了卫星定位,以期为居民生活垃圾的清运机制的优化打下基础.在对合肥市老城区垃圾中转站进行调查的基础上,提出了合肥市老城区的中转站存在的问题,并对合肥市滨湖新区垃圾中转站的建设提出建议. 相似文献
238.
Buckman AH Norstrom RJ Hobson KA Karnovsky NJ Duffe J Fisk AT 《Environmental pollution (Barking, Essex : 1987)》2004,128(3):327-338
Organochlorine contaminants (OCs) were determined in liver and fat of seven species of seabirds (Alle alle, Uria lomvia, Cepphus grylle, Rissa tridactyla, Pagophila eburnea, Larus hyperboreus, and Fulmaris glacialis) collected in May/June 1998 from the Northwater Polynya in northern Baffin Bay. OC concentrations ranged over an order of magnitude between seabird species and OC groups, with PCBs having the highest concentrations followed by DDT, chlordane, HCH and ClBz. Positive relationships between delta15N (estimator of trophic level) and OC concentrations (lipid basis) were found for all OC groups, showing that trophic position and biomagnification significantly influence OC concentrations in Arctic seabirds. Concentrations of a number of OCs in particular species (e.g., HCH in P. eburnean) were lower than expected based on delta15N and was attributed to biotransformation. P. eburnea and F. glacialis, which scavenge, and R. tridactyla, which migrate from the south, were consistently above the delta15N-OC regression providing evidence that these variables can elevate OC concentrations. Stable isotope measurements in muscle may not be suitable for identifying past scavenging events by seabirds. OC relative proportions were related to trophic position and phylogeny, showing that OC biotransformation varies between seabird groups. Trophic level, migration, scavenging and biotransformation all play important roles in the OCs found in Arctic seabirds. 相似文献
239.
Andrea M. Hofmaier Siegfried M. G. Schwirzer Friedrich J. Wiebel Karl-Werner Schramm Martin Wegenke und Antonius A. F. Kettrup 《Umweltwissenschaften und Schadstoff-Forschung》1999,11(1):2-8
Zusammenfassung Polychlorierte aromatische Kohlenwasserstoffe (PHAK), z.B. 2,3,7,8-Tetrachlordibenzo-p-dioxin (TCDD), weisen eine Vielzahl von toxischen Wirkungen und biologischen Effekten auf. Die Substanzklasse der PHAK besitzt
die Eigenschaft der Bindung an ein cytosolisches Rezeptor-Protein, gefolgt von der Synthese bestimmter Genprodukte, u.a. von
Cytochrom P450 1A1 (CYP 1A1). In dieser Arbeit wird ein Bioassay beschrieben, der erlaubt, die Induktion von CYP 1A1 als Summenparameter
für die biologische Wirksamkeit der kritischen, halogenierten Verbindungen in komplexen Umweltmatrizes zu bestimmen. Zur Abtrennung
von Substanzen aus den Extrakten von Umweltproben (z. B. Naturstoffe und polyzyklische aromatische Kohlenwasserstoffe), die
den Bioassay st?ren k?nnen, wurde ein Ein-S?ulen-Clean-up entwickelt. Die biologisch ermittelten TEQ-Werte stimmen gut mit
den Resultaten der chemischen Analytik überein. Der Bioassay in Kombination mit dem Clean-up bietet eine zeitsparende und
kostengünstige M?glichkeit zur Untersuchung von Umweltproben.
相似文献
240.
August Kaiser Helfried Scheifinger Wolfgang Spangl Andrea Weiss Stefan Gilge Wolfgang Fricke Ludwig Ries Danijel Cemas Brigita Jesenovec 《Atmospheric environment (Oxford, England : 1994)》2007,41(40):9273-9287
The Alpine stations Zugspitze, Hohenpeissenberg, Sonnblick, Jungfraujoch and Mt. Krvavec contribute to the Global Atmosphere Watch Programme (GAW) of the World Meteorological Organization (WMO). The aim of GAW is the surveillance of the large-scale chemical composition of the atmosphere. Thus, the detection of air pollutant transport from regional sources is of particular interest. In this paper, the origin of NOx (measured with a photo-converter), CO and O3 at the four Alpine GAW stations is studied by trajectory residence time statistics. Although these methods originated during the early 1980s, no comprehensive study of different atmospheric trace gases measured simultaneously at several background observatories in the Alps was conducted up to present.The main NOx source regions detected by the trajectory statistics are the northwest of Europe and the region covering East Germany, Czech Republic and southeast Poland, whereas the main CO source areas are the central, north eastern and eastern parts of Europe with some gradient from low to high latitudes. Subsiding air masses from west and southwest are relatively poor in NOx and CO.The statistics for ozone show strong seasonal effects. Near ground air masses are poor in ozone in winter but rich in ozone in summer. The main source for high ozone concentration in winter is air masses that subside from higher elevations, often enhanced by foehn effects at Hohenpeissenberg. During summer, the Mediterranean constitutes an important additional source for high ozone concentrations.Especially during winter, large differences between Hohenpeissenberg and the higher elevated stations are found. Hohenpeissenberg is frequently within the inversion, whereas the higher elevated stations are above the inversion.Jungfraujoch is the only station where the statistics detect an influence of air rich in CO and NOx from the Po Basin. 相似文献