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Andrea Pietro Reverberi Vincenzo Giorgio Dovì Bruno Fabiano Luigi Maga 《Journal of Cleaner Production》2009,17(10):963-968
An unsteady-state biosorption column model in one space variable is considered in this paper. The theoretical study is motivated by the need for predicting the dependent variables of biosorption columns for removal of heavy metals from wastewater, which is potentially an important technology in cleaner production. Pollutant concentrations in the bulk phase, in the liquid filling the pores and in the solid biomass along the axial coordinate of the column were evaluated for a wide range of physical and chemical parameters of the global process. In particular, the assumption of instantaneous chemical reactions is replaced by a more realistic expression taking into account chemical kinetics and fluid advection time scales separately. The resulting system of partial differential equations was solved by means of a reliable numerical algorithm based on the method of lines. The data obtained using the model described in this paper are compared with published experimental data and an estimation of the increased efficiency is made. 相似文献
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Increasingly, performance measurement is being used to hold federal agencies accountable, represent environmental progress, and evaluate the effectiveness of environmental programs. The need to track measurable outputs has created a tendency to present programmatic progress solely by quantifiable data, despite the inherent complexity of natural resource management. Wetlands and fire management programs are two specific environmental arenas that have come to overemphasize the tracking of acreage numbers to validate existing policy direction. In both of these arenas, we find the definition and categorization of "countable" acres to be inconsistent and unreliable. We explore this systemic flaw for both wetlands and fire programs and describe its implications for environmental policy and natural resource management more broadly. We conclude with recommendations for improved performance measurement in these arenas. 相似文献
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Andrea Emili Alessandro Acquavita Stefano Covelli Lucia Spada Antonella Di Leo Santina Giandomenico Nicola Cardellicchio 《Environmental science and pollution research international》2016,23(13):12582-12595
In situ benthic flux experiments were conducted at two stations in the Mar Piccolo of Taranto (Italy), one of the most industrialised and contaminated coastal areas of the Mediterranean. Sediments of the two stations are notably different in their trace metal content, with a station closer to a Navy harbour showing higher mean concentrations of almost all investigated metals (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn). Conversely, both stations are characterised by significant Hg contamination, compared to the local baseline. Results of a sequential extraction scheme on surface sediments suggest a relatively scarce mobility of the examined metals (Zn > Ni > Cr > As > Cu > Pb). A Hg-specific extraction procedure showed that most of the element (93.1 %) occurs in a fraction comprising Hg bound to Fe/Mn oxi-hydroxides. Reduction of these oxides may affect Hg remobilisation and redistribution. Porewater profiles of dissolved trace metals were quite similar in the two sites, although significant differences could be observed for Al, Cu, Fe and Hg. The highest diffusive fluxes were observed for As, Fe and Mn. Mobility rates of several trace elements (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn) were directly measured at the sediment–water interface. Results from benthic in situ incubation experiments showed increasing dissolved metal concentrations with time, resulting in higher fluxes for Cu, Fe, Hg, V and Zn in the most contaminated site. Conversely, fluxes of Mn, Ni and Pb were comparable between the two stations. The estimated flux of Hg (97 μg m?2 day?1) was the highest observed among similar experiments conducted in other highly contaminated Mediterranean coastal environments. Benthic fluxes could be partially explained by considering rates of organic matter remineralisation, dissolution of Fe/Mn oxy-hydroxides and metal speciation in sediments. Seasonal and spatial variation of biogeochemical parameters can influence metal remobilisation in the Mar Piccolo area. In particular, metals could be promptly remobilised as a consequence of oxygen depletion, posing a serious concern for the widespread fishing and mussel farming activities in the area. 相似文献
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We test the hypothesis that echolocation behavior can be used to find the border between bat habitats. Assuming that bats
react to background targets in “edge space” but not in “open space”, we determined the border between these two habitat types
for commuting individuals of the parti-colored bat Vespertilio murinus. We recorded sequences of bats’ echolocation signals while they flew parallel to the walls of large buildings and to the
ground and determined the signals’ average bandwidth, duration, and pulse interval. These parameters varied systematically
with the estimated horizontal and vertical distances between the bats and the background. A distinct effect of horizontal
distance to the background on echolocation behavior was found for horizontal distances of less than 6 m, thus indicating the
border between edge and open space. Only a few bats flew at vertical distances below 5 m. However, enough passages at vertical
distances of 5 m and above indicated that the vertical border is somewhere below a distance of 5 m. Within edge space, V. murinus reacted to the background by reducing signal duration, increasing bandwidth at closer distances, and often emitting one signal
per wing beat. In open space, signal parameters did not vary as a function of distance to the background. There, V. murinus emitted the longest signals with the narrowest bandwidth and often made one or two wing beats without emitting a pulse. With
our data we support with statistical methods the hypothesis that echolocation behavior reveals the border between the habitat
types “edge” and “open space”. 相似文献
48.
Hynek Beneš Renáta Černá Andrea Ďuračková Petra Látalová 《Journal of Polymers and the Environment》2012,20(1):175-185
The model polyurethane foam and model compact polyurethane material were prepared and then decomposed by means of natural
oils. Castor oil and fish oil based polyol were used in this study. Optimal conditions for the polyurethane decomposition
were found. Temperature 250 °C was necessary for efficient polyurethane decomposition by castor oil whereas 200 °C is sufficient
in the case of fish oil based polyol. Prepared products have hydroxyl number in the range of 95–168 mg KOH g−1. During the polyurethane decomposition no cleavage of double bonds in the fatty acid chains of castor oil and fish oil based
polyol was observed. 相似文献
49.
1. The HGPRT (Hypoxanthine‐Guanine‐Phospho‐Ribosyl‐Transferase) assay with Chinese Hamster V79 cells was used to measure the mutagenic effects of UV irradiation, potassium dichromate and nickel chloride. The agents were tested separately and in the combinations of UV plus nickel and dichromate plus nickel. 2. UV, Cr(VI) and Ni(II) were confirmed to be mutagenic in the V79 cell assay. The combination of UV(5J/m2) and Ni(II) (0.5 mM) caused a mutation rate 11.2 times above that corresponding to the sum of the individual mutation rates of these agents. The combined action of Cr(VI) (0.1 mM) and Ni(II) (0.5 mM) produced a mutation rate 2.8 fold above that corresponding to the sum of the individual rates of the separate agents. 3. The enhancing effect of nickel chloride on the mutagenicity of UV or Cr(VI) is interpreted by an interference of Ni(II) with the repair of DNA lesions. 相似文献
50.
Awareness of farm animal welfare issues is growing in Canada, as part of a larger food movement. The baseline Canadian standards for farm animal welfare—the Recommended Codes of Practice for the Care and Handling of Farm Animals—are up for revision. The success of these standards will depend in part on perceived legitimacy, which helps determine whether voluntary code systems are adopted, implemented, and accepted by target audiences. In the context of the Codes, legitimacy will also hinge on whether the standards-developers marshal narratives about farm animals that accord with their audiences’ expectations. The aim of this paper is to catalogue factors that influence legitimacy in farm animal welfare standard-setting, including which narratives of animal welfare are emphasized by standard-setters. Drawing upon the example of the baseline Canadian standards, and the National Farm Animal Care Council, the paper will present a theoretical and methodological framework for analyzing legitimacy in the context of animal welfare standards-development and discuss associated policy considerations. 相似文献